• 멤브레인
• /
• 제20권2호
• /
• pp.106-112
• /
• 2010

본 연구에서는 poly(phenylene oxide) (PPO)의 막 표면에 100 ppm의 농도를 갖는 불소가스를 접촉시켜 표면불소화하였다. 표면 개질된 막의 특성을 알아보기 위하여 표면접촉각, XPS, 기체투과 실험을 수행하였다. 표면특성 분석 결과 불소처리 시간이 증가함에 따라 막 표면에 $-CF_2$, $-CF_3$의 perfluoro group의 결합으로 인해 막의 소수성이 증가함을 알 수 있었다. 기체투과 측정으로부터 불소화시간이 증가함에 따라 기체에 대한 투과도는 감소하였으며, 불소노출이 60분 경과한 막의 경우 질소 33%, 산소 23%, 이산화탄소 3%의 감소율을 나타내었다. 선택도의 경우 질소 대비 산소의 경우 3.92로부터 4.47로, 이산화탄소에 대한 질소의 경우 18.09에서 25.4로 증가함을 얻었다.

• 대한안전경영과학회지
• /
• 제14권1호
• /
• pp.43-51
• /
• 2012

This study was carried out to observe the impacts of a mouse's inhalation of toxic gas SO2 generated from combustion on its organs by different concentrations. As for research methods: First, after concentrations of SO2 generation from combustion had been set to three: low (10.4 ppm), middle (24.9 ppm) and high (122 ppm) through Gas Toxicity Testing Method (KS F 2271) and SO2 combustion gas was exposed to eight mice in each concentration. Five mice that were able to move based on LD50, a criterion, which sets the down time of a mouse's average behaviors to over 9 minutes, were randomly selected in each concentration, and they were set up as the subjects of the study on toxicity bio-markers. Second, tissues were taken from heart, liver, lungs, spleen and the thymus gland of the mice selected in each concentration and a pathological examination of them was carried out. As a result, microvascular congestion appeared in the heart, and cell necrosis, cortex congestion and tubule medulla congestion, etc. in each concentration were observed in addition to vascular congestion in liver, lungs, spleen and the thymus gland. Also, it was found that the higher the concentrations of SO2 exposure is, the greater, the changes in the organs get. Through this study, SO2 of various toxic gases generated from fire turned out to affect the tissues of each organ of a mouse, it is expected that the toxic gases may greatly affect human body in case of actual fire, and this study is evaluated as having a significance as a basic data on inhalation toxicity assessment of toxic substances generated in combustion.

• 한국환경보건학회지
• /
• 제34권1호
• /
• pp.101-107
• /
• 2008

Bio-filtration utilizes microorganisms fixed to a porous medium to metabolize pollutants present in an air stream. The microorganisms grow in a bio-film on the surface of a medium or are suspended in the water phase surrounding the medium particles. Therefore, bio-filter support media play one of the most important key roles in bio-filtration of gas phase pollutants. To characterize and select the appropriate support media, gas adsorption capacity and microorganism immobilization were investigated in lab-scale experiments for the selected target support media which were compost I (compost from lab-scale process), compost II (compost from municipal facility), bark, wood chip, orchid stone and vermiculite. As odor materials, ammonia and trimethylamine were utilized. From the result of experiments, bark was superior to any other support media tested in adsorption capacity as much as 12.5 mg ammonia per 1 g bark. In trimethylamine adsorption, bark and wood chip showed a remarkable results of 21.1 and 14.1 mg/g respectively. On the other hand, microorganism fixation test determined by the count of nitrogen oxidizing microbes population, the compost II and wood chips showed the best results. Considering the characteristics of materials and the operating condition of the bio-filter, bark, wood chip, and compost II are applicable to the support media of bio-filter when they are appropriately blended on the basis of studying the media pH, packing porosity and moisture contents.

