• 한국광학회지
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• 제35권3호
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• pp.95-106
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• 2024

일반 백색 LED의 연색성을 보완하기 위해 적색 양자점을 선택적으로 활용함으로써 고연색성 조명을 구현하는 연구가 최근 활발하다. 본 논문에서는 최근 이루어지고 있는 원격 양자점 부품 연구 및 이를 활용한 고연색성 조명 개발의 현황에 대해 소개한다. 특히 양자점 부품이 배치되는 조명의 광구조 최적화에 있어서 중요하게 고려해야 할 다양한 요소를 집중적으로 논의함으로써 향후 고연색성 조명 연구의 방향 및 전망까지 다루고자 했다.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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• pp.1090-1092
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• 2006

There is provided white light illumination system including a radiation source, a first luminescent material having a peak emission wavelength of about 575 to about 620 nm, a second luminescent material having a peak emission wavelength of about 495 to about 550 nm, which is different from the first luminescent material and a third luminescent material having a peak emission wavelength of about 420 to about 480 nm, which is different from the first and second luminescent materials. The LED may be a UV LED and the luminescent materials may be a blend of three phosphors. A human observer perceives the combination of the blue, green and red phosphor emissions as white light.

• 한국재료학회지
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• 제17권3호
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• pp.137-141
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• 2007

A series of $Ca_{1-x}Sr_{x}S:Mn$ phosphors were synthesized by solid-state reactions. The emission peaks of $Ca_{1-x}Sr_{x}S:Mn$ is blue shifted front 605 to 570 nm with increasing Sr content. Since $Ca_{1-x}Sr_{x}S:Mn$. Mn phosphors exhibit strong absorption in region of 254 nm, the emission wavelength of a fluorescent lamp, these phosphors can be used as wavelength tunable emitting phosphors from reddish orange to yellow. We investigated the optical and structural properties of $Ca_{1-x}Sr_{x}S:Mn$ phosphors.

• Journal of the Optical Society of Korea
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• 제17권6호
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• pp.506-512
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• 2013

Recently, the color separation issue of wide-spreading white LEDs has attracted attention due to their wide applicability as light sources in direct-lit LCD backlights. These wide-spreading LED packages usually consist of LED chips, a color-conversion phosphor layer, and a light-shaping lens. The technical aspect of this color issue was related to a method for balancing the yellow spectral component emitting from phosphors with respect to the blue one from the LED chip as a function of viewing angle. In this study, we suggested an approach for carrying out quantitative analysis for the color separation problem occurring in wide-spreading LED packages by optical simulation. In addition, the effect of an internal scattering layer on the color uniformity was investigated, which may be considered as a potential solution for this problem.

• 한국재료학회지
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• 제12권7호
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• pp.555-559
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• 2002

Blue-emitting $Sr_{10}$($PO$)$_{6}$ $Cl_2$:$Eu^{2+}$ and $_{(Sr,Mg) }$ 10/($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ phosphor particles for application of long-wavelength UV LED were prepared by ultrasonic spray pyrolysis. The luminescence characteristics under long- wave-length ultraviolet of the $Sr_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ and (Sr,Mg)$_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$^Eu{2+}$ phosphor particles prepared by the spray pyrolysis were compared with that of the commercial product. The PL intensity of the $Sr_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ particles prepared by the spray pyrolysis was lower than that of the commercial $Sr_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ particles because prepared $Sr_{10}$ ($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ phosphor particles had porous structure and hollow morphology. However, the PL intensity of the (Sr,Mg)$_{10}$($PO_4$)$_{6}$ $Cl_2$:$Eu^{2+}$ phosphor particles prepared by the spray pyrolysis was 8% higher than that of the commercial one. The high brightness of $(Sr,Mg)_{10}$ ($PO_4$)$_{6}$ $Cl_2$:Eu$^{2+}$ phosphor particles prepared by spray pyrolysis is due to the dense structure and high crystallinity of particles. The TEX>$(Sr,Mg)<_{10}$ ($PO_4$)$_{6}$ /$Cl_2$:$Eu^{ 2+}$ phosphor particles had main emission peak t 448 nm under long- wavelength ultraviolet.

• 한국결정성장학회지
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• 제33권1호
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• pp.1-16
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• 2023

LED용 비희토류 기반 strontium-aluminate 계 적색 발광 형광체를 고상반응법으로 합성하였고, 합성온도 및 Mn⁴⁺ 활성제 첨가량이 형광체의 발광특성에 미치는 영향에 대하여 조사하였다. 합성된 SrAl₂O₄:Mn⁴⁺ 형광체는 330 및 460 nm 근처 파장에서 피크가 나타나는 근자외선 및 청색 영역의 광대역 흡광 특성과 644, 658, 및 673 nm 근처의 세 개의 피크로 이루어진 삼중밴드 형태의 deep red 발광 특성을 나타내었다. 합성온도 1600℃, 0.5 mol% Mn⁴⁺ 이온 첨가량에서 합성된 SrAl₂O₄:Mn⁴⁺ 형광체가 가장 우수한 발광 특성을 나타내었고, 0.7 mol% 이상의 첨가량에서는 농도소광이 관찰되었다. FE-SEM 및 DLS 입도크기분포 분석 결과 합성된 SrAl₂O₄:Mn⁴⁺ 형광체 2~6.4 ㎛의 입도 분포 및 불규칙한 구형을 나타내며 약 4 ㎛의 평균 입자 크기를 갖는 것으로 조사되었다.

