• 한국염색가공학회지
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• 제23권2호
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• pp.90-99
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• 2011

The aim of this study is to develope eco-printing method using natural pigments and chitosan as a natural binder. Three chitosans with different molecular weights were employed to find appropriate conditions including chitosan concentration and pigment/binder ratio. Dye uptake, color and fastnesses of the printed fabrics were evaluated to find optimum conditions within the range of experiments carried out in this study. The effectiveness of chitosan as a printing binder was examined in comparison with color, dye uptake, and fastnesses of conventional synthetic binder and guar gum. It was found that chitosans with low or medium molecular weight were appropriate. Using low molecular weight chitosan, optimum concentrations were 1.7% for charcoal, madder and chlorophyll, whereas 2.2% for ocher, yellow soil, indigo and cochineal. Regardless of molecular weight and concentration of chitosan, the color fastnesess of fabrics printed with mineral pigments were superior to those of the fabrics printed with plant and animal pigments. As pigment/chitosan ratio became higher, rubbing fastness was decreased by 1-3 grade. The colorfastness of printed fabric with chitosan binder was similar to that with synthetic binder, which was higher than that with guar gum.

• International Journal of Concrete Structures and Materials
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• 제9권2호
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• pp.185-206
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• 2015

This paper presents statistical models developed to study the influence of key mix design parameters on the properties of lightweight self-consolidating concrete (LWSCC) with expanded shale (ESH) aggregates. Twenty LWSCC mixtures are designed and tested, where responses (properties) are evaluated to analyze influence of mix design parameters and develop the models. Such responses included slump flow diameter, V-funnel flow time, J-ring flow diameter, J-ring height difference, L-box ratio, filling capacity, sieve segregation, unit weight and compressive strength. The developed models are valid for mixes with 0.30-0.40 water-to-binder ratio, high range water reducing admixture of 0.3-1.2 % (by total content of binder) and total binder content of $410-550kg/m^3$. The models are able to identify the influential mix design parameters and their interactions which can be useful to reduce the test protocol needed for proportioning of LWSCCs. Three industrial class ESH-LWSCC mixtures are developed using statistical models and their performance is validated through test results with good agreement. The developed ESH-LWSCC mixtures are able to satisfy the European EFNARC criteria for self-consolidating concrete.

• Advances in concrete construction
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• 제10권3호
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• pp.237-245
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• 2020

Past research efforts already established geopolymer as an environment-friendly alternative binder system for ordinary Portland cement (OPC) and recycled aggregate is also one of the promising alternative for natural aggregates. In this study, an effort was made to produce eco-friendly mortar mixes using geopolymer as binder and recycled fine aggregate (RFA) partially and study the resistance ability of these mortar mixes against the aggressive environments. To form the geopolymer binder, 70% fly ash, 30% ground granulated blast furnace slag (GGBS) and alkaline solution comprising of sodium silicate solution and 14M sodium hydroxide solution with a ratio of 1.5 were used. The ratio of alkaline liquid to binder (AL/B) was also considered as 0.4 and 0.6. In order to determine the resistance ability against aggressive environmental conditions, acid attack test, sulphate attack test and rapid chloride permeability test were conducted. Change in mass, change in compressive strength of the specimens after the immersion in acid/sulphate solution for a period of 28, 56, 90 and 120 days has been presented and discussed in this study. Results indicated that the incorporation of RFA leads to the reduction in compressive strength. Even though strength reduction was observed, eco-friendly mortar mixes containing geopolymer as binder and RFA as fine aggregate performed better when it was produced with AL/B ratio of 0.6.

• 한국염색가공학회지
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• 제30권4호
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• pp.256-263
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• 2018

The binder polymers for digital textile printing(DTP) pigment inks were prepared using miniemulsion polymerization with various monomer compositions to study effects of monomer compositions on particle size distribution, average molecular weight, Tg, and color strength and rubbing fastness of the dyed fabrics with the prepared binder based pigment ink. The monomers used were MMA(Methyl methacrylate), BA(Butyl acrylate), MAA(Methacrylic acid), NMA(N-methylol acrylamide), NEA(N-ethylol acrylamide) and the ratios of the monomers were changed. The particle size was the smallest with 136nm when the MMA to BA weight ratio was 4:16 and the largest with 290nm when the MMA, BA, MAA, NEA ratio was 2.5:17:0.25:0.25. However, the glass transition temperature was lowest with $-41.90^{\circ}C$ and the color strength and rubbing fastness of the resulting sample were the best when the MMA, BA, MAA, NEA ratio was used. This suggested that the introduction of the NEA monomer to the binder polymer for the pigment ink could be an efficient way to enhance the rubbing fastness of the DTP pigment inks present.

