• New & Renewable Energy
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• v.3 no.2 s.10
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• pp.17-23
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• 2007

대두유로부터 생산된 바이오디젤과 바이오디젤 혼합 연료유를 대상으로 지방산메틸에스터 함량과 화학적 분석을 통해 산화 특성과 오일의 수명 예측 연구를 수행하였다. 바이오디젤, 경유, BD5, BD20은 산화가 진행될수록 산가(Acid number), 동점도(Kinematic Viscosity) 및 밀도(Density)는 증가하였다. 산가 측정결과의 활용에 의해 임의의 온도조건에서 정확한 사용수명을 예측하기 위하여 화학속도론에 의거하여 각각의 연료에 대한 사용수명식을 도출하였다. 도출된 사용수명식으로부터 바이오디젤이 가장 빠르게 산화가 진행되었고 바이오디젤 혼합량이 증가할수록 사용수명이 단축되는 것을 확인할 수 있었다.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.6
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• pp.654-660
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• 2018

The dependence on global fossil fuels has been gradually reducing all over the world. Some countries which recognized the important of environmental values were joining to carry out international GHG goals. Our country has also participated with high targets (37% reduction compared to BAU 2030 years). So we need to supply materials of lower GHG value such as a bio-diesel. Bio-alcohol is one of the similar bio-fuels that can be reducing GHG. A lot of countries had tried to commercialize through various R&D for bio-alcohol. In this study, we analyzed the fuel characteristics of bio-alcohol fuel produced by domestic technology. And we evaluated a possibility to use as vehicle fuel through mixing of bio-alcohol and gasoline. The mixed fuels were satisfied with 2.3 wt% of oxygen content that is standard of the petroleum and petroleum alternative fuel business Act. We tried to evaluate a emission characteristic of vehicle by mixed fuel. In accordance with the results we tried to find a correlation between fuel and emission.

• Applied Chemistry for Engineering
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• v.23 no.4
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• pp.421-427
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• 2012

To improve the lubricity of ultra low sulfur diesel, vegetable oil-based alkanol amide derivatives were prepared and their lubricity properties were studied. To synthesize the alkanol amides, we conducted the amidation reaction of diethaolamine High Frequency Reciprocating Rig (HFRR) and the fatty acid methyl esters, obtained by the continuous transesterification of methanol and several vegetable oil, such as soybean oil, palm oil and coconut oil. The synthesized amides were soluble in ultra low sulfur diesel in the concentration range of ca. 1 wt%; the lubricating properties of ultra low sulfur diesel containing 120 ppm of amides were measured using an HFRR method. It was found that the wear scar diameter in the pure ultra low sulfur diesel decreased significantly from 581 ${\mu}m$ to 305~323 ${\mu}m$ upon the addition of the amides, indicating that lubricating properties of the diesel were improved. On the other hand, the types of vegetable oils did not affect the wear scar diameters, implying that lubricating properties of the diesel did not depend strongly on the structures of alkyl groups of alkanol amide derivatives. When we measured the lubricating properties of the one type of diesels containing various amounts of alkanol amide, we observed that the wear scar diameter decreased drastically with increasing the amide concentration, meaning that the lubricity improved with the amide concentration.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.1
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• pp.152-157
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• 2008

The biodiesel becomes one of the favorite alternative fuel applied to diesel engines. This research aims to understand the physics of spray and combustion characteristics of a biodiesel fuel in a constant volume chamber. For spray visualization, biodiesel was injected into a combustion chamber and a high speed camera was applied at various combustion conditions. To investigate heat-release rates and flame propagations, spark was ignited on a hydrogen fuel for the premixed combustion and then biodiesel was injected directly. In addition, parametric study was made by various geometries of combustion chambers and temperatures of fuels and injection pressures. This technology may contribute to improve the performance of bio-diesel engine and reduce emissions in future.

• Microbiology and Biotechnology Letters
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• v.36 no.1
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• pp.1-5
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• 2008

Negative environmental consequences of fossil fuels and the concerns about their soaring prices have spurred the search for alternative energy sources. While other alternative energies-like solar, wind, geothermal, hydroelectric, and tidal-offer viable options for electricity generation, around 40% of total energy consumption requires liquid fuels like gasoline or diesel fuel. This is where bio-energy/biofuels is especially attractive, where they can serve as a practical alternative to oil. The production of liquid biofuels for transportation will depend upon a stable supply of large amount of inexpensive cellulosic biomass obtained on a sustainable basis. This paper reviewed development status of transportation bio-energy for vehicles, technical barriers to the production of cellulosic ethanol, and the global future of bio-diesel and ethanol production.

