• Applied Chemistry for Engineering
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• v.33 no.4
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• pp.381-385
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• 2022

It is very important to secure the adhesion durability between the base film and the conductive paste for the development of a sensor for detecting hazardous chemicals. In this study, an ester binder was used to improve the adhesive properties which can be a problem when applying the sensor to the cross cut 0B or 1B grade. This problem was found while evaluating the adhesive properties by coating the polyaniline/graphene nano plate (GNP) paste on the polyethylene terephthalate (PET) film. When 10 wt% or more of the ester-based binder was added, the cross cut grade to which the sensor can be applied was 3B or higher. It was confirmed that the excessive addition of the binder may affect the electrical properties of the conductive paste and actually decrease the reactivity to sulfuric acid. To improve the electrical property, a carbon black (CB) content was varied resulting in the optimum electrical property observed at 2 wt% of CB.

• Journal of the Optical Society of Korea
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• v.10 no.1
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• pp.1-10
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• 2006

Optical transparency and high diffraction efficiency are two essential factors for high performance of the photopolymer. Optical transparency mainly depends on the miscibility between polymer binder and photopolymerized polymer, while diffraction efficiency depends on the refractive index modulation between polymer binder and photopolymerized polymer. For most of organic materials, the large refractive index difference between two polymers accompanies large structural difference that leads to the poor miscibility and thus poor optical quality via light scattering. Therefore, it is difficult to design a high-performance photopolymer satisfying both requirements. In this work, first, we prepared a new phase-stable photopolymer (PMMA) with large refractive index modulation and investigated the optical properties. Our photopolymer is based on modified poly (methyl methacrylate) as a polymer binder, acryl amide as a photopolymerizable monomer, triethanolamine as initiator, and yellow eosin as a photosensitizer at 532 nm. Diffraction efficiency over 85% and optical transmittance over 90% were obtained for the photopolymer. Second, Organic-inorganic nanocomposite films were prepared by dispersing an aromatic methacrylic monomer and a photo- initiator in organic-inorganic hybrid sol-gel matrices. The film properties could be controlled by optimizing the content of an organically modified silica precursor (TSPEG) in the sol-gel matrices. The photopolymer film modified with the organic chain (TSPEG) showed high diffraction efficiency (> 90%) under an optimized condition. High diffraction efficiency could be ascribed to the fast diffusion and efficient polymerization of monomers under interference light to generate refractive index modulation. The TSPEG modified photopolymer film could be successfully used for holographic memory.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.30 no.5
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• pp.318-324
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• 2017

Powder compaction technology is widely used to prepare thermal battery components. This method, however, is limited by the size, thickness, and geometry of the battery components. This limitation leads to excessive cell capacity, overweight, and higher cost of the pellets, which decreases the specific capacities and delays the activation time of thermal batteries. $FeS_2$ thin-film cathodes were fabricated by tape-casting technology and analyzed by SEM and EDS in this paper. The residual organic binder of the $FeS_2$ thin-film cathodes decreased with the temperature of the heat treatment, which improved the specific capacity because of the lower resistance. Specific capacities of the $FeS_2$ thin-film cathodes decreased because of the higher residual binder and the restrictive reaction of active materials with molten salts as the thickness increased. $FeS_2$ thin-film cathodes showed much higher specific capacity (1,212.2 As/g) than pellet cathodes (860.7 As/g) at the optimal heat-treatment temperature ($230^{\circ}C$).

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.07a
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• pp.467-469
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• 2001

KAM200 which can be used electroluminescence binder is cyano material. In this study, we have fabricated KAM200 thin film by Spin-Coating method. And we have studied the electical properties of KAM200 thin films. In the I-V characteristics, the current decreases as the voltage overflow definite voltage immediately. And that definite voltage depend on thickness of KAM200 material. In the case of thickness is 1.9[$\mu\textrm{m}$], definite voltage is 7[V]. And that's electrical field 3.86[MV/m]. The dielectric properties of KAM200 thin film is investigated by measuring dielectric dispersion and absorption. KAM200's Relative dielectric constant is 10.25, and it has high permittivity compared with different materials.

• International Journal of Highway Engineering
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• v.17 no.6
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• pp.55-63
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• 2015

PURPOSES : The objective of this study is to investigate the properties of recycled asphalt binders with five different rejuvenators, in order to evaluate the applicability of the recycled asphalt binders compared with the original asphalt binder. METHODS : In order to simulate recycled asphalt binders, fresh asphalt binders are aged by various Superpave aging procedures, such as the rolling thin-film oven (RTFO) and the pressure aging vessel (PAV). Then, selected rejuvenators are added to the aged asphalt binders in the amount of 5%, 10%, and 15%. The asphalt binder properties are evaluated by the dynamic shear rheometer (DSR), the rotational viscometer (RV), and the bending beam rheometer (BBR). In this study, AP-5 (penetration grade 60-80, PG 64-16) asphalt binder is used. A total of five types of rejuvenators are employed. RESULTS AND CONCLUSIONS : When considering aged asphalt without a new asphalt binder, it seems that the percentage of rejuvenator used in Korea is a bit too low, and that it fails to possess the characteristics of the original binder. From the current practice of evaluating the properties of recycled binder based on penetration ratio only, the amount of rejuvenator required is similar for the long-term-aged binder, but is excessive for the longest-term aged binder, causing deterioration of workability and stiffness of the recycled binder.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.330-330
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• 2007

