• Title/Summary/Keyword: Blending Surface

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Exploration of shockwaves on polymeric membrane physical properties and performance

  • Lakshmi, D. Shanthana;Saxena, Mayank;Ekambaram, Shivakarthik;Sivaraman, Bhalamurugan
    • Membrane and Water Treatment
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    • v.12 no.1
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    • pp.43-49
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    • 2021
  • The Commercial polymeric membranes like Polysulfone (PSF), Polyvinylidene difluoride (PVDF) and Polyacrylonitrile (PAN) which are an integral part of water purification investigation were chosen for the shockwave (SW) exposure experiment. These membranes were prepared by blending polymer (wt. %) / DMF (solvent) followed by phase-inversion casting technique. Shockwaves are generated by using Reddy Tube lab module (Table-top Shocktube) with range of pressure (1.5, 2.5 and 5 bar). Understanding the changes in membrane before and after shock wave treatment by parameters, i.e., pure water flux (PWF), rejection (%), porosity, surface roughness (AFM), morphology (SEM) and contact angle which can significantly affect the membrane's performance. Flux values PSf membranes shows increase, 465 (pristine) to 524 (1.5wt%) LMH at 50 Psi pressure and similar enhancement was observed at 100Psi (625 to 696 LMH). Porosity also shows improvement from 73.6% to 76.84% for 15wt% PSf membranes. It was observed that membranes made of polymers such as PAN and PSF (of high w/w %) exhibits some resistance against shockwaves impact and are stable compared to other membranes. Shockwave pressure of up to 1.5 bar was sufficient enough to change properties which are crucial for performance. Membranes exposed to a maximum pressure of 5 bar completely scratched the surface and with minimum pressure of 1.5bar is optimum enough to improve the water flux and other parameters. Initial results proved that SW may be suitable alternative route to minimize/control membrane fouling and improve efficiency.

Preparation of Water-Resistant Hydrophilic Coating Solutions for PET film (내수성이 우수한 PET 필름용 친수성 코팅액의 제조)

  • Lee, Soo
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.584-594
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    • 2014
  • To increase of surface hydrophilicity of polymeric thin films is an important approaching technique for introduction of self-cleaning and/or antifogging properties on the surfaces of those films. In general, hydrophilic surface can be produced by coating non ionic surfactants or by increasing surface energy. Various non-ionic surfactants, such as Tween, Span, and PEG-PPG block copolymers were selected for our experiments, because they are cheap and well soluble in toluene system as well as they contain several reactive hydroxy fuctional groups with coupling agents. Blending conditions influence the PET film surface hydrophilicities. However, the introduction of only these surfactants on the surface of PET films did not show the high durability of hydrophilic properties after washing with water. To improve the durability two types of coupling agents such as epoxide and diisocyanate were adopted. Contact angle of water on hydrophilically coated PET film surface with 6 wt% of isophrone diisocyanate(IPDI) containing coating solution was reached to $8.7^{\circ}$, which was an indirect evidence for very high surface hydrophilicity. A light(500 nm of wavelength) transmittance value of coated PET film was changed only from 87% to 85% with keeping a good transparent property. This film can be usable for self-cleaning film industries.

Electrochemical Properties of Activated Polyacrylonitrile/pitch Carbon Fibers Produced Using Electrospinning

  • Kim, Bo-Hye;Bui, Nhu-Ngoc;Yang, Kap-Seung;dela Cruz, Marilou E.;Ferraris, John P.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.9
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    • pp.1967-1972
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    • 2009
  • The electrospinnability of pitch was improved by blending in a solution of polyacrylonitrile (PAN) resulting in the reduction of the average fiber diameter from 2000 to 750 nm. Activated carbon fibers (ACFs) derived by stabilization, carbonization and steam activation at 700, 800, and 900 ${^{\circ}C}$ of the PAN/pitch electrospun fibers for 60 min were investigated as electrodes for supercapacitors. The Brunauer, Emmett, Teller (BET) specific surface area ranged from 732 to 1877 $m^2g^{-1}$ and the specific capacitance from 75.5 to 143.5 $Fg^{-1}$, depending on the activation conditions. Electrodes from the electrospun web activated at 900 ${^{\circ}C}$ exhibited a particularly quick response showing a high frequency of 5.5 Hz at a phase angle of ‒$45^o$ of the impedance spectroscopy.

