• Membrane Journal
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• v.20 no.1
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• pp.8-12
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• 2010

Poly(3,4-ethylenedioxythiophene) (PEDOT), which has the highest stability in conducting polymer was employed to electrochromic (EC) film and studied about electrochromic properties according to the film fabrication method. PEDOT films were coated by two different methods, electropolymerization (EP) and vapor phase polymerization (VPP). Both of PEDOT films showed dark blue color at dedoped neutral state. Spectroelectrochemistry, switching ability and stability of the devices were investigated by UV-Vis Spectrophotometer and Cyclic voltammetry. Surface morphologies of the PEDOT VPP film at oxidized and reduced state were obtained by AFM. The average surface roughness of the PEDOT-VPP film was 50 nm and more homogeneous than that of the PEDOT-EP. The EC property from the PEDOT-VPP film was improved compared to that of the PEDOT-EP film, to show a response time of 1.5 sec, transmittancechange of 49%, and coloration efficiency of 402.

• Asia-Pacific Journal of Business Venturing and Entrepreneurship
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• v.7 no.2
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• pp.77-90
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• 2012

As the influence of service industry into domestic economy is increasing, it also has been influenced more powerfully at the domestic GDP(Gross Domestic Product) relative importance and employment relative importance continuously. By means of these reason, the Korean government announced the synthetic countermeasure for strengthening the competitive power of service industry in December, 2006. After then, it announced phase I of 'service industry advancing plan' which is concrete execution plan in April, 2008. Also, it is announced to announce phase II plans in september, 2008 and phase III plan in December, 2008 additionally. Service quality is the most powerful competitive means at service marketing and a key point for improving service productivity. The improvement of service quality has considerable influence on survival and profitability of service industry. Therefore, the study of objective service quality measurement in service industry is very important issue. The purpose of this study is to suggest a measurement model of service quality using fuzzy theory and AHP which measuring service quality objectively in subjective environment. It is expected that this study will help the improvement of competition power of service industry as well as establishment of effective decision-making.

• International Journal of Oral Biology
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• v.46 no.3
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• pp.105-110
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• 2021

The physicochemical properties of crystalline titanium dioxide nanoparticles (TiO₂ NPs) were investigated by comparing amorphous (amTiO₂), anatase (aTiO₂), metaphase of anatase-rutile (arTiO₂), and rutile (rTiO₂) NPs, which were prepared at various calcination temperatures (100℃, 400℃, 600℃, and 900℃). X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses confirmed that the phase-transformed TiO₂ had the characteristic features of crystallinity and average size. The surface chemical properties of the crystalline phases were different in the spectral analysis. As anatase transformed to the rutile phase, the band of the hydroxyl group at 3,600-3,100 cm^-1 decreased gradually, as assessed using Fourier transform infrared spectroscopy (FT-IR). For ultraviolet-visible (UV-Vis) spectra, the maximum absorbance of anatase TiO₂ NPs at 309 nm was blue-shifted to 290 nm at the rutile phase with reduced absorbance. Under the electric field of capillary electrophoresis (CE), TiO₂ NPs in anatase migrated and detected as a broaden peak, whereas the rutile NPs did not. In addition, anatase showed the highest photocatalytic activity in an UV-irradiated dye degradation assay in the following order: aTiO₂ > arTiO₂ > rTiO₂. Overall, the phases of TiO₂ NPs showed characteristic physicochemical properties regarding size, surface chemical properties, UV absorbance, CE migration, and photocatalytic activity.

• Korean Journal of Materials Research
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• v.12 no.11
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• pp.840-844
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• 2002

A spherical $BaMgAl_{10}$ $O_{17}$ :Eu phosphor has been synthesized by a multi-step precipitation route. In order to successfully synthesize the phosphor with spherical shape, the hydrated-alumina particles should be controlled for spherical shape. In this process, the hydroxypropyl cellulose (HPC) was used as a dispersing reagent. This reagent plays an important role in that the particles were controlled to have the uniform size of sub-micron. The final product prepared by the multi-step precipitation method maintained spherical shape with uniform size of 0.4$\mu\textrm{m}$. It can be seen in X-ray diffraction patterns, formation of the single phase of $BaMgAl_{10}$ $O_{17}$ :Eu phosphor prepared by the multi-step precipitation method at $1350^{\circ}C$. Also, the emission spectra of spherical $BaMgAl_{O}$ $10_{17}$ :Eu phosphor in the present case was compared with those of commercially-available blue phosphor under VUV (Vacuum Ultra Violet) excitation. The luminescence process of the $BaMgAl_{10}$ $O_{17}$ :Eu phosphor is characterized by the $4f^{6}$$5d^1$longrightarrow4f$^{7}$ transition (blue) of the $Eu^{2+}$ ion acting as an activating center and the maximum luminescence intensity was obtained by reduction treatment at 145$0^{\circ}C$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.295-296
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• 2009

There are various application of liquid crystal materials to devices, especially, blue phase liquid crystal (BPLC) and nano-structured liquid crystal mixture have been studied recently because BPs existing temperature range has been expanded by polymer-stabilization and liquid crystal has been confined in room which has certain coherence length so that their particular characters, such as fast response time and optically isotropic state at no electric field, could apply to advanced liquid crystal display devices. However, there is an crucial problem which is high operating voltage from low Kerr constant and limited electric field utilization using in-plain electric field. In this paper, we will analyze cell structure in the way of using electric field and show effective electric field utilization to reduce operating voltage.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.19 no.2
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• pp.90-94
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• 2009

