• Title/Summary/Keyword: Bio composite

Search Result 252, Processing Time 0.027 seconds

Improvement of Frictional Property of BR/CIIR Composite Rubber for Shoes Outsole (운동화 겉창용 BR/CIIR 고무 복합체의 마찰특성 향상에 대한 연구)

  • Pyo, Kyungduk;Choi, Jungsu;Lee, Jongnyun;Park, Chacheol
    • Polymer(Korea)
    • /
    • v.37 no.3
    • /
    • pp.255-261
    • /
    • 2013
  • This paper introduced a new preparation method of a composite rubber by mixing BR (butadiene rubber) and CIIR (chloro-isobutyl rubber) for the purpose of improving frictional property of BR. Since BR has high abrasion and low frictional properties, its frictional property needs to be enhanced in order to be used as an outsole of a sport shoe. Such enhancement was difficult to achieve by simple blending of CIIR. In here, CIIR was added into BR matrix after CIIR was pre-crosslinked for a time period, and both high frictional and high abrasion resistance properties were achieved. Our experiments showed that the composite rubber blend of 60% of BR and 40% of pre-crosslinked CIIR had desired BR's frictional and abrasion resistance properties for sport shoes.

Pervaporative Recovery of Bio-butanol through Dense- and Composite-type PDMS Membranes (PDMS막을 이용한 바이오 부탄올 분리정제와 투과증발 특성에 관한 연구)

  • Kim, Jeong-Hoon;Ryu, Bi-Ho;Chang, Bong-Jun;Kim, Woo-Nyon
    • Membrane Journal
    • /
    • v.19 no.2
    • /
    • pp.157-164
    • /
    • 2009
  • Bio-butanol recovery by pervaporation was performed with dense and composite polydimethylsiloxane (PDMS) membranes. The pervaporative behavior of the membranes was investigated as a function of operation temperature $(20{\sim}40^{\circ}C)$ and membrane thickness $(100{\sim}1{\mu}m)$ using a series of aqueous BtOH model solutions $(1{\sim}5wt%)$. With the increment of the BtOH concentration in feed, the Butanol concentration in permeate, pervaporation selectivity of Butanol over water and Butanol permeation flux increased. As the operating temperature of feed solutions increased, the BtOH concentration in permeate, pervaporation selectivity and permeation flux increased markedly. As the thickness of the PDMS membrane decreased, permeation flux increased but pervaporation selectivity decreased. These results were explained in terms of high solubility and low diffusion resistance of BtOH over water toward hydrophobic and rubbery PDMS membranes.

The Preparation of Multi-walled CNT-PMMA Nanocomposite

  • Seo, D.W.;Yoon, W.J.;Park, S.J.;Jo, M.C.;Kim, J.S.
    • Carbon letters
    • /
    • v.7 no.4
    • /
    • pp.266-270
    • /
    • 2006
  • Multi-walled carbon nanotube-poly methyl methacrylate (MWNT/PMMA) nanocomposite has been prepared by in situ polymerization of MMA dispersed with MWNTs. The MWNTs were functionalized by nitric acid and sulfuric acid treatment, and this was confirmed by FTIR spectrometer. The solution mixture of MWNTs and MMA was partially polymerized at $80^{\circ}C$, followed by the addition of AIBN and polymerization at $50^{\circ}C$. The MWNT-PMMA composite was prepared by casting the pre-polymer on the glass plate, and the optical properties have been studied using UV-vis spectrometer. The acid treated MWNTs were well dispersed in MMA with fairly good dispersion stability, while flocculation and sedimentation was observed from raw MWNTs in MMA.

  • PDF

TENSILE BOND STRENGTH BETWEEN NON-PRECIOUS DENTAL ALLOY AND VENEERING REINFORCED COMPOSITE RESINS (치과용 비귀금속 합금과 전장용 강화형 복합레진의 인장결합강도)