Fitness and Physical Properties in Current Stretch Fabrics for Bottoms -Focused on the Tight Skirt- (하의용 시판 신축성 소재의 물리적 특성과 맞음새에 과한 연구 -스커트를 중심으로-)

  • 이진희;최혜선;도월희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.10
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    • pp.1467-1477
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    • 2002
  • This study was investigated physical properties of stretch fabrics by KES-FB system to show suitable basic data to making skirts of excellent capacity and develop more organized basic skirt pattern by fitness evaluation. 1. The results of T. H. V.(Total Hand Value) were as followa: In the kind of blending fiber, cotton/spandex was more excellent than nylon/spandex and polyester/spandex, in the direction of stretch, one-way(weft inserted polyurethan yarn) polyester/spandex and cotton/spandex were higher than two-way(warp and wet inserted polyurethan yarn) polyester/spandes and cotton/spandex, two-way nylon/spandex was higher than one-way nylon/spandex. 2. The results of calculating the variance between sample stretch fabrics and Japanese s/s women's suit fabrics after standardizing were as follows: Stretch fabrics has 2 range of tensile, bending, shearing, compression, surface, thickness and weight as compared with Jpanese s/s women's suit fabrics. In the tensile property, one-way stretch fabrics were almost the same with Japanese s/s women's suit fabrics, only two-way polyester/spandex had+1~+2 range. In the bending, shear property, there was no difference between sample fabrics and Japanese s/s women's suit fabrics 3. In the total fitness of the skirt, nylon/spandex is the best in the fabrics and one-way stretch fabric is better than two-way strethch fabric.

Study on Establishment of a Wind Map of the Korean Peninsula (I. Establishment of a Synoptic Wind Map Using Remote-Sensing Data) (한반도 바람지도 구축에 관한 연구 (I. 원격탐사자료에 의한 종관 바람지도 구축))

  • Kim Hyungoo;Choi Jaeou;Lee Hwawoon;Jung Woosik
    • New & Renewable Energy
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    • v.1 no.1 s.1
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    • pp.44-53
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    • 2005
  • To understand general status of the national wind environment and to distinguish potential areas to be developed as a largescale wind farm, a synoptic wind map of the Korean Peninsula is established by processing remote sensing data of the satellite, NASA QuikSCAT which Is deployed for the SeaWinds Project since 1999. According to the validation results obtained by comparing with the measurement data of marine buoys of KMA(Korea Meteorological Administration), the cross-correlation factor Is greatly Improved up to 0.87 by blending the sea-surface dat3 of QuikSCAT with NCEP/NCAR CDAS data. It is found from the established synoptic wind map that the wind speed in winter is prominent temporally and the South Sea shows high energy density up to the wind class 6 spatially. The reason is deduced that the northwest winds through the yellow Sea and the northeast winds through the East Sea derived by the low-pressure developed in Japan are accelerated passing through the Korea Channel and formed high wind energy region in the South Sea; the same trends are confirmed by the statistical analysis of meteorological observation data of KMA.

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A Study on Contextuality in Contemporary Arts (현재 조형예술의 정황성에 관한 연구)

  • Kang, Tai-Sung
    • The Journal of Art Theory & Practice
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    • no.6
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    • pp.7-25
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    • 2008
  • The following thesis has been composed with the inspiration attained from Paul Ardenne's conception on Contextual Art. In Europe and in the United States, there is a group of artists who emphasize in the importance of artist's participation in social, political, economical, environmental and moral issues. Since the 1960's, these artists have pondered on Modernism's ideas where art is contextually separated from humanly issues whereas the manners of such artists put on emphasis in the intent to participate in the real human social and ethical issues. Forerunner in this field of art such as Wolfgang Leib display hybrid or meta style in their work. His work displays a quadrilateral form of pollen which represents the simultaneous blending of two mixed ideas such as the abstract from the real. Thus heterogeneous style and philosophy which includes a range of medias and today's trend is observed in Contextual Art. Such art form is also found in landscapes where it is not seen as an observable object but rather an interactive object. It is correlated to Arte Povera of the Italian Art Movement, Support-Surface of the French Art Movement and lastly to the Fluxus. Through these art movements, we find a mutual antipathy towards putting art for sales in the capitalism market and reflect the social role of art in postmodern era.

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The Effect of MBS on the Compatibility of Scrap PVB/PMMA Blends (Scrap PVB/PMMA 블렌드에 미치는 MBS의 상용화효과(相溶化效果))

  • Choi, Hyeong-Ki;Lee, Yong-Moo;Yoon, Ju-Ho;Choi, Sei-Young
    • Elastomers and Composites
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    • v.31 no.1
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    • pp.23-32
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    • 1996
  • PVB was blended with PMMA in order to recycle scraped PVB material which recovered in the safety glass manufactories. The purpose of this research on PVB/PMMA blend was applied with excellent tackiness and transparency of PVB as a material of high strength to make the maximum use. Also, the blending of PVB with PMMA was aimed at the increase of impact strength of PMMA because the elastic property of PVB might decrease the brittleness of PMMA due to the lack of inner impact resistance. Izod impact resistance was propotional to increase the content of PVB, which was predominantly increased in the addition of 10phr above MBS. High rate impact resistance showed a tendency to Increase but it showed a tendency to decrease maximum load and energy if the contents of PVB increased. On the other hand total energy and ductile index showed a tendency to increase excellent impact resistance in the addition of MBS contents. As a result of observed surface of PVB/PMMA blends, the size of PVB domain increased distribution homogenuously, in the addited MBS contents increased it showed distribution homogeneously and partially a wetability.