Mong Hsu rubies from Myanmar were heat treated in oxidizing(oxygen) atmosphere at $1650^{\circ}C$ for 1 hour. The investigations of the micro-structural defects in the samples before and after heat treatment have been carried out by the variety of analysis techniques of FTIR, UV-VIS-NIR and SEM-EDS. It was found that after heat treatment the dark blue cores region were disappeared and turned to orange red color with the presence of the dense cloudy brownish colored tiny particles in and near former blue zoning. As-received ruby samples only revealed the presence of FTIR absorption peaks of diaspore, boehmite and O-H stretching, at 1986, 2115 and $3078/3319\;cm^{-1}$ respectively. The UV-VIS-NIR absorption of as-received and heat treated ruby samples similarly showed peaks at 405, 554 and 693 nm associated with $Cr^{3+}$, but for the same samples, the absorption peak of heat-treated ruby samples at 693 nm was somewhat stronger than that of the untreated ruby samples. Especially the presence of $Cr^{3+}$ peaks at 659 and 675 nm was found obviously in as-received ruby samples only. The SEM-EDS investigation disclosed the micro-porous defect structures commonly related to the core regions of the untreated ruby samples, which after heat treatment in an oxidizing environment those defect features have been dissolved into the host phase resulting in the lightening or disappearance of the dark coloration of ruby core.

• Transactions of the Korean Society of Automotive Engineers
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• v.20 no.4
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• pp.125-132
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• 2012

Urea-SCR system, which converts nitrogen oxides to nitrogen and water in the presence of a reducing agent, usually AdBlue urea solution, is known as one of the powerful NOx reduction systems for mobile as well as stationary applications. For its consistent and reliable operation in mobile applications, such various problems as transient injection, ammonia slip, and freezing in cold weather have to be resolved. In this work, therefore, numerical study on three-dimensional unsteady heating problems were analyzed to understand the melting and heat transfer characteristics such as urea liquid volume fraction, temperature profiles and generated natural convection behavior in urea solution by using the commercial software Fluent 6.3. After validating by comparing numerical and experimental data with pure gallium melting phenomena, numerical experiment for urea melting is conducted with three different coolant heating models named CH1, 2, and 3, respectively. Finally, it can be found that the CH3 model, in which more coolant is concentrated on the lower part of the urea tank, has relatively better melting capability than others in terms of urea quantity of $1{\ell}$ for start-up schedule.

• Journal of the Korean Ceramic Society
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• v.45 no.12
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• pp.821-826
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• 2008

Nanocrystallized glasses with the composition of $(50-x)BaO-xTiO_2-50SiO_2$ (x=10, 15, 16.7 and 20) have been prepared by heat-treatment at $T_x$ (crystallization onset temperature) for 3 h, and their optical properties, photoluminescence (PL), XRD and Raman spectra have been examined. The absorption edges of the glasses were red-shifted and the absorption coefficient increased with an increase of $TiO_2$. The glass subjected to the heat-treatment showed a dense formation of ${Ba_2}{TiSi_2}{O_8}$ crystals. The XRD and Raman results show that the nanocrystallized glasses formed fresnoite phase up to $TiO_2$ concentrations of 15 mol%. Further-more, blue luminescence with a peak at the wavelength of around 470nm was observed in the nanocrystallized glass, demon strating the optical multifunctional nanocrystallized material such as non-linear optics and photo-luminescence. It is thought that the blue luminescence from the ${Ba_2}{TiSi_2}{O_8}$ nanocrystallized glass originated from the presence of $Ti^{4+}$ incorporated into the fresnoite-type structure.

• Journal of Powder Materials
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• v.24 no.6
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• pp.477-482
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• 2017

Nitrogen-doped titanium dioxide (N-doped $TiO_2$) is attracting continuously increasing attention as a material for environmental photocatalysis. The N-atoms can occupy both interstitial and substitutional positions in the solid, with some evidence of a preference for interstitial sites. In this study, N-doped $TiO_2$ is prepared by the sol-gel method using $NH_4OH$ and $NH_4Cl$ as N ion doping agents, and the physical and photocatalytic properties with changes in the synthesis temperature and amount of agent are analyzed. The photocatalytic activities of the N-doped $TiO_2$ samples are evaluated based on the decomposition of methylene blue (MB) under visible-light irradiation. The addition of 5 wt% $NH_4Cl$ produces the best physical properties. As per the UV-vis analysis results, the N-doped $TiO_2$ exhibits a higher visible-light activity than the undoped $TiO_2$. The wavelength of the N-doped $TiO_2$ shifts to the visible-light region up to 412 nm. In addition, this sample shows MB removal of approximately 81%, with the whiteness increasing to +97 when the synthesis temperature is $600^{\circ}C$. The coloration and phase structure of the N-doped $TiO_2$ are characterized in detail using UV-vis, CIE Lab color parameter measurements, and powder X-ray diffraction (XRD).

• Analytical Science and Technology
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• v.23 no.3
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• pp.225-232
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• 2010

In present study, a conventional sol-gel method was used to prepare Fe-ACF/$TiO_2$ composites, a kind of composite photocatalysts, whose capability was evaluated by degrading methylene blue (MB) solution. The particle size, surface structure, crystal phase and elemental identification of the composites prepared were characterized by BET, SEM, XRD and EDX, respectively. The spectra of MB concentration degraded under visible light were obtained by UV/Vis spectrophotometer. These obtained spectra demonstrated the photocaltalytic activity from removal concentrations of MB. It was considered that these photonic activities are induced by a strong synergetic reaction among ACF, $TiO_2$ and Fe in the composite photocatalysts under visible light.