  • Yang, Byung-Duk;Park, Ju-Mi;Ko, Sok-Min;Kang, Geon-Gu
    • The Journal of Korean Academy of Prosthodontics
    • /
    • v.38 no.4
    • /
    • pp.427-437
    • /
    • 2000
  • Recently the 2nd generation laboratory composite resins were introduced. Although the mechanical properties of these composite resins have been improved, there were some disadvantages such as discoloration, low abrasion resistance and debonding between metal and resin. The purpose of this study was to evaluate the tensile bond strength between non-pecious dental alloy(verabond) and four veneering reinforced composite resins ; Targis(Ivoclar Co., U.S.A.), Artglass(Kulzer CO., Germany), Sculpture(Jeneric Pentron Co., U.S.A.), and Estonia(Kurary Co., Japan). All test metal specimens were polished with #1,000 SiC paper, and sandblasted with $250{\mu}m$ aluminum oxide. After then. according to manufacturer's instructions metal adhesive primer and veneering resins were applied. All test specimens were divided into two groups. One group was dried in a desiccator at $25^{\circ}C$ for 3 days, the other group was subjected to thermal cycling($2,000{\times}$) in water($5/55^{\circ}C$). Tensile bond strength was measured using Instron Universal Testing machine and the fractured surface was examined under the naked eyes and scanning electron microscope. Within the limitations imposed in this study, the following conclusions can be drawn: 1. In no-thermal cycling groups, there were no significant differences between Estenia and VMK68 but there were significant differences between Targis, Artglass, Sculpture and VMK68(p<0.05). 2. In no-thermal cycling resin groups, the highest tensile bond strength was observed in Estenia and there were significant differences between Estenia and the other resins(p<0.05). 3. Before and after thermal cycling, there were significant differences in tensile bond strength of Targis and Artglass(p<0.05). The tensile bond strength of Artglass was decreased and that of Targis was increased. 4. In no-thermal cycling groups, Artglass showed mixed fracture modes(95%), but after thermal cycling, Artglass showed adhesive fracture modes(75%).

  • PDF

Effect of Surface Treatment of CdS-TiO2 Composite Photocatalysts with Film Type on Hydrogen Production (수소제조에 관한 박막형 CdS-TiO2 복합 광촉매계의 표면처리 효과)

  • Jang, Jum-Suk;So, Won-Wook;Kim, Kwang-Je;Moon, Sang-Jin
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.13 no.1
    • /
    • pp.34-41
    • /
    • 2002
  • CdS and $TiO_2$ nanoparticles were made by the precipitation method and sol-gel method, respectively, and they were mixed mechanically and then treated with the hydrothermal processing. CdS-$TiO_2$ composite particulate films were thus prepared by casting CdS-$TiO_2$ mixed sol onto $SnO_2$ conducting glass and a subsequent heat-treatment at $400^{\circ}C$. Again, the physico-chemical and photoelectrochemical properties of these films were controlled by the surface treatment with $TiCl_4$ aqueous solution. The photocurrents and the hydrogen production rates measured under the present experimental conditions varied in the range of $3.5{\sim}4.5mA/cm^2$ and $0.3{\sim}1.8cc/cm^2$-hr, respectively, and showed the maximum values at the $CdS/[CdS+TiO_2]$ mole ratio of 0.2. Also, the surface treatment with $TiCl_4$ aqueous solution caused a considerable improvement in the photocatalytic activity, Probably as a result of close contacts between the primary particles by the etching effect of $TiCl_4$ It was found that the photoelectrochemical performance of these particulate films could be effectively enhanced by this approach.

Reconstruction of Endodontically Treated Teeth using Post and Composite Resin in Three Cats (치아골절이 있는 고양이에서 근관치료 후 복합 레진과 포스트를 이용한 치아 재건술)

  • Heo, Su-Young;Kim, Nam-Soo
    • Journal of Veterinary Clinics
    • /
    • v.30 no.5
    • /
    • pp.380-383
    • /
    • 2013
  • This clinical report describes the dental treatment of canine teeth fractures in three cats. These animals were diagnosed by oral examination and dental radiography as having fractured teeth with pulpal exposure. After endodontic treatment was completed, root canal filling material was removed from the coronal access and a trial post placement was performed. The post was permanently cemented after shortening. Teeth were etched and a bonded composite resin core formed and then shaped using rotary instruments. Fractured canine teeth were treated without any complications observed during a six-month follow-up period, proving that fractured cat canine teeth can be treated successfully with root canal therapy followed by restorative treatment with posts and composite resin.

