• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.11
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• pp.876-885
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• 2009

Char oxidation experiments were performed with a sub-bituminous roto-middle coal in the Drop Tube Furnace (DTF) at atmospheric pressure condition. While temperatures varied between 900, 1100, 1400 $^{\circ}C$, particle size, mass, particle temperature, and CO/$CO_2$ concentration were obtained to be used for kinetic analysis of the char oxidation. This study addresses several different methods to analyze the char consumption rate, which are classified as energy balance method, ash-traced mass method, flue-gas based method, and particle size based method. The char consumption rate obtained with such methods was compared with the results of Monson et al.$^{(24)}$ While there are some differences between them because of differences in experimental apparatus and parameters to be measured, the kinetic results seems to be reasonable enough to be incorporated in a numerical modeling of coal combustion.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.9 no.1
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• pp.182-188
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• 2008

The compounds of recycled polyethylene(PE) and fly-ashes were prepared. Polymers used were sorted PE from mixed plastics of household waste and Low Density Polyethylene(LDPE) and Linear Low Density Polyethylene(LLDPE) recycled from the scrap of packaging film plants. Fly-ashes were from the power plant and from the household waste incinerator. The tensile strength of recycled LDPE and LLDPE compounds decreased and the flexural modulus increased with greater amount of the power plant fly-ash. Anthracite fly-ash gave rise to slightly higher tensile and flexural strength of the LLDPE mixtures than bituminous coal fly-ash presumably due to higher content of unburned carbon. The incinerator fly-ash introduced to household waste PE enhanced both tensile strength and flexural modulus of the compounds. When LDPE and household waste PE were used together, the synergistic effect of incinerator fly-ash to household waste PE was offset by reduced crystallization of LDPE due to the filler particle. The compounds of household waste PE and incinerator fly-ash might be applied to structural materials for such as sewage pipe, which reduces the waste treatment cost and conserve the environment and resources.

• Journal of the Korean Society of Combustion
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• v.8 no.2
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• pp.34-40
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• 2003

Analyses for concentration, surface phenomena, and crystal structure were performed to identify the causes of clinker formation in three type of pulverized coal fired boilers. Some clinkers had partially molten surface and more CaO and $Fe_2O_3$ as compared with fly ash, and the major crystalline phases identified in the clinker were mullite and quartz. Clinkers were formed in high temperature zone of the boiler according to the identification of mullite by XRD. Free $SiO_2$ in sand combined with K, Na and Ca in limestone served as a fluxing agent to form clinkers in a circulating bed boiler.

• Journal of Mechanical Science and Technology
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• v.15 no.2
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• pp.239-247
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• 2001

Measured radiative heat fluxes on the furnace exit plane of a heavy duty power boiler of steam output 1650 T/h are discussed. A high-ash pulverized bituminous coal was used. Such measurements are necessary to improve heat fluxes inside a steam boiler furnace was manufactured. An extra small heat radiation sensor was placed in the water cooled head of the probe. The sensor had no direct contact with furnace gases and measured only the radiant energy. There was no exposure to convective heat transfer. With the radiometric probe, one can obtain a spherical indicatrix of radiation intensity as well as hemispherical radiative heat flux incident on any surface passing through a measuring point inside the furnace. Thus, the quantity of radiation energy, passing through the furnace exit plane, to the convective heating surfaces and the quantity of radiation energy going in the opposite direction were measured. A formula for relative radiative heat flux on the furnace exit plane has been proposed.

