• Clean Technology
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• v.25 no.2
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• pp.168-176
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• 2019

Spent coffee is one of biomass sources to be converted into bio-oil. However, the bio-oil should be further upgraded to achieve a higher quality bio-oil because of its high oxygen content. Deoxygenation under hydrotreating using different catalysts (catalytic hydrodeoxygenation; HDO) is considered as one of the promising methods for upgrading bio-oil from pyrolysis by removal of O-containing groups. In this study, the HDO of spent coffee bio-oil, which was collected from fast pyrolysis of spent coffee ($460^{\circ}C$, $2.0{\times}U_{mf}$), was carried out in an autoclave. The product yields were 72.16 ~ 96.76 wt% of bio-oil, 0 ~ 18.59 wt% of char, and 3.24 ~ 9.25 wt% of gas obtained in 30 min at temperatures between $250^{\circ}C$ and $350^{\circ}C$ and pressure in the range of 3 to 9 bar. The highest yield of bio-oil of 97.13% was achieved at $250^{\circ}C$ and 3 bar, with high selectivity of D-Allose. The carbon number distribution of the bio-oil was analyzed based on the concept of simulated distillation. The $C_{12}{\sim}C_{14}$ fraction increased from 22.98 wt% to 27.30 wt%, whereas the $C_{19}{\sim}C_{26}$ fraction decreased from 24.74 wt% to 17.18 wt% with increasing reaction time. Bio-oil yields were slightly decreased when the HZSM-5 catalyst and dolomite were used. The selectivity of CO was increased at the HZSM-5 catalyst and decreased at the dolomite.

• Membrane Journal
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• v.22 no.4
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• pp.251-257
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• 2012

For the separation and recovery of n-pentane from nitrogen environment, the poly (dimethyl siloxane) (PDMS) composite membranes supported by polyetherimide (PEI) hollow fiber membranes were prepared. To characterize the gas separation properties of the resulting membranes, the permeance of n-pentane and nitrogen, concentrations of permeate and retentate, and recovery ratio were measured for n-pentane and nitrogen mixtures. The permeance of n-pentane and nitrogen, 2485.3 and 9.9 GPU, were observed respectively. As the stage cut decreases and the feed concentration increases, the n-pentane concentration in permeate tends to increase. In the meanwhile, the recovery efficiency tends to increase as the stage cut increases and the feed concentration decreases.

• Journal of the Korea Organic Resources Recycling Association
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• v.28 no.1
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• pp.83-95
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• 2020

The economic issue of the period of return versus investment has emerged to efficiently utilize the thermal energy of public resource recovery facilities using waste and private thermal source facilities using BIO-SRF. Accordingly, the optimum temperature and pressure facilities are required beyond the traditional designed, constructed and operated. In this study, we analyzed current energy output by different heat and pressure model in domestic facilities, and calculated the characteristics of green-house gas emission. In order to, utilize the thermal energy producing facilities using waste and biomass fuel more efficiently, it is temperature and pressure, which will lead to more lucrative investment and return as well.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.13 no.4
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• pp.21-27
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• 2014

The injection molding process has several advantages enabling it to produce large quantities of molded plastic products using a repetitive process. In recent years, it has been necessary to develop an injection molding process with micro/nano-sized patterns for application to the semiconductor industry and to the bio/nano manufacturing industry. In this study, we apply gas pressure to the inside of a mold and consider the gas dissolution phenomenon for a resin filling into a micro pattern with a line structure. Using numerical analysis, we calculate the filling ratio with respect to time for various internal gas pressures and various aspect ratios of the micro-patterns.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.144-144
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• 2013

Non-thermal atmospheric pressure plasmas have recently garnered much attention due to their unique physical and chemical properties that are sometimes significantly different from those of low pressure plasmas. It can offer many possible application areas including nano and bio/medical areas. Many different types of plasma sources have been developed for specific needs, which can be one of the important merits of the atmospheric pressure plasmas since characteristics of the produced plasma depend significantly on operating parameters such as driving frequency, supply gas type, driving voltage waveform, gas flow rate, gas composition, geometrical factor etc. Among many source configurations, parallel plate type geometry is one of the simplest configurations so that it can offer many insights for understanding basic underlying physics. Traditionally, the parallel plate type set up has been studied actively for understanding low pressure plasma physics along with extensive employment in industries for the same reason. By considering that understanding basic physics, in conjunction with plasma-surface interactions especially for nano & bio materials, should be pursued in parallel with applications, we investigated atmospheric pressure discharge characteristics in a parallel plate type capacitive discharge source with two parallel copper electrodes of 60 mm in diameter and several millimeters in gap distance. In this presentation, some plasma characteristics by varying many operating variables such as inter-electrode distance, gas pressure, gas composition, driving frequency etc will be discussed. The results may be utilized for plasma control for widening application flexibility.

