• Advances in materials Research
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• v.9 no.3
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• pp.219-231
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• 2020

The aim of this study is to investigate the durability of fly ash based geopolymer mortar with and without protective coatings in aggressive chemical environments. The source materials for geopolymer are Fly ash and Ground Granulated Blast furnace Slag (GGBS) and they are considered in the combination of 80% & 20% respectively. Two Molarities of NaOH solution were considered such as 8M and 10M. The ratio of binder to sand and Sodium silicate to Sodium hydroxide solution (Na₂SiO₃/NaOH) are taken as 1:2 and 2 respectively. The alkaline liquid to binder ratio is 0.4. Compressive strength tests were conducted at various ages of the mortar specimens. In order to evaluate the performance of coatings on geopolymer mortar under aggressive chemical environment, the mortar specimens were coated with two different types of coatings such as epoxy and Acrylic. They were then subjected to different chemical environments by immersing them in 10% standard solutions of each ammonium nitrate, sodium chloride and sulphuric acid. Drop in compressive strength as a result of chemical exposure was considered as a measure of chemical attack and the drop in compressive strength was measured after 30 and 60 days of chemical exposure. The compressive strength results following chemical exposure indicated that the specimens containing the acrylic coating proved to be more resistant to chemical attacks. The control specimen without coating showed a much greater degree of deterioration. Therefore, the application of acrylic coating was invariably much more effective in improving the compressive strength as well as the resistance of mortar against chemical attacks. The results also indicated that among all the aggressive attacks, the sulphate environment has the most adverse effect in terms of lowering the strength.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.24 no.1
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• pp.27-32
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• 2014

This study analyzed the fundamental characteristics of concrete according to a ternary system mixing in order to reduce hydration heat of mass concrete and to improve early age strength. The results are as follows. The fluidity of unconsolidated concrete satisfied the target scope regardless of the binder conditions. When the replacement ratio between FA and BS increased, the slump of low heat-A mix and low heat-B mix increased, and air content was not affected by the change of binders. As for setting time, low heat cement mix had the fastest regardless of W/B, and high early strength low heat mix achieved 6 hours' reduction compared with low heat-B mix at initial set, and 12 hours' reduction at the final set respectively. As for the simple hydration heat, the low mix peak temperature was the highest and low heat-B mix had the lowest temperature. And high early strength low heat mix was similar with that of low heat-B. The compressive strength of hardened concrete had similar strength scope in all mixes except for low heat-B mix at early ages, and had unexceptionally similar one without huge differences at long-term ages.

• Proceedings of the SCSK Conference
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• 1999.10a
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• pp.97-110
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• 1999

The new stick make-up product was studied by using a gel, which is a viscous complex formed with clay minerals, vitamins A and I and fluorinated liquid polymer with a 1500 molecular weight. The gel cannot be obtained with any random combination of clay minerals and the ingredients described above. It takes the sequential manufacturing method as follows to get this kind of gel. Firstly, clay minerals and liquid polymers have ·to be pre-mixed in order to saturate the liquid polymers with the clay minerals. Then tile on-processed gel has to be finely crystallized. The clay minerals, which are the core elements for this gel, were used as a function of Binder & Buffer and liquid polymer was mixed together for the deterioration of the surface tension of each component and to from a functional film in the gel. This liquid polymer was combined with clay minerals because it is not miscible with most oils and solvents. Waxes have a function of keeping a solid status in the stick. We reduced the usage of waxes by putting clay minerals as buffer in the proportion of 0.5 : 1 with oil phase. Ceramide takes care of the skin when used regularly and maintains the skin’s moisture. Vitamins A and I contribute to preventing skin’aging by the activation of skin cells. We could get the stable viscous gel, which has about 80% oil phase using clay minerals and liquid polymer, The crystal 1 me structures of gel were surface-chemical1y-analyzed using SEM and Image Analyzer and were thermodynamically analyzed using DSC, Surface tension test and softness were done by Rheometer. In the end, these characteristics were verified by consumer panel tests in Seoul, Baegeon and Pusan in Korea and Hokkaido, Oska and Miyazaki in Japan with correlation to the climate.

