• Title/Summary/Keyword: Bio-carbon

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Preparation of Micro-/Macroporous Carbons and Their Gas Sorption Properties

  • Hwang, Yong-Kyung;Shin, Hye-Seon;Hong, Jin-Yeon;Huh, Seong
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.377-382
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    • 2014
  • Micro-/macroporous carbons (MMCs) were prepared using a hollow mesoporous silica capsule (HMSC) as a sacrificial hard template. The carbonization process after the infiltration of furfuryl alcohol into the template-free HMSC material afforded MMC materials in high yield. The hard template HMSC could be removed by HF etching without deteriorating the structure of MMC. The MMC materials were fully characterized by SEM, TEM, PXRD, XPS, and Raman spectroscopy. The replication processes were so successful that MMCs exhibited a hollow capsular structure with multimodal microporosity. Detailed textural properties of MMC materials were investigated by volumetric $N_2$ adsorption-desorption analysis at 77 K. To explore the gas sorption abilities of MMCs for other gases, $H_2$ and $CO_2$ sorption analyses were also performed at various temperatures. The multimodal MMC materials were found to be good sorbents for both $H_2$ and $CO_2$ at low pressure.

The Treatment of Flexo-inks Wastewater using Powdered Activated Carbon Including Iron-transition Metal (철 전이금속이 담지된 분말활성탄을 이용한 후렉소잉크 폐수의 처리)

  • Cho, Yong-Duck;Yoon, Won-Jung;Kang, Ik-Joong;Yoo, In-Sang;Lee, Sang-Wha
    • Journal of Korean Society on Water Environment
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    • v.22 no.6
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    • pp.996-1003
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    • 2006
  • The absorption characteristics of powdered activated carbon doped by transition-metal nanoparticles were investigated to enhance the remove efficiencies of $TCOD_{Mn}$ and Color from the flexo-inks wastewater. According to the adsorption dynamics of PAC and MPAC, the optimal dosage of activated-carbon adsorbents was 3 g/L under the reaction conditions of pH6.0, 30 mill of reaction time, 240 rpm of mixing intensity. The removal efficiencies by the optimal dosages were maximized as 19% $TCOD_{Mn}$, 57% Color for PAC and 88% $TCOD_{Mn}$, 95% Color for MPAC. Freundlich indexes of isotherm absorption were estimated as follows: i) For PAC, k=-8.11, 1/n=2.98, r=0.91 in the raw water, and k=0.14, b/n=0.75, r=0.96 in the biological treatment water, ii) For MPAC, k=2.69, 1/n=0.21, r=0.80 in the raw water, and k=0.74, 1/n=1.17, r=0.95 in the biological treatment water. MPAC (Powdered activated carbon doped by transition-metal nanoaprticles) was very effective in the removal of organics from the raw water and biological treatment water, as Freundlich indexes of 1/n for both types of water were estimated less than 2.0.

Sustainable middle indices development for Algae Bio-energize industry (해조류를 이용한 바이오 에너지화 산업의 지속가능 중간지표 개발)

  • Koo, Ja-Kong;Kim, So-Hyun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.2
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    • pp.11-16
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    • 2014
  • Korea is the urgent need to diversify the bio-energy raw materials because we have narrow area of land cultivated plants and lack the bio-mass resources. Using a resource-rich the marine environment enclosed on three sides by the sea. Through bio-energy production-technical and carbon dioxide reduction measures which will be a very effective alternative. Sustainable development about algae bio-energize industry through SSaM-GG(Smart, Shared and Mutual-Green, Growth) is expected. Algae has high carbon dioxide absorption factor, extracting oil from algae is thirty times much more than sunflower.

Improved Power Capability with Pyrolyzed Carbon Electrodes in Micro Direct Photosynthetic/Metabolic Bio-fuel Cell

  • Moriuchi, Takeyuki;Morishima, Keisuke;Furukawa, Yuji
    • International Journal of Precision Engineering and Manufacturing
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    • v.9 no.2
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    • pp.23-27
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    • 2008
  • As a biofuel source, direct photosynthetic/metabolic biofuel cells (DPBFC) use cyanobacteria whose photosynthesis and metabolization reactions can convert light energy to electricity, In our previous work, we fabricated a prototype micro-DPBFC that could generate a peak current density of $36{\mu}A/cm^{2}$ and a maximum power density of $270nW/cm^{2}$. In this study, we improve on the previous results by using carbon micro electromechanical systems (C-MEMS), formed from the pyrolysis of patterned photoresist, to fabricate carbon electrodes of an arbitrary shape and controlled porosity to increase the surface area. With these new C-MEMS electrodes, the maximum power density of the micro-DPBFC was $516nW/cm^{2}$, a performance twice as good as the results of our previous work.