Preparation of EVA/Intumescent/Nano-Clay Composite with Flame Retardant Properties and Cross Laminated Timber (CLT) Application Technology (난연특성을 가지는 EVA/Intumescent/나노클레이 복합재료 제조 및 교호집성재(Cross Laminated Timber) 적용 기술)

  • Choi, Yo-Seok;Park, Ji-Won;Lee, Jung-Hun;Shin, Jae-Ho;Jang, Seong-Wook;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
    • /
    • v.46 no.1
    • /
    • pp.73-84
    • /
    • 2018
  • Recently, the importance of flame retardation treatment technology has been emphasized due to the increase in urban fire accidents and fire damage incidents caused by building exterior materials. Particularly, in the utilization of wood-based building materials, the flame retarding treatment technology is more importantly evaluated. An Intumescent system is one of the non-halogen flame retardant treatment technologies and is a system that realizes flame retardancy through foaming and carbonization layer formation. To apply the Intumescent system, composite material was prepared by using Ethylene vinyl acetate (EVA) as a matrix. To enhance the flame retardant properties of the Intumescent system, a nano-clay was applied together. Composite materials with Intumescent system and nano - clay technology were processed into sheet - like test specimens, and then a new structure of cross laminated timber with improved flame retardant properties was fabricated. In the evaluation of combustion characteristics of composite materials using Intumescent system, it was confirmed that the maximum heat emission was reduced efficiently. Depending on the structure attached to the surface, the CLT had two stages of combustion. Also, it was confirmed that the maximum calorific value decreased significantly during the deep burning process. These characteristics are expected to have a delayed combustion diffusion effect in the combustion process of CLT. In order to improve the performance, the flame retardation treatment technique for the surface veneer and the optimization technique of the application of the composite material are required. It is expected that it will be possible to develop a CLT structure with improved fire characteristics.

Study of Non Pressure and Pressure Foam of Bio-based Polymer Containing Blend (바이오 기반 폴리머가 포함된 블렌드의 상압 및 가압 발포 연구)

  • Dong-Hun Han;Young-Min Kim;Danbi Lee;Seongho Son;Geon-hee Seo;Hanseong Kim
    • Composites Research
    • /
    • v.36 no.5
    • /
    • pp.297-302
    • /
    • 2023
  • There are several methods for shaping foams, but the most commonly used methods involve the use of resin mixed with a foaming agent, which is then foamed under high temperature and pressure in the case of compression foaming, or foamed under high temperature without applying pressure in the case of atmospheric foaming. The polymers used for foaming require design and analysis of optimal foaming conditions in order to achieve foaming under ambient pressure. Environmentally friendly bio-based polymers face challenges when it comes to foaming on their own, which has led to ongoing research in blending them with resins capable of traditional foam production. This study investigates changes in the characteristics of bio-based polymer-EVA blend foams based on variations in the content of bio-based polymers and explores the optimal foaming conditions according to crosslinking. The correlation between foaming characteristics and mechanical properties of the foams was examined. Through this research, we gained insights into how the content of bio-based polymers affects the properties of foams containing bio-based polymers and identified differences between ambient pressure and high-pressure foaming processes. Additionally, the feasibility of commercializing bio-based polymer-EVA composite foams was confirmed.

Mechanical Properties of Corn Husk Flour/PP Bio-composites

  • Jagadeesh, Dani.;Sudhakara, P.;Lee, D.W.;Kim, H.S.;Kim, B.S.;Song, J.I.
    • Composites Research
    • /
    • v.26 no.4
    • /
    • pp.213-217
    • /
    • 2013
  • The focus in the present work is to study the agro-waste corn husk bio-filler as reinforcement for polypropylene. These materials have been created by extrusion and injection molding. The effect of filler content by 10, 20, 30 and 40 wt. % and mesh sizes of 50~100, 100 and 300 on the mechanical properties was studied. For the un-notched specimens, the results of flexural strength showed a declining trend with increase the filler loading and the results of impact strength showed an increasing trend with increase the mesh size. In contrast, enhanced flexural modulus was observed with increasing filler loading and size.

Electro-optic Characteristics of Polymer Dispersed Liquid Crystal Films

  • Yang, Kee-Jeong;Kim, Chang-Geun;Lee, Seung-Chul;Do, Yun-Seon;Kim, Bae-In;Choi, Byeong-Dae
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2009.10a
    • /
    • pp.902-903
    • /
    • 2009
  • Polymer Dispersed Liquid Crystal (PDLC) films were prepared using the phase separation method with liquid crystal and a newly developed prepolymer. This study investigated the electro-optic characteristics of the PDLC film at various temperatures. It was found that as temperatures increased, the voltage varied, and that the ordinary refractive index of the liquid crystal and the polymer refractive index in the composite had similar dependence at various temperatures.

  • PDF