• Environmental Engineering Research
• /
• 제19권2호
• /
• pp.123-130
• /
• 2014

Percolation is the important process of extracting the soluble constituents of a fine mesh, porous substance by passage of a liquid through it. In this study, bio-wastes were percolated under various conditions through continuous percolation processes, and the energy potential of percolate was evaluated. The representative bio-wastes from the K composting plant in Darmstadt, Germany were used as the sample for percolation. The central objective of this study was to determine the optimal amount of process water and the optimum duration of percolation through the bio-wastes. For economic reasons, the retention time of the percolation medium should be as long as necessary and as short as possible. For the percolation of the bio-wastes, the optimal percolation time was 2 hr and maximum percolation time was 4 hr. After 2 hr, more than two-thirds of the organic substances from the input material were percolated. In the first percolation process, the highest yields of organic substance were achieved. The best percolation of the bio-wastes was achieved when the process water of 2 L for the first percolation procedure and then the process water of 1.5 L for each further percolation procedure for a total 8 L for all five procedures were used on 1,000 g fresh bio-waste. The gas formation potentials of 0.83 and $0.96Nm^3/ton$ fresh matter (FM) were obtained based on the percolate from 1 hr percolation of 1,000 g bio-waste with the process water of 2 L according to the measurement of the gas formation in 21 days (GB21). This method can potentially contribute to reducing fossil fuel consumption and thus combating climate change.

• 한국수소및신에너지학회논문집
• /
• 제30권5호
• /
• pp.428-435
• /
• 2019

A comparative evaluation of engine cleanliness was performed on the transport gasoline blended with bio- alcohols, and this study was considered to achieve the aim of greenhouse gas reduction in Korea. In particular, the fuel blended with bio-ethanol and bio-butanol showed the best engine cleaning performance both on combustion chamber deposits and intake valve deposits. The deposit control gasoline additive was effective to remove intake valve deposits. In contrast, the amount of combustion chamber deposits were tend to increase even though fuels blended with bio-alcohols were used. In overall, fuels blended with bio-alcohols, compared to fossil fuels, still showed outstanding performance in terms of engine cleanliness.

• 공업화학
• /
• 제17권5호
• /
• pp.465-470
• /
• 2006

실록산은 많은 소비 및 공업제품에 사용되고 있고 이들이 매립되어 발생되는 매립가스에는 휘발성 실록산을 포함한다. 휘발성 실록산을 포함한 매립가스를 가스엔진의 연료로 사용할 경우 매립가스내 휘발성 실록산은 가스엔진뿐만 아니라 전처리 시설에 큰 해를 입히게 된다. 따라서 본 연구에서는 매립가스내 휘발성 실록산 흡착제로서 활성탄 대용으로 천연 점토광물인 질석과 일라이트를 사용해 이의 유용성을 검토하였다. 질석, 일라이트 및 활성탄의 SEM 및 BET 분석을 통해 이들의 물성값을 비교하였다. 또한 일라이트 및 질석을 흡착제로 사용하여 D5 실록산의 흡착용량을 평가 하였는바, 각각 1.7 g/g 일라이트 및 3.8 g/g 질석의 대단히 높은 흡착용량을 나타내었다.

