• Title/Summary/Keyword: Binary properties

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Measurement of Mutual Solubility of High-pressure Gaseous Fire Extinguishing Agents(HFCs) and Nitrogen (고압가스계 소화약제(HFCs계열)와 질소의 상호용해도 측정)

  • 임종성;박지영;이병권;김재덕;이윤용
    • Fire Science and Engineering
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    • v.16 no.3
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    • pp.26-31
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    • 2002
  • Bromotrifluoromethane(halon-1301) and bromochlorodifluoromethane(halon-1211) have been widely used as a clean fire extinguishing agents due to their outstanding properties. However, production and use of halon are currently being phased out under an international agreements Montreal Protocol because of global environmental concerns and HFCs have been considered as promising alter-natives for the replacement of halon since their ozone depletion potentials are low. The vapor-liquid equilibrium data are required as important basic information in evaluating the solubility of clean fire extinguishing agents and determining their optimal compositions. In this work, we chose HFCs such as HFC-22 HFC-125, and HFC-l34a for gaseous fire extinguishing agents and nitrogen as a pressurization gas for a proper jet velocity of these agents. Phase equilibria for binary mixtures of nitrogen/HFC-22, nitrogen/HFC-125, and nitrogen/HFC-l34a were measured in the temperature range from 283.15K to 303.15K. For equilibrium measurement, we used a circulation type apparatus in which both vapor and liquid phases were continuously recirculated. The experimental data were relatively well correlated with the Peng-Robinson equation of state with Wong-Sandier mixing rules.

The Properties of Internal Temperature of Paste and Concrete according to Component Ratio Variation of Ternary System Cement (3성분계 시멘트의 구성비 변화에 따른 페이스트 및 콘크리트의 내부온도 특성)

  • Kim, Yeon-Seung;Kim, Dong-Hyeok;Jee, Nam-Yong
    • Journal of the Korea Concrete Institute
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    • v.20 no.6
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    • pp.797-807
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    • 2008
  • For this study, the semi-adiabatic temperature rising test is accomplished by using ternary system cement (OPC, BFS, FA) reducing temperature crack. Two tests are conducted; one is for the paste test, and the other is for the concrete test. As the results of paste tests, using fly ash is better to reduce hydration temperature than doing blast furnace slag. In the case of the paste mixed ternary system cement, the more fly ash is mixed and the less blast furnace slag is used, the lower the temperature is. The less the mixture ratio of blast furnace slag is and the more the mixture ratio of fly ash is, the later the temperature rising velocity and descending velocity are. Besides, the temperature is lower if water/binder ratio is high. The use of ternary system cement has the retardation effect of temperature rising because the time to reach the maximum temperature is in the order of OPC100, binary system cement, and ternary system cement. From the test, the maximum temperature of concrete used ternary system cement is $8{\sim}11^{\circ}C$ lower than that of concrete used OPC100. Moreover, temperatures rising velocity and descending velocity of ternary system cement range $47{\sim}51%$ and $37{\sim}42%$ compared with OPC100. The specimen of concrete shows remarkable low internal temperature and slow temperature rising velocity and descending velocity compared with the specimen of paste because it is that temperature loss of concrete is much more than paste specimen according to aggregates.

A study on the teaching of algebraic structures in school algebra (학교수학에서의 대수적 구조 지도에 대한 소고)

  • Kim, Sung-Joon
    • Journal of the Korean School Mathematics Society
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    • v.8 no.3
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    • pp.367-382
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    • 2005
  • In this paper, we deal with various contents relating to the group concept in school mathematics and teaching of algebraic structures indirectly by combining these contents. First, we consider structure of knowledge based on Bruner, and apply these discussions to the teaching of algebraic structure in school algebra. As a result of these analysis, we can verify that the essence of algebraic structure is group concept. So we investigate the previous researches about group concept: Piaget, Freudenthal, Dubinsky. In our school, the contents relating to the group concept have been taught from elementary level indirectly. Tn elementary school, the commutative law and associative law is implicitly taught in the number contexts. And in middle school, various linear equations are taught by the properties of equality which include group concept. But these algebraic contents is not related to the high school. Though we deal with identity and inverse in the binary operations in high school mathematics, we don't relate this algebraic topics with the previous learned contents. In this paper, we discussed algebraic structure focusing to the group concept to obtain a connectivity among school algebra. In conclusion, the group concept can take role in relating these algebraic contents and teaching the algebraic structures in school algebra.