• 한국표면공학회지
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• 제54권3호
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• pp.112-118
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• 2021

Dy³⁺- and Eu³⁺-codoped BaWO₄ phosphors for white light-emitting diode were synthesized with different activator ions via a solid-state reaction process. The structural, morphological, and optical properties of the BaWO₄:Dy³⁺,Eu³⁺ phosphors were investigated as a function of Eu³⁺ concentration at a fixed concentration of Dy³⁺ ions. XRD patterns exhibited that all the synthesized phosphors had a tetragonal system, irrespective of the concentrations of Dy³⁺ and Eu³⁺ ions. The excitation spectra of the synthesized phosphors were composed of three intense bands centered at 251, 355, and 393 nm and several weak peaks. For the BaWO₄:Dy³⁺,Eu³⁺ phosphors synthesized with 1 mol% of Eu³⁺, the emission spectra under ultraviolet excitation at 393 nm showed two strong blue and yellow bands at 485 and 577 nm corresponding to the ⁴F_9/2⁶H_15/2 and ⁴F_9/2⁶H_13/2 transitions of Dy³⁺ ions, respectively and several weak bands in the range of 600-700 nm resulting from the 4f transitions of Eu³⁺ ions. As the concentration of Eu³⁺ ions increased, intensities of the blue and yellow emission bands gradually decreased while those of the red emissions increased rapidly and the energy transfer efficiency from Dy³⁺ to Eu³⁺ ions was 95.3% at 20 mol% of Eu³⁺. The optimum white light emission with x=0.363, y=0.357 CIE 1931 chromaticity coordinates was obtained for the sample doped with 5 mol% Dy³⁺ and 1 mol% of Eu³⁺.

• 한국자기학회지
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• 제15권4호
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• pp.246-249
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• 2005

플라즈마 디스플레이(Plasma Display Panel: PDP)용 청색 형광체인 $CaMgSi_{2}O_6:Eu^{2+}(CMS:Eu^{2+})$를 고상반응(sold-state reaction)법으로 합성하였다. 합성한 재료를 실온에서부터 $1,100^{\circ}C$까지 열처리하여 photoluminescence(PL)와 EPR 측정으로 열적 안정성을 연구하였다. $CMS:Eu^{2+}$ 형광체를 대기 분위기 하에서 상온에서부터 $700^{\circ}C$까지 열처리하였을 때 PL의 변화는 없었으나, $700^{\circ}C$ 이상의 온도에서 열처리 하였을 때는 PL의 감소를 나타내었다. $700^{\circ}C$까지 PL의 안정된 거동을 보이는 것은 구조적으로 안정된 12 면체를 하고 있는 $Ca^{2+}$ 이온의 일부를 $Eu^{2+}$ 이온이 점유하고 있어 $Eu^{2+}$의 원자가 변화에 영향을 미치지 못했으나, $700^{\circ}C$이상의 PL의 감소는 $Eu^{2+}$에서 $Eu^{3+}$의 산화에 의한 것이라는 것을 EPR 흡수세기의 변화로부터 알 수 있었다.

• 한국세라믹학회지
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• 제44권5호
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• pp.155-159
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• 2007

Blue light-emitting phosphors having the excitation spectrum range of the medium-long ultraviolet ($280nm{\sim}400nm$) have been prepared by solid state reaction method. As a starting material the natural alkaline feldspar powder produced from the domestic mine field in Buyeo, Chungnam-do. The photoluminescence characteristics and crystal structures have been analyzed for the phosphor samples. The powder mixture of the natural alkaline feldspar and the rare-earth oxide was calcined at $800{\sim}1000^{\circ}C\;for\;3{\sim}4h$ in air. The calcined samples we fully ground at room temperature and then heat-treated in the mild reducing gas atmosphere of $5%H_2-95%N_2$ mixture at $1100{\sim}1150^{\circ}C\;for\;3{\sim}4h$. The natural alkaline feldspar material consists of the monoclinic orthoclase ($KAlSi_3O_8$) and the triclinic albite ($NaAlSi_3O_8$) phases. At the $0.5wt%Eu_2O_3$ addition the PL spectrum showed the maximum intensity and with further increase of $Eu_2O_3$ the PL intensity decreased. The albite phase disappeared in the $Eu_2O_3$ doped phosphors. The effect of the co-doped activator on the PL characteristics have been also discussed.

• Journal of Advanced Marine Engineering and Technology
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• 제39권4호
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• pp.473-477
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• 2015

본 논문에서는 인광물질을 포함하는 조명용 백색 LED를 이용한 가시광 통신 시스템의 변조 대역폭을 늘리기 위한 등화기를 설계하고 실험적으로 결과를 보였다. 등화기의 성능을 분석하기 위한 해석적 방법으로 회로 시뮬레이터인 PSpice를 이용하였다. 등화기는 저항과 커패시터를 이용한 수동필터와 증폭기를 이용한 능동필터의 조합으로 구성하였다. 등화기를 수신단에 적용함으로써 3.5 MHz 부근의 인광성 백색 LED 변조 대역폭이 청색 광학필터를 사용하지 않고도 25 MHz 까지 확장되었다. 상용화된 라운드형 백색 LED 1개와 PIN형 광 다이오드 1개를 이용하여 구현한 가시광 통신 시스템에서 진폭편이변조 방식으로 변조된 LED의 가시광 신호는 1미터 거리에서 35 Mbit/s 데이터 전송률을 보였다. 이때의 비트 에러율은 $7.6{\times}10^{-4}$이었으며 이는 순방향 오류 정정의 한계인 $3.8{\times}10^{-3}$ 이하를 만족하였다.