• Title/Summary/Keyword: Blends

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A Study on the One Bath Two Step Dyeing of Wool/Cationized Cotton Blends With Acid Dye/Direct Dye (양모/카티온화 면 혼방품의 산성염료/직접염료에 의한 1욕2단 염색에 관한 연구)

  • Sung, Woo-Kyung;Lee, Choon-Gil
    • Fashion & Textile Research Journal
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    • v.3 no.2
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    • pp.168-173
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    • 2001
  • In order to overcome the disadvantage of the conventional two bath dyeing method of wool/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish savings in energy, water usage and time. To improve the dyeability of cotton toward direct dyes in a non-electrolytic and acidic dyebath, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate almost equal color strength between wool component and cationized cotton component when wool/cationized cotton blends was dyed with acid dye/direct dye by the one bath two step method in a non-electrolytic and acidic dyebath.

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Properties of Polyaniline Blends (폴리아닐린 블렌드의 물성)

  • Kim, Dong-Hyun;Lee, Tae-Hee;Kim, Jong-Eun;Suh, Kwang-S.
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1428-1430
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    • 2002
  • Polyaniline/polystyrene conducting blends were prepared and measured with the mechanical properties such as tensile strength and elongation and the electrcal properties such as surface resistance, electrical conductivity and dielectric loss tangent. The percolation threshold concentration of blends was 5phr of polyaniline and the morphology of blends was setting colser to that of polyaniline at higher concentration. The dielectric loss increased up to $10^5$ at the 50 % of polyaniline and was much influenced by frequency than temperature at higher concentration of polyaniline.

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The rheological behavior of collagen dispersion/poly(vinyl alcohol) blends

  • Lai, Guoli;Du, Zongliang;Li, Guoying
    • Korea-Australia Rheology Journal
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    • v.19 no.2
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    • pp.81-88
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    • 2007
  • Blends of collagen dispersion (COL) with poly(vinyl alcohol) (PVA) in different weight ratios were investigated by oscillatory rheometry, Fourier transform-infrared spectroscopy and scanning electron microscopy. It was found that even with 80% of PVA, the COL/PVA blends behaved more like collagen dispersion than pure PVA solution in the dynamic thermal and frequency processing, for instance, a dominant elastic appearance (G'>G"), a similar shear thinning behavior and the thermal denaturation below $40^{\circ}C$. However, influence on the blend behaviour by PVA was noticeable, for instance, an increase of dynamic denaturation temperature, the decreasing intensity of amide I, II and III bands as well as the diminishing irregular pores on the surface of blends. The interaction between collagen and PVA could be observed, especially at the regions with low content or high content of PVA.

Dyeing properties of Nylon/Spandex blends with vat dye (배트염료에 의한 나일론/스판덱스 교직물의 염착특성)

  • Park, Young-Min;Kim, Byung-Soon;Son, Young-A
    • Textile Coloration and Finishing
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    • v.18 no.6 s.91
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    • pp.63-68
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    • 2006
  • In synthetic/spandex blends fibers, contents of the synthetic fiber by percentage is higher than those of spandex. Thus, the dyeing process of the blends fiber is mainly focused on the synthetic fiber, but not the spandex. In this study, we used several series of vat dyes for dyeing the nylon/spandex blend fabrics and their dyeing properties(fk value) were investigated at various reduction agents, temperatures, pH which have the potential for deep shade dyeing effects. The formamidinesulfinic acid were found to be effective to increase the fk values of the blend fiber compared to sodium hydrosulfite and Rongalit C. Higher temperature($100^{\circ}C$) and lower pH(pH 4) were observed as suitable conditions for maximum fk values.

Fluorescence Characterization of LaRC PETI-5, BMI, and LaRC PETI-5/BMI Blends

  • Cho, Donghwan;Yang, Gyeongmo
    • Fibers and Polymers
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    • v.3 no.2
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    • pp.60-67
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    • 2002
  • In the present study, the fluorescence behavior ova phenylethynyl-terminated imide (LaRC PETI-5) resin, a bismaleimide (BMI) resin, and various LaRC PETI-5/BMI blends with different blend compositions has been characterized as a function of heat-treatment temperature, using a steady-state fluorescence technique with a front-face illumination method far solid-state films. It is observed that there are distinguishable changes in the spectral shape, size, and position of fluorescence with varying heat-treatment temperature in the pure and blend samples. The result is qualitatively explained in terms of charge transfer complex formation as well as microenvironmental change with local mobility and viscosity occurring in the LaRC PETI-5, BMI, and their blends during the cure process. The result also implies that a steady-state fluorescence technique may be a useful tool to understand the processing conditions of polyimides and their blends in the film form on the basis of their thermo-photophysical responses.