Mycological Characteristics and Carbon Source Activities of Unrecorded Wild Yeast Species from Vineyard Soil in Korea (국내 포도밭 토양에서 분리된 야생 효모 미기록종들의 균학적 특성과 탄소원 활성)

  • Bong Soon Yim;Myung Kyum Kim
    • The Korean Journal of Mycology
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    • v.51 no.4
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    • pp.373-381
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    • 2023
  • This study aimed to isolate and characterize wild yeast strains from the vineyard soil in Korea. Twenty yeast strains were isolated from vineyard soil in Gimpo-si, Gyeonggi-do, Korea, where Vitis labrusca cv. Campbell Early is grown. Eighteen strains were previously recorded in Korea. The remaining two, Cyberlindnera mrakii VG-21-10C and Starmerella bacillaris GR9 were not previously recorded in Korea. The mycological characteristics of VG-21-10C and GR9 were investigated. Both were oval-shaped, convex, and smooth. However, differences were evident in colony color and carbon assimilation activities. Strain VG-21-10C is white-colored and assimilates glucose, glycerol, D-xylose, D-cellobiose, D-saccharose, and D-raffinose as carbon sources. Strain GR9 is cream-colored and assimilates glucose, D-saccharose, and D-raffinose as carbon sources.

Preparation and Properties of Polyurethanes Containing Polycarbonate Polyol/Bio Polyol for Wet Type Artificial Leather (폴리카보네이트 폴리올/바이오 폴리올을 이용한 습식 인조피혁용 폴리우레탄의 제조 및 물성)

  • Sur, Suk-Hun;Ko, Jae-Wang;Choi, Pil-Jun;Lee, Jae-Yeon;Lee, Young-Hee;Kim, Han-Do
    • Clean Technology
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    • v.25 no.2
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    • pp.114-122
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    • 2019
  • The synthesis of bio polyol from renewable resources has attracted attention in recent years. In particular, it is important to take advantage of bio polyols in the synthesis of polymers. In this study, a series of dimethylformamide (DMF) based polyurethanes were synthesized using polycarbonate polyol/bio polyol (PO3G: polytrimethylene ether glycol prepared from 1, 3-propanediol produced by fermentation from corn sugar), methylene diphenyl diisocyanate (MDI) and 1,4-butandiol (BD). The properties of prepared polyurethane films and the cell structure of wet type artificial leather were investigated. As the bio polyol content increased, the tensile strength of polyurethane films decreased, however, the elongation at break increased significantly. As a result of thermal characteristics analysis, the glass transition temperature of polyurethanes increased when increasing the content of polycarbonate polyol. As a result of comparing the cell characteristics of wet type artificial leathers prepared in this study, it was found that the number and uniformity of cells formed in the artificial leather samples increased when increasing the content of polycarbonate polyol in polycarbonate polyol/bio polyol. From these results, it was found that DMF-based polyurethane containing an appropriate amount of bio polyol could be used for wet type artificial leather. The bio textile analysis system according to ASTM standard was used to measure the bio carbon content of polyurethane. The content of bio carbon increased proportionally with the increase of bio polyol content used in polyurethane synthesis.

Effect of bio-char application combined with straw residue mulching on soil soluble nutrient loss in sloping arable land

  • Gu, Chiming;Chen, Fang;Mohamed, Ibrahim;Brooks, Margot;Li, Zhiguo
    • Carbon letters
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    • v.26
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    • pp.66-73
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    • 2018
  • We assessed the effects of combining bio-char with straw residue mulching on the loss of soil soluble nutrients and citrus yield in sloping land. The two-year study showed that straw residue mulching (ST) and bio-char application combined with straw residue (ST+BC) can significantly reduce soil soluble nutrient loss when compared with the control treatment (CK). The comparative volume of the soil surface runoff after each of the treatments was as follows: CK > ST > ST + BC. Compared with the CK, the runoff volume of the ST was reduced by 13.6 % and 8.5 % in 2014 and 2015, respectively. Compared with the CK, combining bio-char with the ST application reduced the loss of soluble nitrogen and improved the soil total nitrogen content reaching a significant level in 2015. It dramatically increased the soil organic matter content over the two year period (36.3% in 2014, 50.6% in 2015) as well as the carbon/nitrogen ratio (C/N) (16.6% in 2014 and 39.3% in 2015). Straw mulching combined with bio-char showed a trend for increasing the citrus yield.

Carbon Nanotube DNA Bioconjugates as Nano-Bio Markers (탄소 나노튜브와 DNA와의 결합을 통한 나노-바이오 마커 응용)

  • Hwang Eung-Soo;Chengfan Cao;Hong Sang-Hyun;Jung Hye-Jin;Cha Chang-Yong;Choi Jae-Boong;Kim Young-Jin;Baik Seung-Hyun
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.668-671
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    • 2005
  • Carbon nanotubes exhibit strong fluorescence emissions in the region of near infrared regions where most biomolecules are transparent. Such signals are highly sensitive to environment variations as well as adsorption of specific biomolecules. In this research, single walled carbon nanotubes(SWNTs) are assembled with different types of DNAs and used to target specific types of DNAs. Dot blot investigations and corresponding raman spectroscopy observations demonstrated excellent selectivity of carbon nanotube-DNA bioconjugates. The results show possibility of using SWNT as generic nano-bio markers for precise detection of different kinds of genes.

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