• 한국건축시공학회지
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• 제8권6호
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• pp.131-137
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• 2008

In recent years, the light-weight aggregate has widely been used to reduce the weight of construction structures, and to achieve the thermal insulation of building structures. The purpose of this study is to evaluate the heat resistance of polymer concrete composites with light-weight aggregate made by binders as resin and cement with polymer dispersion. The light-weight polymer concrete composites are prepared with various conditions such as binder content, filler content, void-filling ratio, light-weight aggregate content and polymer-cement ratio, and tested for heat resistant test, and measured the weight reducing ratio, strengths and exhaustion content of gas such as CO, NO and $SO_2$. From the test results, the weight reducing ratio of light weight polymer concrete using UP binder after heat resistance test increase with an increase in the UP content irrespective of the filler content. The weight reducing ratio of polymer cement concrete is considerably smaller than that of UP concrete. In general, the strengths after heat resistance of polymer concrete composites are reduced about 40 to 65% compared with those before test. The exhausted quantity of CO, NO and $SO_2$ gases in polymer concrete composites is less than EPS(Expanded poly styrene). From the this study, it is confirmed that the many types gases discharge according to binder type of polymer concrete composites, its amount is controlled by selection of the binder type and mix proportions.

• 한국농공학회논문집
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• 제46권5호
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• pp.79-85
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• 2004

This study was performed to evalute mechanical and drying shrinkage properties of polypropylene fiber reinforced high flow concrete. The compressive strength and drying shrinkage ratio were increased with increasing the binder volume ratio and decreased with increasing the content of polypropylene fiber. The splitting tensile strength was increased with increasing the binder volume ratio and the content of polypropylene fiber. The flexural strength was increased with increasing the binder volume ratio and increased by the polypropylene fiber content 0.4%, but above the polypropylene fiber content 0.6% was decreased. This concrete can be used for high flow concrete.

• 펄프종이기술
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• 제34권2호
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• pp.22-31
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• 2002

In this paper, PVA(polyvinylalcohol), oxidized starch and SBR latex were used as binders for ink-jet printing papers, and their effects of the type and blending ratio of binders on ink-jet printing properties were compared. In case of coating color using PVA mainly used for a binder in ink-jet printing, spreading of printed letters decreased and excellent images were manifested resulting from strong hydrophilic of PVA. However, increasing solids content of coating color was somewhat limited because of the interaction of PVA and functional groups in silica as well as high molecular weight of PVA. When oxidized starch and SBR latex were mixed with PVA at desirable ratio to solve these problems, runnability in coating process was improved and good printing properties were shown. Gloss was improved when latex was used along with PVA as a binder because of the thermoplastic property of the latex. From this result, possibilities of high solids content and high gloss ink-jet printing papers were investigated.

• 한국농공학회:학술대회논문집
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• 한국농공학회 2005년도 학술발표논문집
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• pp.123-127
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• 2005

EVA Powder modified high strength concretes were prepared by varying polymer/binder mass ratio with a constant water/binder mass ratio of 0.3. The effect of EVA powder on the slump, hydration heat, compressive and flexural strength, toughness and water absorption ratio was studied. In hydration heat test, temperature of hydration reaction displayed almost fixed level regardless of containing rate of EVA powder, but peak time of hydration reaction displayed late inclination as containing rate of powder increases. With the same water/binder mass ratio, the compressive strength and water absorption of EVA powder modified concretes decreased slightly when EVA powder was added and the flexural strength of EVA powder modified concretes rised slightly when EVA powder was added. Also, the toughness of the modified concretes can be improved markedly. The interpenetrating structure between the polymeric phase and cement hydrates formed at a $2{\sim}6%$(containing rate of EVA powder). The properties of the polymer modified concretes were influenced by the polymer film, cement hydrates and the combined structure between the organic and inorganic phases.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.513-516
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• 2004

The purpose of this study is to investigate properties of porous concrete according to volume of binder and compaction energy. The result of this study, as compaction energy goes on increasing, the actual measured void ratio is decreased according as a change of compaction energy and volume of binder. The compaction energy has a very near value by target void ratio on the whole when it is $50kN{\cdot}m/m^2,\;50\~75kN{\cdot}m/m^2$ in case of target void ratio is $15\%\;and\;25\%$. As compaction energy goes on increasing, compressive strength of specimens picked up when target void ratio is $20\%\;and\;25\%$. Also, compressive strength of specimens bluntly picked up when compaction energy is over $50\~75kN{\cdot}m/m^2$.

• 한국구조물진단유지관리공학회 논문집
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• 제5권3호
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• pp.153-162
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• 2001

This paper presents the fundamental study on rational manufacture of Ultra High Strength(VHS) concrete using industrial by-products as like silica fume, slag and fly ash. In this study, we had tested various mixing cases to manufacture the UHS concrete(target compressive strength : over $1,000kgf/cm^2$) which is easily workable (target slump flow : $60{\pm}10cm$). The main variables are studied: 1) to find the optimum replacement ratio of mineral admixture. 2) to find a rational water-binder ratio and a proper binder content. 3) to find the method for reduction of slump loss. From the test results, it is concluded that the rational mix design can be made by using 40% slag, 10% silica fume. We found that compressive strength of UHS concrete increases according to decreasing W/B ratio but in W/B ratio 18~20%, the difference is vague and the compressive strength does not necessarily increase according to increasing binder content over 700kg.