• Korean Journal of Soil Science and Fertilizer
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• v.31 no.2
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• pp.151-157
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• 1998

Fly ash application with a rate of 0, 50, 100, $150Mg\;ha^{-1}$ in clay loam paddy, which had properties of pH 5.3 and low contents of silicate and boron, gave a strongly positive effects on the growth and yields of malting barley showing better responses in bituminous coal fly ash(BCFA) than anthracite fly ash(AFA). Especially, soil chemical characteristics improved greatly by fly ash were pH, available phosphate, exchangeable calcium, available silicate, and boron. Shoot length and the number of tiller till defrosting season appeared the most positive responses by application of BCFA $50Mg\;ha^{-1}$ and AFA $100Mg\;ha^{-1}$. However, the number of spikelet per panicle at heading stage was proportionally increased to the rates of each fly ash. As a result, the grain yields of malting barley were increased to $13.8(4.221Mg\;ha^{-1}){\sim}37.7%(5.106Mg\;ha^{-1})$ by application of BCFA and to $1.1(3.75Mg\;ha^{-1})-20.6%(4.473Mg\;ha^{-1})$ by application of AFA. Protein contents in the grain was the highest in $150Mg\;ha^{-1}$ plot, showing 10.5 and 10.8% by BCFA and AFA application, which were suitable for malting. At harvesting, plants showed 49 and 58% of lodging indices by application of BCFA 100 and $150Mg\;ha^{-1}$, respectively, which were equivalent to two fold values of those by AFA.

• Applied Chemistry for Engineering
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• v.23 no.6
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• pp.529-533
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• 2012

In this study, we compare various physicochemical properties of solvent extracted coals obtained at both mild and high temperature conditions. In order to characterize the extraction behavior, experiments were performed using a sub-bituminous coal (Kideco) and a polar solvent (N-methyl-2-pyrrolidinone, NMP), where the extraction temperature and the effect of solvent recycling were evaluated. As the extraction temperature increased up to $350^{\circ}C$, an extraction yield and a calorific value of the extracted coal increased, while an ash content of the extracted coal decreased. FT-IR results revealed that the surface of the coal extracted at $350^{\circ}C$ was found to contain more amide, aromatic ester, and aliphatic ether groups than that at the lower temperatures. The result of MALDI-TOF/MS analysis confirmed that the smaller molecules with 300~500 m/z were extracted at a mild condition, while the bigger molecules in the range of 500~1500 m/z were extracted at the high temperature.

• Korean Journal of Soil Science and Fertilizer
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• v.27 no.2
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• pp.65-71
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• 1994

This study was conducted to investigate the influence of treatment of fly ash on heavy metal contents in the arable soils. Rice was cultivated on the two types of paddy field(clay loam and sandy loam soil) with 0, 4, 8, 12t/10a of anthracite fly ash and bituminous coal fly ash, respectively. And soybean was cultivated on the same types of upland field with those of 0, 3, 6, 9t/10a, respectively. At the harvest time, the heavy metal contents in surface and subsoil were investigated. The results were summarized as follows : 1. Anthracite fly ash. 1) In the paddy field of clay loam, the contents of Cu and Zn in the surface soil and Cd and Ni in the subsoil were increased with the increase of the amount of fly ash applied, but the others didn't show that tendency. 2) In the paddy field of sandy loam, only the content of Fe was increased in the surface and subsoils. 3) In the case of upland soil, the concentration of Ni and Cr in the surface soil and Cd in the subsoil were increased in the clay loam soil, and those of Cr in the surface soil and Pb in the subsoil were increased in the sandy loam soil. 2. Bituminous coal fly ash 1) In the paddy field of clay loam, the contents of Cu and Zn in the subsoil were increased with increase of the amount of fly ash applied, but in the case of sandy loam, those of Pb and Ni in the surface soil were increased. 2) In the upland soil of clay loam, the concentration of Ni in the surface soil and Pb in the subsoil were increased. 3) In case of upland soil of sandy loam, the contents of Cr and Fe were increased in the surface and subsoil, respectively, but those of Cu and Mn were increased in the both of the surface and subsoil.