• Journal of Korean Society of Industrial and Systems Engineering
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• v.44 no.2
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• pp.85-92
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• 2021

Ambient Air Vaporizer (AAV) is an essential facility in the process of generating natural gas that uses air in the atmosphere as a medium for heat exchange to vaporize liquid natural gas into gas-state gas. AAV is more economical and eco-friendly in that it uses less energy compared to the previously used Submerged vaporizer (SMV) and Open-rack vaporizer (ORV). However, AAV is not often applied to actual processes because it is heavily affected by external environments such as atmospheric temperature and humidity. With insufficient operational experience and facility operations that rely on the intuition of the operator, the actual operation of AAV is very inefficient. To address these challenges, this paper proposes an artificial intelligence-based model that can intelligent AAV operations based on operational big data. The proposed artificial intelligence model is used deep neural networks, and the superiority of the artificial intelligence model is verified through multiple regression analysis and comparison. In this paper, the proposed model simulates based on data collected from real-world processes and compared to existing data, showing a 48.8% decrease in power usage compared to previous data. The techniques proposed in this paper can be used to improve the energy efficiency of the current natural gas generation process, and can be applied to other processes in the future.

• Asian-Australasian Journal of Animal Sciences
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• v.18 no.10
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• pp.1435-1439
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• 2005

Bacterio-mineral water (BMW) produced from manure has been known to exert a number of positive effects on animal production and odor control. An experiment was conducted to examine the effects of BMW produced from bio-reacted swine manure on in vitro gas production, cellulose degradation, microbial growth and fibrolytic enzyme activities of mixed rumen microorganisms. The five levels of 0, 0.001, 0.005, 0.01 and 1.0% BMW were supplemented into serum vials containing mixed rumen microorganisms. Incubations were carried out anaerobically at $39^{\circ}C$ without shaking for 0, 12, 24, 48, 72 and 96 h. There were no significant (p>0.05) differences among the treatments for the initial rate of gas production. At 72 h incubation, the gas production tended (p<0.1) to be increased by the 0.01 and 1.0% BMW treatments compared with control and the 0.001% BMW treatment. At the end of incubation (96 h), the sample supplemented with 0.01% BMW was higher (p<0.05) than control (0% BMW) in the gas production. The microbial growth rate was increased by all the BMW treatments, while 0.01% BMW was most effective in stimulating the growth rate. Although the addition of BMW on the filter paper DM degradation was not significantly influenced throughout the incubation period except the 48 h incubation, DM degradation tended to be increased by all BMW treatments compared with control. The addition of both 0.005 and 0.01% BMW highly increased (p<0.05) CMCase activity compared with control after 24 h and 48 h incubation, while at the 72 h incubation the 0.01% BMW addition only significantly increased (p<0.05). After 72 h incubation, the xylanase activity was significantly (p<0.05) increased with the addition of 1.0% BMW compared with the addition of 0.001 and 0.005% BMW, while at the other incubation times, the xylanase activity was not different among the treatments. In conclusion, the 0.01% BMW of supplementation level would be the suitable addition level to stimulate rumen fermentation increasing microbial growth and cellulose degradation.