Thermodynamic Characteristics of Blends Involving Polycarbonates and Various Polymethacrylates (폴리카보네이트들과 다양한 종류의 폴리메타아크릴레이트 블렌드의 열역학적 특성에 관한 연구)

  • 김주헌;박동식;김창근
    • Polymer(Korea)
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    • v.24 no.5
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    • pp.682-689
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    • 2000
  • The information related to the interaction energy between repeat units is essential for the production of useful polymer blends via molecular structure design. Based on the interaction energies obtained here, a method for the fabrication of miscible blend was suggested. An investigation related to the equilibrium phase behavior of polymer blends of various polycarbonates with various polymethacrylates was performed and then based on the obtained interaction information miscible polymer blends were produced by controling molecular structure of polymer. Binary interaction energies between repeat units were calculated from the lower critical solution temperature-type phase boundary using an equation of state combined with binary interaction model.

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Structure -Properties Relations of Polypropylene/ Liquid Crystalline Polymer Blends

  • Sahoo, N.G.;Das, C.K.;Jeong, Hye-Won;Ha, Chang-Sik
    • Macromolecular Research
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    • v.11 no.4
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    • pp.224-230
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    • 2003
  • The blends of polypropylene (PP) with glass filled thermotropic liquid crystalline polymer (LCP-g) have been prepared by melt mixing techniques at different blend ratios. The thermal, dynamic mechanical, crystalline and morphological characteristics of these blends were investigated. Higher percent crystallinity was observed for 10% level of LCP-g in the blend in comparison to that of other blend ratios. The thermal stability increased with LCP-g concentration in the blend with PP. The variation of storage modulus, stiffness and loss modulus as a function of blend ratios suggested the phase inversion at the 50% level of LCP-g in the blend. The scanning electron microscopy (SEM) photographs showed the creation of voids and destruction of the fiber structures during the dynamic mechanical measurements. Processing behavior of the blends depended on the fiber forming characteristics of LCP-g, which again varied with the molding temperatures.

A Kinetic Study of Thermal Degradations of Chitosan/Polycaprolactam Blends

  • Liao, Shen-Kun;Hung, Chi-Chih;Lim, Ming-Fung
    • Macromolecular Research
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    • v.12 no.5
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    • pp.466-473
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    • 2004
  • We have used FT-IR spectra to explain the effects of hydrogen bonding between chitosan and polycaprolactam (PA6). A dynamic mechanical analysis study suggested that the optimum chitosan and PA6 miscibility under the conditions of this experiment were obtained at a blending ratio of 40:60. We studied the thermal degradation of chitosan blended with PA6 (chitosan/PA6) by thermogravimetric analysis and kinetic analysis (by the Ozawa method). Dry chitosan and PA6 exhibited a single stage of thermal degradation and chitosan/PA6 blends having> 20 wt% PA6 exhibited at least two stages of degradation. In chitosan/PA6 blends, chitosan underwent the first stage of thermal degradation; the second stage proceeded at a temperature lower than that of PA6, because the decomposition product of chitosan accelerated the degradation of PA6. The activation energies of the blends were between 130 and 165 kJ/mol, which are also lower than that of PA6.

Studies on the Physical Properties and Application of EPDM-Polymer Blends. Part 4. Physical Properties for EPDM-NBR Blends (EPDM과 각종(各種)Polymer의 Blend에 의(依)한 성능변화(性能變化) 및 그 응용(應用)에 관(關)한 연구(硏究)(제4보(第4報)) EPDM과 Acrylonitrile-Butadiene Rubber의 Blend에 대(對)하여)

  • Kim, Joon-Soo
    • Elastomers and Composites
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    • v.7 no.1
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    • pp.45-52
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    • 1972
  • As a series of the studies of EPDM-Polymer blends, the experiments are concentracted to the investigation of the physical properties of the EPDM-NBR blends. The results are shown as follows; 1. As EPDM addition ratio is increased, the physical properties such as resistance to ozone and aging have also improved, on the other hand, elongation and abrasion resistance decreased. 2. Tear strength is less influenced by blending and character after aging exhibited the same result. 3. Tensile strength decreased with increase in EPDM contents, especially the ratio of EPDM/NBR are 50/50 and 75/25.

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Studies on the Physical Properties and Application of EPDM-Polymer Blends. Part 6. Physical Properties for EPDM-NR-SBR Blends (EPDM과 각종(各種) Polymer의 Blend에 의(依)한 성능변화(性能變化) 및 그 응용(應用)에 관(關)한 연구(硏究)(제6보(第6報)) EPDM과 Natural Rubber 및 Butadiene-Styrene Rubber의 Blend에 대(對)하여)

  • Kim, Joon-Soo
    • Elastomers and Composites
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    • v.7 no.2
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    • pp.183-192
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    • 1972
  • As a series of tile studies of EPDM-Polymer blends, tile experiment are concentrated to the investigation of the physical properties of tile EPDM-NR-SBR blends. The results are shown as follows: 1. In blending, tensile strength decreased with increase in EPDM contents, especially the ratio of EPDM/NR-SBR is 75/25. 2. Elongation and tear strength were much influenced by blending, especially the ratio of EPDM/NR-SBR is 50/50. 3. Ozone resistance is much improved after blending. It was effective more than tile ratio of EPDM/NR-SBR is 25/75. 4. Aging resistance is much improved after blending. It was effective more than the ratio of EPDM/NR-SBR is 50/50. 5. Hardness increased with increase in EPDM contents and on the other hand, abrasion resistance decreased.

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