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Design and Analysis of Code Sequence Generating Algorithms using Almost Perfect Nonlinear Functions (APN 함수를 이용한 부호계열 발생 알고리즘 설계 빛 분석)

  • Lee, Jeong-Jae
    • Journal of the Institute of Convergence Signal Processing
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    • v.11 no.1
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    • pp.47-52
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    • 2010
  • For cryptographic systems, nonlinearity is crucial since most linear systems are easily decipherable. C.Bracken, Z.Zhaetc., propose the APN(Almost Perfect Nonlinear) functions with the properties similar to those of the bent functions with perfect nonlinearity. We design two kinds of new code sequence generating algorithms using the above APN functions. And we find that the out of phase ${\tau}\;{\neq}\;0$, autocorrelation functions, $R_{ii}(\tau)$ and the crosscorrelation functions, $R_{ik}(\tau)$ of the binary code sequences generated by two new algorithms over GF(2), have three values of {-1, $-1-2^{n/2}$, $-1+2^{n/2}$}. We also find that the out of phase ${\tau}\;{\neq}\;0$, autocorrelation functions, $R_{p,ii}(\tau)$ and the crosscorrelation functions, $R_{p,ik}(\tau)$ of the nonbinary code sequences generated by the modified algorithms over GF(p), $p\;{\geq}\;3$, have also three values of {$-1+p^{n-1}$, $-1-p^{(n-1)/2}+p^{n-1}$, $-1+p^{(n-1)/2}p^{n-1}$}. We show that these code sequences have the characteristics of the correlation functions similar to those of Gold code sequences.

Characterization and Formation Mechanism of Zr-Cu and Zr-Cu-Al Metallic Glass Thin Film by Sputtering Process

  • Lee, Chang-Hun;Sun, Ju-Hyun;Moon, Kyoung-Il;Shin, Seung-Yong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.271-272
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    • 2012
  • Bulk Metallic Glasses (BMGs or amorphous alloy) exhibit high strength and good corrosion resistance. Applications of thin films and micro parts of BMGs have been used a lot since its inception in the research of BMGs. However, Application and fabrication of BMGs are limited to make structural materials. Thin films of BMGs which is sputtered on the surface of structural materials by sputtering process is used to improve limits about application of BMGs. In order to investigate the difference of properties between designed alloys and thin films, we identified that thin films deposited on the surface that have the characteristic of the amorphous films and the composition of designed alloys. Zr-Cu (Cu=30, 35, 38, 40, 50 at.%) and Zr-Cu-Al (Al=10 at.% fixed, Cu=26, 30, 34, 38 at.%) alloys were fabricated with Zr (99.7% purity), Cu (99.997% purity), and Al (99.99% purity) as melting 5 times by arc melting method before rods 2mm in diameter was manufactured. In order to analyze GFA (Glass Forming Ability), rods were observed by Optical Microscopy and SEM and $T_g$, $T_x$, ($T_x$ is crystallization temperature and $T_g$ is the glass transition temperature) and Tm were measured by DTA and DSC. Powder was manufactured by Gas Atomizer and target was sintered using powder in large supercooled liquid region ($=T_x-T_g$) by SPS(Spark Plasma Sintering). Amorphous foil was prepared by RSP process with 5 gram alloy button. The composition of the foil and sputtered thin film was analyzed by EDS and EPMA. In the result of DSC curve, binary alloys ($Zr_{62}Cu_{38}$, $Zr_{60}Cu_{40}$, $Zr_{50}Cu_{50}$) and ternary alloys ($Zr_{64}Al_{10}Cu_{26}$, $Zr_{56}Al_{10}Cu_{34}$, $Zr_{52}Al_{10}Cu_{38}$) have $T_g$ except for $Zr_{70}Cu_{30}$ and $Zr_{60}Al_{10}Cu_{30}$. The compositions with $T_g$ made into powders. Figure shows XRD data of thin film showed similar hollow peak.

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Performance Evaluation of Underwater Acoustic Communication in Frequency Selective Shallow Water (주파수 선택적인 천해해역에서 수중음향통신 성능해석)

  • Park, Kyu-Chil;Park, Jihyun;Lee, Seung Wook;Jung, Jin Woo;Shin, Jungchae;Yoon, Jong Rak
    • The Journal of the Acoustical Society of Korea
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    • v.32 no.2
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    • pp.95-103
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    • 2013
  • An underwater acoustic (UWA) communication in shallow water is strongly affected by the water surface and the seabed acoustical properties. Every reflected signal to receiver experiences a time-variant scattering in sea surface roughness and a grazing-angle-dependent reflection loss in bottom. Consequently, the performance of UWA communication systems is degraded, and high-speed digital communication is disrupted. If there is a dominant signal path such as a direct path, the received signal is modeled statistically as Rice fading but if not, it is modeled as Rayleigh fading. However, it has been known to be very difficult to reproduce the statistical estimation by real experimental evaluation in the sea. To give an insight for this scattering and grazing-angle-dependent bottom reflection loss effect in UWA communication, authors conduct experiments to quantify these effects. The image is transmitted using binary frequency shift keying (BFSK) modulation. The quality of the received image is shown to be affected by water surface scattering and grazing-angle-dependent bottom reflection loss. The analysis is based on the transmitter to receiver range and the receiver depth dependent image quality and bit error rate (BER). The results show that the received image quality is highly dependent on the transmitter-receiver range and receiver depth which characterizes the channel coherence bandwidth.