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Crystallization and Melting Behavior of Silica Nanoparticles and Poly(ethylene 2,6-naphthalate) Hybrid Nanocomposites

  • Kim Jun-Young;Kim Seong-Hun;Kang Seong-Wook;Chang Jin-Hae;Ahn Seon-Hoon
    • Macromolecular Research
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    • v.14 no.2
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    • pp.146-154
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    • 2006
  • Organic and inorganic hybrid nanocomposites based on poly(ethylene 2,6-naphthalate) (PEN) and silica nanoparticles were prepared by a melt blending process. In particular, polymer nanocomposites consisting mostly of cheap conventional polyesters with very small quantities of inorganic nanoparticles are of great interest from an industrial perspective. The crystallization behavior of PEN/silica hybrid nanocomposites depended significantly on silica content and crystallization temperature. The activation energy of crystallization for PEN/silica hybrid nanocomposites was decreased by incorporating a small quantity of silica nanoparticles. Double melting behavior was observed in PEN/silica hybrid nanocomposites, and the equilibrium melting temperature decreased with increasing silica content. The fold surface free energy of PEN/silica hybrid nanocomposites decreased with increasing silica content. The work of chain folding (q) for PEN was estimated as $7.28{\times}10^{-20}J$ per molecular chain fold, while the q values for the PEN/silica 0.9 hybrid nanocomposite was $3.71{\times}10^{-20}J$, implying that the incorporation of silica nanoparticles lowers the work required to fold the polymer chains.

Spray Characteristics of Diesel Fuel with Oxygenates (함산소 물질이 혼합된 디젤연료의 분무특성)

  • Ryu, Keun-Young;Ha, Jong-Suk;No, Soo-Young
    • Journal of ILASS-Korea
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    • v.6 no.3
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    • pp.38-44
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    • 2001
  • The effect of four diesel fuels with oxygenated agents fuels on spray properties from plain-orifice atomizer was investigated. The oxygenates evaluated were diglyme, MTBE, DEE and DMM and were blended in weights of 5, 10, 15, 20 and 30% in a baseline diesel fuel. The physical properties such as surface tension, density and viscosity are also measured for each blended oxygenated fuels. It was found that changes in physical properties of fuels considered are enough to influence spray properties, i.e. spray angle, spray tip penetration and mean drop size. Spray properties were measured by PMAS(particle motion analysis system) which is employing a point measurement technology. Spray angle increased with increase in oxygenate content. The effect, however, was not great in the higher blend level. The oxygenated fuels produced more shorter spray tip penetration than diesel fuels. SMD was decreased with the increase in blending percent. SMD for DMM and DEE are represented 10.33 and 3.41% decreasing rates respectively. It was found that changes in spray characteristics of oxygenated fuel were easily large enough to impact pollutant emissions. It was clear from this study that spray characteristics of oxygenated fuel is one of possible cause of reducing pollutant emissions. It was clear from this study that spray characteristics of oxygenated fuel is one of possible cause of reducing pollutant emissions from diesel engines when oxygenated fuels is applied.

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Correlation of Microstructure and Tribological Properties of Mo Blended Fe-Base Coatings Fabricated by Atmospheric Plasma Spraying (대기 플라즈마 용사 공정에 의해 제조된 철계합금-몰리브덴 혼합 코팅층의 미세조직 및 내마모성)

  • Lee, Illjoo;Park, Hyungkwon;Lee, Changhee
    • Journal of Welding and Joining
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    • v.32 no.5
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    • pp.65-71
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    • 2014
  • Atmospheric plasma spraying (APS) is world-widely used process in the automotive industry as a method to provide wear resistance coatings for engine cylinder bore, using various materials. The weight of engine blocks can be considerably decreased by removing cast iron liners, which can finally result in the improvement of fuel efficiency. In this study, five kinds of powder materials, 1.2C steel powder and 1.2C steel powder mixed with 5, 10, 15, 20 wt.%. molybdenum powder, were deposited by atmospheric plasma spraying in order to investigate the effect of molybdenum on the wear resistance of coatings. Microstructural analysis showed that molybdenum splats were well distributed in 1.2C steel matrix with intimate bonding. The molybdenum added coatings showed better tribological properties than 1.2C steel coating. However, above the 15 wt.%. blending fraction, wear resistance was somewhat degraded with poor roughness of worn surface due to the brittle fracture occurred in molybdenum splats. Consequently, compared to conventional liner material, gray cast iron, 10 wt. pct. molybdenum blended 1.2C steel coating showed much better tribological properties and therefore it looks very feasible to replace gray cast iron liner.