• Journal of the Korea Concrete Institute
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• v.16 no.5 s.83
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• pp.605-612
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• 2004

This study investigated the fundamental properties and shrinkage properties of high performance concrete with water/binder ratio of 0, 30 and with combination of expansive additive and shrinkage reducing agent. According to the results, the fluidity of high performance concrete showed lower the using method in combination with expansive additive and shrinkage reducing agent than the separately using method of that, so the amount of superplasticizer increased when the adding ratio of expansive additive and shrinkage reducing agent increased. However the air content of concrete increased when used in combination with expansive additive and shrinkage reducing agent, so the amount of AR agent decreased. The compressive strength showed the highest at $5\%$ of expansive additive, and decreased with an increase of the amount of shrinkage reducing agent. Furthermore, in order to reduce the shrinkage of high performance concrete, it was found that the using method in combination with expansive additive and shrinkage reducing agent was more effective than separately using method of that. Therefore, it analyzed that the combination of expansive additive of $5\%$ and shrinkage reduction agent of $1\%$ was the most suitable mixture, considering to the fluidity, strength and shrinkage under the condition of this experiment.

• Journal of the Korea Concrete Institute
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• v.28 no.5
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• pp.593-600
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• 2016

The paper presented investigates the effects of kaolinite on strength properties of alkali-activated multi-component cement. The binders of this study was blended of ground granulated blast furnace slag (GGBFS), fly ash (FA), silica fume (SF) and kaolinite (KA). In this study, the specimens of combination of 20%~70% GGBFS, 10%~60% FA, 10% SF (constant ratio) and 10%~50% KA binder were used for strength properties tests. The water/binder ratio was 0.5. The binders (GGBFS + FA + SF + KA) was activated by sodium hydroxide (NaOH) and sodium silicate ($Na_2SiO_3$) was 10% by total binder weight (10% NaOH + 10% $Na_2SiO_3$). The research carried out is on the compressive strength, water absorption, ultrasonic pulse velocity (UPV) and X-ray diffraction (XRD). The compressive strength decreased as the contents of KA increase. One of the major reason for this is the low reactivity of KA compared with other raw materials used as precursors such as GGBFS or FA. The presence of remaining KA indicates that the initially used quantity has not fully reacted during hydration. Moreover, the results have indicated that increased of KA contents decreased UPV under all experimental conditions. The drying shrinkage and water absorption increased as the content of KA increase. Test result clearly showed that the strength development of multi-component blended cement were significantly dependent on the content of KA and GGBFS.

• Computers and Concrete
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• v.12 no.6
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• pp.785-802
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• 2013

Ready-mixed soil material, known as a kind of controlled low-strength material, is a new way of soil cement combination. It can be used as backfill materials. In this paper, artificial neural network and nonlinear regression approach were applied to predict the compressive strength of ready-mixed soil material containing Portland cement, slag, sand, and soil in mixture. The data used for analyzing were obtained from our testing program. In the experiment, we carried out a mix design with three proportions of sand to soil (e.g., 6:4, 5:5, and 4:6). In addition, blast furnace slag partially replaced cement to improve workability, whereas the water-to-binder ratio was fixed. Testing was conducted on samples to estimate its engineering properties as per ASTM such as flowability, strength, and pulse velocity. Based on testing data, the empirical pulse velocity-strength correlation was established by regression method. Next, three topologies of neural network were developed to predict the strength, namely ANN-I, ANN-II, and ANN-III. The first two models are back-propagation feed-forward networks, and the other one is radial basis neural network. The results show that the compressive strength of ready-mixed soil material can be well-predicted from neural networks. Among all currently proposed neural network models, the ANN-I gives the best prediction because it is closest to the actual strength. Moreover, considering combination of pulse velocity and other factors, viz. curing time, and material contents in mixture, the proposed neural networks offer better evaluation than interpolated from pulse velocity only.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.32 no.4
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• pp.12-17
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• 2004

