• Title/Summary/Keyword: Blending Surface

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Study on Manufacturing and Characteristics of Silicone/EPDM Rubber Blend (실리콘/EPDM고무 블렌드의 제조와 특성에 관한 연구)

  • 김진국;이형규
    • Polymer(Korea)
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    • v.25 no.3
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    • pp.406-413
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    • 2001
  • Blending has become an interesting way for preparing new materials with tailored properties. Unfortunately, many materials are incompatible due to the difference in their viscoelastic properties, surface energy and interaction. Therefore, the properties of polymer blends are not obtained as expected levels. Silicone rubber has an excellent heat-resistance and electrical characteristics, and ethylene propylene diene monomer (EPDM) rubber also has good mechanical properties. The purpose of this study is to develop a new engineering material which has excellent electrical and mechanical properties through blending of silicone with EPDM rubber.

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Studies on the Application and Characteristics of IR for Footwear (IR 고무의 특성(特性) 및 고무화류(靴類)에 활용(活用)하는데 관(關)한 연구(硏究))

  • Kwak, Byung-Kil
    • Elastomers and Composites
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    • v.9 no.1
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    • pp.5-13
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    • 1974
  • The characteristics of IR and IR blended elastomers, for footwear by means of blending with NR and SBR, have been studied. The results obtained were as follows: 1. The mastication of IR was almost not required, where as NR and SBR are necessary. Therefore mixing time was much reduced because of speedy filler feeding. 2. Disadvantage of low Mooney viscosity was covered by blending with NR and SBR, and by loading filler. Superior flow property in comparison to other polymers was worthy and valuable in providing formulas for mould flow, 3. The elongation property of green stocks and vulcanizates was shown smooth surface for extruded and calendered stocks, and facilitated fabrication processes. 4. Because of slow vulcanization, IR is required to control vulcanization time by adding proper accelerators. This property, in turn, made possible to improve the storing stability of green stocks by controlling scorch time.

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The Effects of Surface-Modified Pigment on the Properties of Coated Paper (표면 개질된 도공안료가 도공지의 특성에 미치는 영향)

  • 이희명;민동진;이용규;조준형;김용식
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.3
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    • pp.13-20
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    • 2003
  • This study was carried out to investigate the effect of surface modified pigments on the properties of coated paper. The selected core particle(clay, talc) and fine particle(TiO$_2$) were modified by hybridization. The optical properties of modified pigments, rheological properties of coating color, and optical properties of coated paper were investigated. It was found that particles formed sphere-like shape and became more uniform during the surface modification in the hybridization system. As a result, It was estimated that surface modification of TiO$_2$ turned out to be more effective in improving optical properties of pigment and coated paper than simply blending it.

Surface Modeling of Forebody's Hull Form Using Form Parameters and Fair-Skinning (형상 파라메터와 평활화 스키닝을 이용한 선수 선형 곡면 모델링)

  • Kim, Hyun-Cheol;HwangBo, Seung-Myun
    • Journal of the Society of Naval Architects of Korea
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    • v.45 no.6
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    • pp.601-610
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    • 2008
  • This paper deals with a new geometrical surface modeling method of forebody's hull form which is fully defined by form parameters. The complex hull form in the forebody can be modeled by the combination of three parts: bare hull, bulbous bow and blending part which connects a bare hull and a bulbous bow. All these subdomain parts are characterized by each own form parameters and constructed with simple surface model. For this, we need only 2-dimensional hull form data and then the form parameters are calculated automatically from these data. Finally, the smooth hull form surfaces are generated by parametric design and fair-skinning. In the practical point of view, we show that this new method can be useful and efficient modeling tool by applying to the hull form surface modeling of Panamax container's forebody.

