• Computers and Concrete
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• v.13 no.1
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• pp.97-115
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• 2014

Silica fume is a by-product of induction arc furnaces and has long been used as a mineral admixture to produce high-strength, high-performance concrete. Due to the pozzolanic reaction between calcium hydroxide and silica fume, compared with that of Portland cement, the hydration of concrete containing silica fume is much more complex. In this paper, by considering the production of calcium hydroxide in cement hydration and its consumption in the pozzolanic reaction, a numerical model is proposed to simulate the hydration of concrete containing silica fume. The heat evolution rate of silica fume concrete is determined from the contribution of cement hydration and the pozzolanic reaction. Furthermore, the temperature distribution and temperature history in hardening blended concrete are evaluated based on the degree of hydration of the cement and the mineral admixtures. The proposed model is verified through experimental data on concrete with different water-to-cement ratios and mineral admixture substitution ratios.

• Architectural research
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• v.20 no.1
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• pp.27-34
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• 2018

To improve the chloride ingress resistance of concrete, slag is widely used as a mineral admixture in concrete industry. And currently, most of experimental investigations about non steady state diffusion tests of chloride penetration are started after four weeks standard curing of concrete. For slag blended concrete, during submerged chloride penetration tests periods, binder reaction proceeds continuously, and chloride diffusivity decreases. However, so far the dependence of chloride ingress on curing ages are not detailed considered. To address this disadvantage, this paper shows a numerical procedure to analyze simultaneously binder hydration reactions and chloride ion penetration process. First, using a slag blended cement hydration model, degree of reactions of binders, combined water, and capillary porosity of hardening blended concrete are determined. Second, the dependences of chloride diffusivity on capillary porosity of slag blended concrete are clarified. Third, by considering time dependent chloride diffusivity and surface chloride content, chloride penetration profiles in hardening concrete are calculated. The proposed prediction model is verified through chloride immersion penetration test results of concrete with different water to binder ratios and slag contents.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.10a
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• pp.131-134
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• 1999

Microstructure modification and electrochemical properties are investigate to estimate the effects of internal chlorides on the steel corrosion in the blended cement systems. According to the test results, slag cement system showed high chloride binding capacity and low corrosion rate. The impedance data showed three distince arcs from lowest(mHz) frequency to highest (MHz) frequency due to product layer, interfacial reaction and bulk matrix. Through the microstructural investigation, fine steel-matrix interface of slag cement system was observed but rough steel-matrix interface of OPC system was observed. Friedel's salt was thought that the substantial material contributed to the chloride binding of slag cement system.

• The Korean Journal of Ceramics
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• v.6 no.3
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• pp.286-290
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• 2000

The hydration behavior of fly ash and slag on cement paste were investigated. Early stage of hydration reaction was delayed by mixing fly ash and/or slag with cement, but production of C-S-H hydrates by pozzolanic reaction densified the microstructure. The Ca/Si ratio of C-S-H hydrates in OPC and blended cement of fly ash 50%, slag 50%, fly ash+slag 50% were 2.24, 1.80, 1.82 and 1.97, respectively. The C-S-H gel with low Ca/Si ratio showed rather reticulate than needle-like structure.

• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.3
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• pp.271-280
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• 2024

In this study, commercially available chemical activator was utilized as a grin din g agen t for bottom ash to develop bottom ash blended cement. The hydration characteristics of the bottom ash blended cement were analyzed using X-ray diffraction and thermogravimetric analysis. In particular, the PONKCS method was employed to quantify the amorphous C-S-H and bottom ash. The use of chemical activator delayed the hydration reaction of the cement and reduced the reactivity of the bottom ash. However, appropriate delay of hydration and enhanced reaction of aluminate successfully led to the formation of a substantial amount of monocarboaluminate. Consequently, the use of chemical activator greatly improved the compressive strength of the bottom ash blended cement, resulting in the 20240713development of high-performance bottom ash blended cement.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.1
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• pp.39-48
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• 2020

The present study investigates the chemical reaction and performance of ternary blended binders by mixing ferronickel slag. Cement was replaced using ground granulated blast furnace slag and ferronickel slag, combined up to 50% of the replacement rate. The blended cements were tested by setting times, length change, compressive strength at 1, 3, 7, 28 days. X-ray diffraction and scanning electron microscope were conducted for detecting hydration products while the MIP and microhydation heat were used for examining morphological characteristics. The results showed that by adding ferronickel slag, Pozzolanic reaction occurred, forming a dense pore structure and the effect of reducing hydration heat and dry shrinkage was also found. The compressive strength at 28 days was lower than that of 100% OPC control specimen (OSP0), but ternary blended cements showed no significant difference compared to binary blended (OSP50). If the optimal mix is derived later and used for the purpose, the potential for use as a cement binder is expected.