• KSBB Journal
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• v.11 no.2
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• pp.159-164
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• 1996

Transesterification of used frying oil was investigated to produce the bio-diesel oil. Experimental conditions included molar ratio of used frying oil to alcohol (1:3, 1:5 and 1:7), concentration of catalyst (0.5, 1.0 and 1.5 wt.%), ippe of catalyst(sodium melhoxide, NaOH and KOH), reaction temperature (30, 45 and $60^{\circ}C$), and types of alcohol(methanol, ethanol and butanol). The conversion of used frying oil increased with the alcohol mixing ratio and with the reaction temperature. The effect of the type of catalysts on conversion was not significant. The highest conversion was obtained when methanol was used as alcohol. Viscosity was a little higher with the ester product over grade #2 diesel oil. But the physical properties improved significantly with transesterification, resulting in similar fuel properties with those obtained for grade #2 diesel fuel.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.9
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• pp.1081-1086
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• 2014

An experimental study was performed in order to compare with the case of using pure diesel the characteristics of combustion pressure and exhaust emissions when the engine speed was changed in a CRDI 4-cylinder diesel engine using biodiesel( Canola oil) blended and pure diesel fuel. As a results, the combustion pressure was decreased with increasing biodiesel blended rate when engine speed was 1,000, 1,500, 2000(rpm). but the combustion pressure of the engine speed 2,500rpm was increased with increasing biodiesel blended rate. The emission results show, that CO was decreased with increasing biodiesel blended rate and engine speed. The emission of $CO_2$, NOx, were increased with increasing biodiesel blended rate and engine speed.

• Journal of Advanced Marine Engineering and Technology
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• v.39 no.7
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• pp.716-721
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• 2015

As the severity of environmental pollution has increased, restrictions on air pollution have been strengthened. Stringent regulations have been imposed, not only on marine diesel engines but also on automotive and industrial power plants. Thus, biofuels have been directly applied in practical engines and used in training ships for basic research. Even though a high biofuel percentage cannot be used in a training ship engine for safety reasons, because this type of engine is larger than those used in institutional laboratories, the results will provide important basic information that will allow organizations to determine the status of a large output. Biodiesel fuel was studied to determine how it would affect the combustion characteristics and exhaust emissions of a marine diesel generator engine. The main results can be summarized as follows. Because the physical and chemical compositions of biofuels are similar to those of diesel fuel, it was found that their practical use was possible in a training ship. The specific fuel consumption and NOx increased, whereas a tendency was found for carbon monoxide and soot to decrease. In addition, no significant pressure change difference was found between the diesel fuel and biofuels.

• Journal of Marine Bioscience and Biotechnology
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• v.7 no.1
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• pp.1-10
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• 2015

Bio diesel has advantages to reduce GHG(Greenhouse Gas) compare with the fossil fuel by using oil comes from plant/animal sources and even waste such as used cook oil. The diversity of energy feeds brings the positive effects to secure the national energy mix. In this circumstance, micro-algae is one of the prospective source, though some technical barriers. We analyzed the bio diesel which was derived from Dunaliella tertiolecta LB999 through the BD100 quality specifications designated by the law. From that result, it is revealed that the oxidation stability is one of the properties to be improved. In order to find the reason for low oxidation stability, we analyzed the oxidation tendency of each FAME components through some methods(EN 14111, EN14112, EN16091). In this study, we could find the higher double bond FAME portion, the more oxidative property(C18:1${\ll}C18:3$) in bio diesel and main unsaturated FAME group is acted as the key component deciding the bio diesel's oxidation stability. It is proved experimentally that C18:3 FAME are oxidized easily under the modified accelerated oxidation test. We also figure out low molecular weight hydrocarbon and FAME were founded as a result of thermal degradation. Some alcohol and aldehydes were also made by FAME oxidation. In conclusion, it is necessary to find the way to improve the micro-algal bio diesel's oxidation stability.

• Journal of Biosystems Engineering
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• v.30 no.6 s.113
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• pp.354-359
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• 2005

This is a fundamental study to develop a bio-gas utilization technology using livestock manure. Especially, this study was carried out to develop an engine using bio-gas. A bio-gas engine was designed and manufactured by modification of a diesel engine of 3 cylinders powering 13.31 kW/2800 rpm, changing the fuel supplying system fit for bio-gas. The result showed that, when the Air/Fuel ratio was controlled with fixed spark timing, the power of biogas-fueled engine is about $10.6{\~}14.6\%$ lower then that of LNG-fueled engine because of low volumetric efficiency. The engine output and torque was $11.85{\~}13.3$ kW, $39.5{\~}40.8\;N{\cdot}m$, respectively at the engine speed of 2600 rpm. Bio-gas consumption rate was 260.20 g/kW/hr, 315.20 g/kW/hr in engine speed or 1000 rpm, 2800 rpm, respectively.