Polycrystalline mercuric iodide $HgI_2$) films are being developed as a new detector technology for digital x-ray imaging. The $HgI_2$ is generally vacuum deposited by physical vapor deposition (PVD) process. But the PVD thick deposition has been caused any instability in the biasing due to any defects or cracks. In this work we present a new particle-in-binder (PIB) methodologies used for the $HgI_2$ thick films. These growth techniques can be easily extended to produce much larger film areas. This paper, for the first time, presents results and comparison of polycrystalline $HgI_2$ films derived by various PIB methods. We investigated the structural and morphological properties of the films using X-ray diffraction (XRD) and scanning electron microscopy (SEM) analysis. The films were characterized with respect to their electrical properties and in response to x-ray photons. Physical and electrical results were also compared between conventional polycrystalline PVD and our detectors. Leakage current as low as $350\;pA/cm^2$ at the bias voltage of ~ 200 V has been observed. And high sensitivity and good linearity in the response to x-rays was obtained in the film derived by PIB sedimentation method. Our future efforts will concentrate on optimization of film growth techniques for uniform large area deposition on image readout arrays.

• Journal of the Korean Graphic Arts Communication Society
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• v.26 no.2
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• pp.31-43
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• 2008

The functional dyes, which has various optical characteristics that can be applicable to field of electronic, photo electronic, such as sensor or electrode, were synthesized. Physical property and optical stability was studied with preparation of conductive type film as a kind of optical filter of plasma display panel, by adapting neon cut off dye, which can selectively absorbing between 580 and 610nm wavelength. The filter was prepared with PSA resin, which has functional group of - COOH and - OH, as binder. And the characters such as spectroscopy, heat-proof / wet-proof, thermal stability and commerciality, which must be held by functional dyes, were examined. Conductive type film is the kind of film includes only neon cut off dyes. For the neon cut off dyes, cyanine dyes can be applied. And it is observed that spectrum of before and after the durability test are not changed due to stability of dyes, as the result of coating on the mesh film with PSA binder.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2005.10a
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• pp.97-101
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• 2005

High strength concretes utilizing EVA with micro particles were prepared by varying polymer/binder mass ratio and curing conditions with a constant water/binder mass ratio of 0.3. The EVA modified concretes on the compressive and flexural strength, microstructure, ultrapulse modulus in curing condition(dry and water curing) were studied. Also, scanning electron microscope analysis(SEM) was performed to reveal the presence of polymer film and cement hydrates in the concrete. The compressive strength of the EVA modified concretes cured at water conditions ere higher than that of the EVA modified concretes cured at dry conditions. But, the flexural strength of the specimens cured at dry conditions were higher than that of the specimens cured at water conditions. Due to the interaction of the cement hydrates and polymer film, an interpenetrating network originated in which the aggregates were embedded. The curing of the polymer modified concrete involves two step of cement hydrates and polymer modification, and cement hydrates was promoted in water conditions and polymer film formation take place when water evaporates and was thereby was favored in dry conditions. By SEM analysis, influences of polymer modification was strengthening of the transition zone between the aggregate and the paste, and the porosity of transition zone decreases. By spring analysis, it could known that polymer film affects in porosity decrease and strengthening of transition zone.

• 한국신재생에너지학회:학술대회논문집
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• 2009.11a
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• pp.396-396
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• 2009

Chalcopyrite semiconductor $CuInSe_2$ nanoparticles were prepared using a low temperature colloidal route by reacting the starting materials (CuI, $InI_3$ and $Na_2Se$) in solvents. After synthesised $CuInSe_2$ nanoparticles precursors were mixed with organic binder for the viscosity of the precursor slurry to be suitable for the doctor blade method. The mixture of $CuInSe_2$ and binder was deposited onto molybdenum-coated sodalime glass substrates to form thin film. The precursor thin films were preheated on the hot plate to remove remaining solvents and binder material. After subsequent thermal processing of the thin film under a selenium ambient, $CuInSe_2$ absorber layer with grain size significantly lager than that of the nanoparticles was formed.

• 한국신재생에너지학회:학술대회논문집
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• 2006.06a
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• pp.222-224
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• 2006

A non-vacuum process for $Cu(In,Ga)Se_2$ (CIGS) thin film solar cells from nanoparticle precursors was described in this work CIGS nanoparticle precursors was prepared by a low temperature colloidal route by reacting the starting materials $(CuI,\;InI_3,\;GaI_3\;and\;Na_2Se)$ in organic solvents, by which fine CIGS nanoparticles of about 20nm in diameter were obtained. The nanoparticle precursors were mixed with organic binder material for the rheology of the mixture to be adjusted for the doctor blade method. After depositing the mixture of CIGS with binder on Mo/glass substrate, the samples were preheated on the hot plate in air to evaporate remaining solvents ud to burn the organic binder material. Subsequently, the resultant (porous) CIGS/Mo/glass simple was selenized in a two-zone Rapid Thermal Process (RTP) furnace in order to get a solar ceil applicable dense CIGS absorber layer. Complete solar cell structure was obtained by depositing. The other layers including CdS buffer layer, ZnO window layer and Al electrodes by conventional methods. The resultant solar cell showed a conversion efficiency of 0.5%.