• 한국토양비료학회지
• /
• 제20권4호
• /
• pp.351-357
• /
• 1987

상품화(商品化) 되어있는 유기질비료(有機質肥料) Bio-com$^{(R)}$을 토양(土壤)에 시용시(施用時) 토양(土壤)의 pH, Eh, gas 생성(生成), Ammonia 화성율(化成率) 질산화성율(窒酸化成率) 및 미생물(微生物) 변화(變化)에 미치는 영향(影響)을 알기 위하여 일반농가퇴비(一般農家堆肥) 및 양송이 폐상퇴비등(等)을 비교(比較)하여 담수조건(湛水條件)에서 실내시험(室內試驗)한 결과(結果)를 요약(要約)하면 다음과 같다. 1. 삼요소구(三要素區)에 비(比)하여 각종(各種) 퇴비시용(堆肥施用)은 토양(土壤) pH를 상승시키는 경향(傾向)이 있었으며 Bio-com$^{(R)}$ 시용(施用)은 타공시유기물(他供試有機物)과 상이(相異)하지 않했다. 2. 시험후(試驗後) 토양(土壤)의 미생물수(微生物數) 변화(變化)는 삼요소(三要素) 혹은 각종(各種) 퇴비(堆肥)를 삼요소(三要素)와 병용(倂用)하므로서 현저(顯著)한 증가(增加)를 보였으며 농가퇴비시용구(農家堆肥施用區)에서 세균수(細菌數)의 증가(增加)가 현저(顯著)하였다. 3. Bio-com$^{(R)}$ 시용(施用)은 항온기간중(恒溫期間中) 질산화성율(窒酸化成率)을 증가(增加)시켰으며 그율(率)은 타처리(他處理)에 비(比)하여 수배정도(數培程度)높아서 밭작물재배지(作物栽培地)에 시용(施用)이 합리적(合理的)이었다. 4. Bio-com$^{(R)}$ 시용(施用)에 의한 gas의 생성(生成)은 일반퇴비(一般堆肥)나 양송이 폐상퇴비(堆肥) 시용(施用)과 비슷한 경향(傾向)을 보였고 $N_2O$의 생성(生成)은 삼요소시용(三要素施用)보다 낮은양(量)을 보였다.

• Journal of Advanced Marine Engineering and Technology
• /
• 제22권6호
• /
• pp.754-762
• /
• 1998

Exhaust emissions in diesel engine are affected by fuel properties but the reason for this is not clear. Especially the recent strong interest in using low-grade fuel demands extensibe investigation in order to clarify the exhaust emissions. Bio-Diesel oil has a great possibility to solve the pollution problem caused by the exhaust gas from diesel engine vehicles. The use of bio-oils in diesel engines has received considerable atten-tion to the forseeable depletion of world oil supplies. So bio-diesel oil has been attracted with attentions for alternative and clean energy source. The purpose of this paper is to evaluate the fea-sibility of the rice-bran oil for alternative fuel in a diesel engine with rgard to exhaust emis-sions.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2007년도 춘계학술대회
• /
• pp.585-588
• /
• 2007

As the distributed generation becomes more reliable and economically feasible, it is expected that a higher application of the distributed generation units would be interconnected to the existing grids. This new generation technology is linked to a large number of factors like economics and performance, safety and reliability, market regulations, environmental issues, or grid connection constrains. KEPCO (Korea Electric Power Corporation) is performing the project to develope the Distributed Micro Gas Turbine (MGT) technolgies by using Swine BIO-ENERGY. This paper describes the plans and strategies for the renewable energy of MGT on actual grid-connection under Korean situations. KEPCO also, has a research plan on bio-gas pretreatment system applicable to our domestic swine renewable resources and is performing concept design of pilot plant to test grid operation. In addition, this testing will be conducted in order to respond to a wide variety of needs for application and economic evaluation in the field of On-site generation.

• 한국환경과학회지
• /
• 제23권6호
• /
• pp.1061-1066
• /
• 2014

This study has cross checked the change of internal sludge-recycle in Anaerobic-Digestion, and researched about not only the improvement of Bio-gas production from the digested sludge but also the efficient method of sludge minimization. Ultimate object of the study is to reduce the amount of sludge by the improved efficiency of contact with the organic-matter and the microbes in Anaerobic-Digestion. The sludge-recycle fluidized sludge layer and raised the activity of the sludge, the optimal sludge-recycle ratio, VS and COD removal ratio were 1,000%, 28.2% and 27.7%, respectively. Through these results of this study, it may be of use to treat waste sludge by the sludge-recycle ratio in terms of minimization and circulation of resources.