• Computers and Concrete
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• v.10 no.6
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• pp.649-662
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• 2012

This paper presents the results of an investigation on the compressive strength and weight loss of mortars containing three types of fillers as cement replacements; Limestone Filler (LF), Silica Fume (SF) and Trass (TR), subjected to elevated temperatures including $400^{\circ}C$, $600^{\circ}C$, $800^{\circ}C$ and $1000^{\circ}C$. Results indicate that addition of TR to blended cements, compared to SF addition, leads to higher compressive strength and lower weight loss at elevated temperatures. In order to model the influence of the different parameters on the compressive strength and the weight loss of specimens, artificial neural networks (ANNs) were adopted. Different diagrams were plotted based on the predictions of the most accurate networks to study the effects of temperature, different fillers and cement content on the target properties. In addition to the impressive RMSE and $R^2$ values of the best networks, the data used as the input for the prediction plots were chosen within the range of the data introduced to the networks in the training phase. Therefore, the prediction plots could be considered reliable to perform the parametric study.

• Computers and Concrete
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• v.17 no.2
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• pp.271-280
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• 2016

This study examined the mechanical properties and adiabatic temperature rise of low-heat concrete developed based on ternary blended cement using ASTM type IV (LHC) cement, ground fly ash (GFA) and limestone powder (LSP). To enhance reactivity of fly ash, especially at an early age, the grassy membrane was scratched through the additional vibrator milling process. The targeted 28-day strength of concrete was selected to be 42 MPa for application to high-strength mass concrete including nuclear plant structures. The concrete mixes prepared were cured under the isothermal conditions of $5^{\circ}C$, $20^{\circ}C$, and $40^{\circ}C$. Most concrete specimens gained a relatively high strength exceeding 10 MPa at an early age, achieving the targeted 28-day strength. All concrete specimens had higher moduli of elasticity and rupture than the predictions using ACI 318-11 equations, regardless of the curing temperature. The peak temperature rise and the ascending rate of the adiabatic temperature curve measured from the prepared concrete mixes were lower by 12% and 32%, respectively, in average than those of the control specimen made using 80% ordinary Portland cement and 20% conventional fly ash.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.10a
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• pp.127-130
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• 1999

Physical properties and microstructure of slag blended cement were investigated to evaluate the influence of sulphates and chlorides. The compressive strength developed as high chloride content dust and gypsum added and accordingly the microstructure modification was showed. The deviation of pore size distribution and hydrates was also observed. From these results we discussed optimum condition of gypsum and high chloride content dust leading to physical properties in this study.

• Journal of the Korea Concrete Institute
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• v.11 no.4
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• pp.21-29
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• 1999

In this study, an experiment was performed to analyze the influence of water-cement ratio on the fundamental characteristics of antiwashout underwater concrete using blended sand (sea sand:river sand = 1:1). The water-cement ratio (45%, 50%, 55%, 60%), andtiwashout underwater agent contents (0.82%, 1.00%, 1.14% of water contents per unit volume of concrete), and superplasticizer contents (1.5%, 2.0%, 2.5% of cement contents per unit volume of concrete) were chosen as the experimental parameters. The experimental results show that the underwater segregation resistance, unit weight of hardening concrete and compressive strength were increased as the water-cement ratio decreased and as the antiwashout underwater agent contents increased. On the other hand, the flowability(slump flow) was increased to the 55% of the increase of water-cement ratio, however, it was decreased at the ratio of 60%. From this study, the antiwashout underwater concrete can potentially be used as a materials underwater work of ocean if the water-cement ratio and chemical admixture contents for the suitable balance between cost and performance are properly selected.