Control of Catalytic Properties of Heteropoly Acid by Blending it with a Polymer (고분자와의 블랜딩에 의한 헤테로폴리산의 촉매 특성 제어)

  • Song, In Kyu;Lee, Jong Koog;Lee, Wha Young
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.819-824
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    • 1994
  • A membrane-like $H_3PMo_{12}O_{40}$-polysulfone film was prepared by blending $H_3PMo_{12}O_{40}$ with polysulfone using dimethylformamide as a common solvent. SEM and EDX analysis showed that $H_3PMo_{12}O_{40}$ was uniformly and finely distributed in the film catalyst. The ESCA measurement also revealed that the oxidation state of Mo was not changed. The $H_3PMo_{12}O_{40}$-polysulfone catalyst showed lower activity for acid-catalyzed reaction and higher activity for oxidation reaction than $H_3PMo_{12}O_{40}$ in ethanol conversion reaction. The oxidation activity of the film catalyst was about 10 times higher than $H_3PMo_{12}O_{40}$. The decrease of acidic activity was due to DMF strongly adsorbed in acid sites of $H_3PMo_{12}O_{40}$, whereas the increase of oxidation activity was mainly due to uniform distribution of $H_3PMo_{12}O_{40}$. Adsorption results showed that the surface character of $H_3PMo_{12}O_{40}$ was drastically increased, while the bulk property of that was almost same after blending. It is suggested that the control of surface/bulk property as well as acid/redox property of heteropoly acid would be possible by blending it with a polymer.

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Use of Response Surface Methodology for Optimization of Clarified Mixed Apple and Carrot Juice Production (반응표면 분석을 이용한 사과.당근 혼합주스의 청징공정 최적화)

  • Seog, Eun-Ju;Lee, Jun-Ho
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.8
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    • pp.1051-1056
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    • 2006
  • Response surface methodology was used to investigate the quality of clarified mixed apple and carrot juices using ultrafitration. Apple and carrot juices were blended at the ratio of 1:3, 1:1, and 3:1. A three-variable, three-level central composite design was employed where the independent variables were the blend ratio, temperature and average transmembrane pressure (ATP). With increasing temperature and pressure, flux linearly increased regardless of blending ratio. Blend juice with 75% apple showed the highest soluble sugar and total sugar content in apple and carrot blend juices. Soluble solid contents were more affected by blending ratio than temperature and ATP. Total sugar contents were greatly affected by temperature; increasing temperature led to higher total sugar content up to $25^{\circ}C$. Higher carrot ratio led to higher vitamin C content. In general, higher acidity was achieved by higher apple content and acidity was increased with increasing temperature. Turbidity increased for all samples as APT increased, with the blending ratio of 1:1 (apple:carrot) showing the highest turbidity. Viscosity was greatly changed in the blending ratio of 3:1 (apple:carrot) juice. The polynomial models developed by RSM were satisfactory to describe the relationships between the studied factors and the responses. Analytical optimization gave $flux=0.216\;L/m^2.h$, soluble $solids=10.39^{\circ}Brix$, total sugar=71.32 mg/mL, vitamin C=315.18 mg%, acidity=7.78 mL, turbidity=0.017, and viscosity=1.44 cp, when using a $temperature=44.97^{\circ}C$, ATP=113.57 kPa, and blend ratio=28.50%.

Hydrophobisity Recovery of PDMS Blended with Fluorinated Silicone Rubber Using Dynamic Contact Angle Measurement (동적 접촉각 측정을 이용한 실리콘고무 블렌드의 발수성회복 검토)

  • Lee, C.R.;Ryu, S.S.;Homma, H.;Izumi, K.
    • Proceedings of the KIEE Conference
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    • 2001.11a
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    • pp.6-8
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    • 2001
  • This report describes the effect of the blending of poly(trifluoropropylmethylvinylsiloxane) (PTFPMVS) with poly(dimethylsiloxane) (PDMS) on the surface properties such as water repellency using dynamic contact angle (DCA) measurement. We have investigated the surface molecular mobility of the PDMS/PTFPMVS blends via a DCA measurement and an adhesion tension relaxation. It could be shown that a flexible side-chain segment in PTFPMVS having higher surface energy, could be reoriented easily in water to decrease the interfacial tension of the polymer/water interface, which seems to play a major role at the decrease of the receding contact angle and the surface resistivity of PDMS/PTFPMVS blends.