• Korean Chemical Engineering Research
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• v.52 no.5
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• pp.657-666
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• 2014

Coal gasification technology is considered as next generation clean coal technology even though it uses coal as fuel which releases huge amount of greenhouse gas because it has many advantages for carbon capture. Coal or pet-coke slurry gasification is very attractive technology at present and in the future because of its low construction cost and flexibility of slurry feeding system in spite of lower efficiency compared to dry feeding technology. In this study, we carried out gasification experiment using bituminous coal slurry sample by integrating coal slurry feeding facility and slurry burner into existing dry feeding compact gasifier. Especially, our experiment was conducted under fairly lower operation temperature than that of existing entrained-bed gasifier, resulting in partial slagging operation mode in which only part of ash was converted to slag and the rest of ash was released as fly ash. Carbon conversion rate was calculated from data analysis of collected slag and ash, and then cold gas efficiency, which is the most important indicator of gasifier performance, was estimated by carbon mass balance method. Fairly high performance considering pilot-scale experiment, 98.5% of carbon conversion and 60.4% of cold gas efficiency, was achieved. In addition, soundness of experimental result was verified from the comparison with chemical equilibrium composition and energy balance calculations.

• Korean Journal of Soil Science and Fertilizer
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• v.32 no.3
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• pp.279-284
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• 1999

Fly ash is the fine ash particles that are flying out of chimney of the thermoelectric power plant where coals are used as fuel. There are two kinds of fly ashes from anthracite and bituminous coal. By scanning electron microscope(SEM) morphological feature of fly ash was confirmed to the exact spherical particles with the diameter variation from the fine to the largest about $50{\mu}m$(mainly silty particle). Surface of anthracite ash particle was very smooth but that of bituminous was somewhat coarse. To find the utilization of fly ash for improving soil permeability, soils of 4 kinds of different texture, clay, clay loam, sandy clay loam and sand mere applied with 7 levels of fly ash: 0, 10, 20, 40, 60, 80, 100%(w/w) and their saturated hydraulic conductivity(Ks) were determined at each application by constant head method. In clay soil with low water permeability, Ks value was increased about 10 times from $10^{-8}$ to $10^{-7}m\;s^{-1}$ level with application of 10% fly ash and it was slightly increased with increasing fly ash application from 40 to 80%. In clay loam Ks value was about $10^{-7}m\;s^{-1}$ level and its value was not influenced by the fly ash application. In sandy clay loam with relatively high permeability, Ks value was decreased about 10 times from $10^{-5}$ to $10^{-6}m\;s^{-1}$ level with application of 10% fly ash and also decreased about 50 times from $10^{-5}$ to $5.0{\times}10^{-7}m\;s^{-1}$ with application of more than 20% fly ash. In sand with very high permeability, Ks value was decreased about 10 times from $10^{-4}$ to $10^{-5}m\;s^{-1}$ level with application of 10% fly ash and also decreased about 100 times from $10^{-4}$ to $10^{-6}m\;s^{-1}$ level with application of 20% fly ash and continuously decreased about 500 times from $10^{-4}$ to $5.0{\times}10^{-7}m\;s^{-1}$ level with application of more than 40% fly ash. In conclusion by fly ash application saturated hydraulic conductivity was increased in clay soil, on the contrary it was decreased in sandy soils. Fly ash may be used as a material for amelioration of soil permeability.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.4
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• pp.445-449
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• 2005

Present study was designed to evaluate the practical application of triethyl amine(TEA) injection for improving the collection efficiency of electrostatic precipitator(ESP) connected to a real operating plant. The major fuels used at the domestic power stations were bituminous coals imported from Australia, China, South Africa, and USA. Although the values of the electric resistance would be more or less different according to the type of the coals used, the unique electric resistance values of fly ash from the coals were mostly higher than $1{\times}10^{12}\;{\Omega}-cm$ and therefore, back corona problems were always expected to occur in the electrostatic precipitator. The particulates concentrations, smoke concentrations and their electric resistivity measured at the outlet of ESP, and the inspection of collection indicated that the injection of TEA improved the collection efficiency of particulate at collection plates of ESP. The electric resistance for, fly ash with the injection concentration of TEA 15 ppm(Purity 99.7%) was lowered to $2.1{\times}10^{11}\;{\Omega}-cm$ after injection from $1.9{\times}10^{12}\;{\Omega}-cm$ before injection. Under this condition, the dust emission content at the stack was reduced to approximately 80%, lowering the average outlet concentrations of particulates from $70\;mg/Sm^3$ to $14\;mg/Sm^3$.