• 농업과학연구
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• 제47권1호
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• pp.29-41
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• 2020

Biodiesel is a clean energy resource that can replace diesel as fuel, which can be used without any structural changes to the engine. Vegetable oil accounts for 95 percent of the raw materials used to produce biodiesel. Thus, many problems can arise, such as rising prices of food resources and an imbalance between supply and demand. Most of the previous studies using waste cooking oil used waste cooking oil from a single material. However, the waste cooking oil that is actually collected is a mixture of various types of waste cooking oil. Therefore, in this study, biodiesel produced with mixed waste cooking oil was supplied to an agricultural single-cylinder diesel engine to assess its potential as an alternative fuel. Based on the results, the brake specific fuel consumption (BSFC) increased compared to diesel, and the axis power decreased to between 70 and 99% compared to the diesel. For emissions, NO_x and CO₂ were increased, but CO and HC were decreased by up to 1 to 7% and 16 to 48%, respectively, compared to diesel. The emission characteristics of the mixed waste cooking oil biodiesel used in this study were shown to be similar to those of conventional vegetable biodiesel, confirming its potential as a fuel for mixed waste cooking oil biodiesel.

• 한국분무공학회지
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• 제18권4호
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• pp.182-187
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• 2013

This study was performed to investigate the effect of biodiesel derived from waste cooking oil on the spray behavior and macroscopic spray characteristics. To analyze quantitative characteristics of test fuels, injection quantity was measured at various injection pressures and the spray images of injected fuels in the pressurized chamber were obtained by using a high speed camera and image analysis system. Based on the measured spray images, the spray tip penetration and spray cone angle were investigated at various energizing timings and injection pressures. In this work, the experimental results showed that the injection quantity of waste cooking biodiesel indicated the higher quantities than diesel at high injection pressure. As the injection pressure was increased, the spray tip penetrations of biodiesel were higher value than diesel. The difference of penetration between biodiesel and conventional diesel fuel was reduced in accordance with the increase of injection pressure. Also, the spray angles of diesel were larger than that of biodiesel because diesel fuel has lower viscosity than biodiesel. In addition, the spray evolution processes of biodiesel fuel at various injection pressures and the elapsed time after the injection were compared to the conventional diesel fuel.

• International journal of advanced smart convergence
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• 제4권1호
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• pp.162-178
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• 2015

Petroleum based fossil fuels used to power most processes today are non-renewable fuels. This means that once used, they cannot be reproduced for a very long time. The maximum combustion of fossil fuels occurs in automobiles i.e. the vehicles we drive every day. Thus, there is a requirement to shift from these non-renenewable sources of energy to sources that are renewable and environment friendly. This is causing the need to shift towards more environmentally-sustainable transport fuels, preferably derived from biomass, such as biodiesel blends. These blends can be made from oils that are available in abundance or as waste e.g. waste cooking oil, animal fat, oil from seeds, oil from algae etc. Waste Cooking Oil(WCO) is a waste product and so, converting it into a transportation fuel is considered highly environmentally sustainable. Keeping this in mind, a life cycle assessment (LCA) was performed to evaluate the environmental implications of replacing diesel fuel with WCO biodiesel blends in a regular Diesel engine. This study uses Life Cycle Assessment (LCA) to determine the environmental outcomes of biodiesel from WCO in terms of global warming potential, life cycle energy efficiency (LCEE) and fossil energy ratio (FER) using the life cycle inventory and the openLCA software, version 1.3.4: 2007 - 2013 GreenDelta. This study resulted in the conclusion that the biodiesel production process from WCO in particular is more environmentally sustainable as compared to the preparation of diesel from raw oil, also taking into account the combustion products that are released into the atmosphere as exhaust emissions.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.313-316
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• 2012

In this study, the combustion and emission characteristics of waste cooking oil biodiesel was investigated. The fuel was injected from 5 CAD (Crank angle degree) ATDC (After top dead center) to -60 CAD ATDC by 5 CAD with 800 bar and 1600 bar injection pressure. Generally, the hydrocarbon, carbon monoxide and smoke emissions from biodiesel fuel were lower than the emission levels of diesel fuel. However, the emission characteristic of biodiesel got worse than diesel when the fuel was injected earlier than -30 CAD ATDC. $NO_x$ emission from biodeisel was higher than diesel fuel in all experimental conditions.

• 한국자동차공학회논문집
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• 제22권3호
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• pp.105-113
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• 2014

Spray and combustion process with waste cooking oil (WCO) biodiesel and commercial diesel were analyzed in an optically-accessible single-cylinder compression ignition diesel engine equipped with a high pressure common-rail injection system. Direct imaging method was applied to investigate spray and combustion characteristics. From the mie-scattering results, it was verified that WCO biodiesel had a longer injection delay compared to diesel. Spray tip penetration length of WCO biodiesel was longer and spray angle was narrower than those of diesel due to poor atomization characteristics. In terms of combustion, WCO biodiesel showed later start of combustion, while flame was vanished more rapidly. Analysis of flame luminosity showed that WCO biodiesel combustion had lower intensity and lasted for shorter duration.