• Clean Technology
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• v.13 no.2
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• pp.122-126
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• 2007

When ammonia ($NH_3$) gas was supplied to a biofilter packed with bio-carrier made of waste polyurthane and worm cast. No odor gases were detected at the outlet of the biofilter when $NH_3$ gas was supplied to the biofilter at the space velocity(SV) of $50\;h^{-1}$ until the inlet $NH_3$ concentration increased to $4\;{\sim}\;454\;ppmv$. The gradual inlet $NH_3$ concentration was set and the removal efficiency of $NH_3$ gas was measured at each condition, while the SV of $NH_3$ increased step by step from 100 to $400\;h^{-1}$. The maximum possible inlet $NH_3$ loading was $11.38\;g-NH_3{\cdot}m^{-3}{\cdot}h^{-1}$ and $34.42\;g-NH_3{\cdot}m^{-3}{\cdot}h^{-1}$ while maintaining the removal efficiency of 100% when the SV was $50\;h^{-1}$ and $100 \;h^{-1}$, respectively. The maximum $NH_3$ loading was $71.28 \;g-NH_3{\cdot}m^{-3}{\cdot}h^{-1}$ with the $NH_3$ removal efficiency of 99.85% at SV $300\;h^{-1}$.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.44-45
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• 2010

We are currently conducting studies on culturing and biocompatibility assessment of various cells such as neural stem cells and induced pluripotent stem cells(IPS cells) on carbon nanotube (CNT), on nerve regeneration electrodes, and on silicon wafers with a focus on developing nerve integrated CNT based bio devices for interfacing with living organisms, in order to develop brain-machine interfaces (BMI). In addition, we are carried out the chemical modification of carbon nanotube (mainly SWCNTs)-based bio-nanosensors by the plasma ion irradiation (plasma activation) method, and provide a characteristic evaluation of a bio-nanosensor using bovine serum albumin (BSA)/anti-BSA binding and oligonucleotide hybridization. On the other hand, the researches in the case of "novel plasma" have been widely conducted in the fields of chemistry, solid physics, and nanomaterial science. From the above-mentioned background, we are conducting basic experiments on direct irradiation of body tissues and cells using a micro-spot atmospheric pressure plasma source. The device is a coaxial structure having a tungsten wire installed inside a glass capillary, and a grounded ring electrode wrapped on the outside. The conditions of plasma generation are as follows: applied voltage: 5-9 kV, frequency: 1-3 kHz, helium (He) gas flow: 1-1.5 L/min, and plasma irradiation time: 1-300 sec. The experiment was conducted by preparing a culture medium containing mouse fibroblasts (NIH3T3) on a culture dish. A culture dish irradiated with plasma was introduced into a $CO_2$-incubator. The small animals used in the experiment involving plasma irradiation into living tissue were rat, rabbit, and pick and are deeply anesthetized with the gas anesthesia. According to the dependency of cell numbers against the plasma irradiation time, when only He gas was flowed, the growth of cells was inhibited as the floatation of cells caused by gas agitation inside the culture was promoted. On the other hand, there was no floatation of cells and healthy growth was observed when plasma was irradiated. Furthermore, in an experiment testing the effects of plasma irradiation on rats that were artificially given burn wounds, no evidence of electric shock injuries was found in the irradiated areas. In fact, the observed evidence of healing and improvements of the burn wounds suggested the presence of healing effects due to the growth factors in the tissues. Therefore, it appears that the interaction due to ion/radicalcollisions causes a substantial effect on the proliferation of growth factors such as epidermal growth factor (EGF), nerve growth factor (NGF), and transforming growth factor (TGF) that are present in the cells.

• Journal of Power System Engineering
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• v.18 no.2
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• pp.5-11
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• 2014

The purpose of this study is to investigate the specific characteristics of combustion and exhaust emissions on a 4-cylinder common rail diesel engine as EGR rate and the rate of blended bio-diesel was altered. Bio-diesel fuel which is a sort of alternative fuels can be adapted to diesel engine directly without modifying. This study was performed to 2000rpm of engine speed with torque 30Nm while EGR rate and the rate of blended bio-diesel was changed. Decreasing combustion pressure and increasing the rate of heat were occurred when we had changed the EGR rate on the 20% of bio-diesel blended diesel fuel. The maximum pressure of combustion and the IMEP became higher as the EGR rate and the rate of blended bio-diesel were changed. Exhaust gas temperature was increased the higher rate of the blended bio-diesel under the fixed EGR rate. However, it went down as the EGR rate increased. The amounts of CO and Soot were reduced with increasing the rate of the blended bio-diesel without changing EGR rate and raised with increasing of the EGR rate. On the fixed EGR rate, NOx was increased along with growing the rate of the bio-diesel. On the other hand, it was decreased while EGR rate were going up.