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Synthesis and Adhesion Properties of Waterborne Polyurethane Adhesives for Footwear according to Polyol Blending

  • Choi, Min Ji;Jeong, Boo Young;Cheon, Jung Mi;Chun, Jae Hwan
    • Elastomers and Composites
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    • v.52 no.1
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    • pp.81-85
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    • 2017
  • In order to improve the water resistance, we synthesized waterborne polyurethane by using polyester polyol, poly(propylene carbonate) (PPC), 4,4'-dicyclohexylmethane diisocyanate ($H_{12}MDI$), and dimethylolpropionic acid (DMPA). The properties of the synthesized waterborne polyurethane using poly(propylene carbonate) (WPUP) were evaluated by FT-IR, $^1H-NMR$, GPC, DSC, TGA, and UTM. The mechanical properties increased while the adhesion properties decreased with the increase in the amount of PPC. The highest water resistance was shown when the ratio of polyester polyol to PPC was 9:1.

Influence of Organic Pigment Blending on Surface and Optical Properties of Coated Paper (유기안료 배합이 도공층의 표면 및 광학적 특성에 미치는 영향)

  • Jeong, Kyoung-Mo;Won, Jong-Myoung;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.3
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    • pp.1-8
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    • 2012
  • The effects of several factors including organic pigment blending and calending conditions on the surface and optical properties of coated paper were investigated. When clay and calcium carbonate are blended in the ratio of 7 to 3, highest smoothness and relative sediment volume were obtained. When organic pigments were added to the mixture of clay and calcium carbonate, the relative sediment volume did not changed significantly. However, when organic pigments were added to calcium carbonate, sheet gloss and smoothness were improved, and showed the better results than that obtained from the mixture of organic pigment and clay. When organic pigment is blended with clay, the particles of organic pigment are buried in the packing structure of coating layer. However, the particle shape of calcium carbonate is quite different from that of clay, and the aspect ratio of calcium carbonate is similar to that of organic pigment. Thus organic pigment particles are not buried and improved effectively the physical characteristics of coating layer. When the hollow sphere pigment was blended, opacity and sheet gloss were improved significantly. Even though the coating color applied was reduced, the similar level of opacity was maintained. Also, if particle size and void volume are increased, gloss is improved, because coating layer is easily transformed in calendering. Therefore, even though lower pressure was applied during calendering, the smoothness of surface of coating layer was improved, and the decrease of void volume in coating layer was reduced, and the quality of coated sheet can be improved.

A Study on the Development of Eco-friendly Materials Using EPDM Scrap : Functionalization of EPDM and PP (에틸렌-프로필렌 고무 스크랩을 이용한 친환경소재 개발에 관한 연구 : EPDM과 PP의 기능화)

  • Kim, Sub;Chung, Kyung-Ho
    • Clean Technology
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    • v.15 no.3
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    • pp.180-185
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    • 2009
  • The ethylene-propylene rubber (EPDM) scrap generated from automobile weatherstrip manufacturing process was used to make a thermoplastic elastomer through blending with polypropylene. The surface activated EPDM powder was obtained by the high temperature and shear pulverizer. The addition of surfactant resulted in more surface activated EPDM powder and the optimum loading amounts of surfactant was 1.5 phr. Maleic anhydride was grafted onto polypropylene by reactive blending to give functionalized polypropylene. The wetting property between EPDM scrap and polypropylene was improved by the addition of poly (ethylene-co-acrylic acid) as a compatibilizing agent. Poly(ethylene-co-acrylic acid) decreased the surface tension of polypropylene and thus would contribute to the wettability with EPDM powder.