• 동력기계공학회지
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• 제19권2호
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• pp.90-95
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• 2015

Recently worldwide concern and research is being actively conducted on green energy which can reduce environmental pollution. A plant such as the natural rapeseed oil, soybean oil, palm, etc. is used as a bio source in home and industry. Biofuels is a sustainable fuel having economically benefits and decreasing environmental pollution problems caused due to fossil fuel, and it can be applied to the conventional diesel engine without changing the existing institutional structure. Waste vegetable oil contains a high cetane number and viscosity component, the low carbon and oxygen content. A lot of research is progressing about the conversion of waste vegetable oil as renewable clean energy. In this study, waste oil was prepared to waste cooking oil generated from the living environment, and applied to diesel engine to confirm the possibility and cost-effectiveness of biodiesel blend waste oil. As a result, brake specific fuel consumption and NOx was increased, carbon monoxide and soot was decreased.

• 신재생에너지
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• 제19권4호
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• pp.2-10
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• 2023

The current mandatory domestic biodiesel blending ratio is 3.5%, which is planned to be gradually increased to achieve carbon neutrality by 2050. The aim of this study was to improve domestic self-sufficiency in biodiesel raw oil by conducting a technical review on the possibility of utilizing waste oils, such as soup oil, chicken oil, and leather oil, as biodiesel feedstocks. These waste oils have an acid value that is too high to be converted directly into biodiesel. Therefore, a pretreatment to reduce the acid value is necessary. The neutralization process was examined as a potential technology for reducing the acid value. The oil recovery rate of the soup oil after neutralization was significantly low at 37.6 wt%. The oil recovery rates of leather oil and chicken oil were 66.49 wt% and 79.08 wt%, respectively. Based on biodiesel conversion experiment using waste oil with a reduced acid value, the conversions were analyzed as 89 wt%, 91.1 wt%, and 90.5 wt% for soup oil, leather oil, and chicken oil, respectively. Thus, it is technically possible to use soup oil, leather oil, and chicken oil as raw materials for producing biodiesel.

• 공업화학
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• 제35권5호
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• pp.438-444
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• 2024

Lipid-extracted algae (LEA) cell residue is generated as an organic solid waste in the process of biodiesel production from microalgae, and its recycling or reuse is important in the aspect of waste minimization. In this study, the influence of the addition of LEA hydrolysate to Chlorella vulgaris (C. vulgaris) cultivation on cell growth and biodiesel production was investigated to seek a possible use of LEA as a carbon source. LEA was hydrolyzed by three different methods: acid hydrolysis, autoclave, and ultra-sonication. The resulting hydrolysates were supplemented with three background media: formulated defined medium (BG-11), organic liquid fertilizer (PAL1), and distilled water. Both cell growth and lipid production of C. vulgaris were improved under mixotrophic cultivation. By supplementing hydrolysates, biomass productivity was increased several folds because the LEA hydrolysates contained monosaccharides such as glucose and galactose. Lipid contents and biodiesel productivity were bestly increased in PAL1 medium supplemented with ultrasonication (UL) hydrolysate, from 11 to 25% after 14 days, while nitrate concentration was quickly reduced from 55 to below 10 mg/L. The suggested recycling option of the LEA to microalgae cultivation was helpful to improve biodiesel productivity as well as to reduce organic waste generation.

• 한국환경과학회지
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• 제19권10호
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• pp.1247-1256
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• 2010

Since biodiesel as bioenergy is defined as ester compounds formed by esterification of animal/vegetable oils, in this study three vegetable cooking oils (market, waste and refined waste ones) were esterified by reactions of alkali catalyst and immobilized enzyme. The fatty acid composition of the formed ester compounds was analyzed to investigate the feasibility of biodiesel production. By lipolysis (i.e, hydrolysis of Triglyceride (TG)), all three vegetable oils used in this study were found to produce Diglyceride (DG), Monoglyceride (MD) and Fatty acid ethylester (FAEE). However, the amount of produced FAEE (which can be used as an energy source) was in the increasing order of market cooking oil, waste one and refined waste one. With NaOH catalyst, FAEE was produced about 24.92, 17.63 and 11.31 % for the respective oils while adding Lipozyme TL produced FAEE about 43.54, 38.16 and 24.47 %, respectively. This indicates that enzyme catalyst is more effective than alkali one for transesterification. In addition, it was found that the composition of fatty acids produced by hydrolysis of TG was unchanged with alkali and immobilized enzyme reactions. Thus it can be expected that stable conditions remain in the course of mixing with gasoline whose composition is similar to that of the fatty acids.

• 수산해양교육연구
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• 제27권2호
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• pp.516-525
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• 2015

In this study, Life Cycle Assessment(LCA) was applied to the production processes of waste cooking oil recycling products. Recycling products as defined in the Law of Saving of Resources and Recycling Promotion are biodiesel and soap. Weighting result of biodiesel production process showed that the most significant impact potential was abiotic resource depletion(84.17%) followed by global warming(13.93%). In the case of the soap, the most significant impact potential was also abiotic resource depletion(58.59%) followed by global warming(33.71%). In terms of the whole system of the biodiesel production process, methanol showed the largest environmental impact potential(87.35%). While in the case of the soap, sodium chloride showed the largest environmental impact potential(99.99%). This study suggests that there should be improvement of the methanol recovery system in the biodiesel production process and also appropriate use of the major environmental impact materials in both processes.