The PSP technique has been used to measure pressure distribution on model surfaces ins high-speed flows. The objective of this study is to develop a PSP technique which can be applied to low-speed aerodynamic flows. Four different PSP formulations including two porphyrins (PtOEP and PtTFPP) and two polymers (Poly(TMSP) and RTV-118) were tested and the performance of each combination was evaluated. In a static calibration, the luminescent intensity of the PSP coatings was measured from 0kPa to 11kPa with 0.5, 1, 2kPa increments. Among 4 PSP formulations tested, the combination of PtOEP and RTV-118 shows the best performance. The developed PSP technique was applied to an oblique impinging jet to measure the pressure field distribution on the impinging plate.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.5
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• pp.34-40
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• 2014

High-performance fiber-reinforced cement composite (HPFRCC) shows very high autogenous shrinkage, because it contains a low water-to-binder ratio (W/B) of 0.2 and high fineness admixture without coarse aggregate. Thus, it needs a method to decrease the cracking potential. Accordingly, in this study, to effectively reduce the shrinkage of HPFRCC, a total of five different ratios of SRA (1% and 2%), EA (5% and 7.5%), and a combination of SRA and EA (1% and 7.5%) were considered. According to the test results of ring-test, a combination of SRA and EA (1% and 7.5%) showed best performance regarding restrained shrinkage behavior without significant deterioration of compressive and tensile strengths. This was also verified by performing modified drying shrinkage crack test.

• Advances in concrete construction
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• v.3 no.3
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• pp.203-221
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• 2015

This paper presents the results of a study undertaken to investigate the enhancement of concrete strength using Silpozz and Rice Husk Ash (RHA). The total percentage of supplementary cementitious material (SCM) substituted in this study was 20%. Six different concrete mixes were prepared such as without replacement of cement with silpozz and RHA (0% silpozz and 0% RHA) is treated as conventional concrete, whereas in other five concrete mixes cement was replaced by 20% of silpozz and RHA as (0% silpozz and 20% RHA), (5% silpozz and 15% RHA), (10% silpozz and 10% RHA), (15% silpozz and 5% RHA) and (20% silpozz and 0% RHA) with decreasing water-binder (w/b) ratio i.e. 0.375, 0.325 and 0.275 and increasing super plasticiser dose. New generation polycarboxylate base water reducing admixture i.e., Cera Hyperplast XR-W40 was used in this study. The results of this research indicate that as w/b decreases, super plasticiser dose need to be increased so as to increase the workability of concrete. The effects of replacing cement by silpozz and RHA on the compressive strength, split tensile strength and flexural strength were evaluated. The concrete mixture with different combination of silpozz and RHA gives higher strength as compared to control specimen for all w/b ratios and also observed that the early age strength of concrete is more as compared to the later age strength. It is also observed that the strength enhancement of concrete mixture prepared with the combination of cement, silpozz and RHA is higher as compared to the concrete mixture prepared with cement and silpozz or cement and RHA.

• Metals and materials international
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• v.24 no.6
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• pp.1256-1261
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• 2018

Both thermoplastic formability and electrical conductivity of Al-Ni-Y metallic glass with 12 different compositions have been investigated in the present study with an aim to apply as a functional material, i.e. as a binder of Ag powders in Ag paste for silicon solar cell. The thermoplastic formability is basically influenced by thermal stability and fragility of supercooled liquid which can be reflected by the temperature range for the supercooled liquid region (${\Delta}T_x$) and the difference in specific heat between the frozen glass state and the supercooled liquid state (${\Delta}C_p$). The measured ${\Delta}T_x$ and ${\Delta}C_p$ values show a strong composition dependence. However, the composition showing the highest ${\Delta}T_x$ and ${\Delta}C_p$ does not correspond to the composition with the highest amount of Ni and Y. It is considered that higher ${\Delta}T_x$ and ${\Delta}C_p$ may be related to enhancement of icosahedral SRO near $T_g$ during cooling. On the other hand, electrical resistivity varies with the change of Al contents as well as with the change of the volume fraction of each phase after crystallization. The composition range with the optimum combination of thermoplastic formability and electrical conductivity in Al-Ni-Y system located inside the composition triangle whose vertices compositions are $Al_{87}Ni_3Y_{10}$, $Al_{85}Ni_5Y_{10}$, and $Al_{86}Ni_5Y_9$.