Fabrication of Silane-crosslinked Proton Exchange Membranes by Radiation and Evaluation of Fuel Cell Performance (방사선을 이용한 실란 가교구조의 유/무기 복합 수소이온 교환막 제조 및 연료전지 성능 평가)

  • Lee, Ji-Hong;Sohn, Joon-Yong;Shin, Dong-Won;Song, Ju-Myung;Lee, Young-Moo;Nho, Young-Chang;Shin, Jun-Hwa
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.525-530
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    • 2012
  • In this study, silane-crosslinked organic/inorganic composite membranes were prepared by simultaneous irradiation grafting of binary monomer mixtures (styrene and 3-(trimethoxysilyl)propyl methacrylate (TMSPM)) with various compositions onto a poly(ethylene-alt-tetraethylene) (ETFE) film and followed by sol-gel processing and sulfonation to provide a silane-crosslinked structure and a proton conducting ability, respectively. The Fourier transform infrared spectroscopy (FTIR) and thermo gravimetric analysis (TGA) were utilized to confirm the crosslinking of ETFE-g-PS/PTMSPM films. The prepared membranes with similar ion exchange capacity but a different TMSPM content were selected and their membrane properties were compared. The ETFE-g-PSSA/PTMSPM membranes were characterized by water uptake, dimensional stability, and proton conductivity after sulfonation. The membrane electrode assemblies (MEA) of the prepared membranes were fabricated and their single cell performances were measured.

An Experimental Study on the Self-Consolidating Concrete with EP Nylon Fiber (EP 나일론섬유를 혼입한 자기충전콘크리트(SCC)에 관한 실험적 연구)

  • Ryou, Jae Suk;Lee, Yong Soo;Jeon, Joong Kyu;Jeon, Chan Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.1
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    • pp.159-168
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    • 2011
  • In this study, we find out the feasibility of self-consolidating concrete with EP nylon fiber. Three kinds of method were used; when length of nylon fiber is differed for the experiment to investigate usability of nylon fiber with enhanced performance by dispersing-agent coating in self-consolidating concrete, when mixing in other organic fibers (polypropylene, cellulose) and in case of Binary Blended and Ternary Blended concrete mixed with different types of mineral admixtures (blast-furnace slag and fly ash). Based on the results of the experiment described above, comparison was made on the basic properties and dynamic characteristics of general fiber reinforced concrete mixed with enhanced performance nylon fiber and SCC mixed with enhanced performance nylon fiber as a Mock-up test prior to the experiment of application to the actual structure. Considering characteristics and durability of the fresh and hardened self-compacting concrete, dynamic characteristics and durability were found to be more outstanding when using nylon fiber for the mineral admixtures used, dynamic characteristics and durability were found to be more outstanding when using blast-furnace slag.

The Critical Pigment Volume Concentration Concept for Paper Coatings: I. Model Coating Systems Using Plastic Pigments and Latex Binders for Paper Coating Applications

  • Lee, Do-Ik
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.5
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    • pp.1-17
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    • 2002
  • The immobilization and consolidation of the model coatings based on the plastic pigment and latex binder of known particle sizes were theoretically Studied in terms of the dense random packing of binary spheres and varying extent of latex film shrinkage. The porosity of the model coatings was calculated based on three proposed latex shrinkage models: Maximum, Minimum, and Linearly Decreasing Latex Shrinkage. The increasing extent of latex shrinkage was calculated up to the critical pigment volume concentration(CPVC) as a function of plastic pigment volume fractions, and the maximum latex shrinkage was estimated from the CPVC. Also, the number of pores and the average equivalent spherical pore diameters were calculated based on those proposed models. The opacity and gloss of the model coatings on polyester films were measured and their porosity was also determined by a simple coat weight-thickness method. As expected, various coating structure-property-composition relationships, such as opacity, gloss, porosity, etc., were shown to exhibit sharp transitions near the CPVC. The CPVC values determined by the opacity, gloss, and porosity vs. PVC relationships, respectively, agreed very well with each other. Especially, the CPVC's determined by the opacity and porosity vs. PVC curves were identical. The comparison between the theoretically calculated and experimental porosity values showed that the intermediate value between the maximum and minimum latex shrinkage would best fit the experimental porosity data. The effect of plastic pigment particle size on the optical properties and porosity of model coatings was also studied and it was observed that the coating opacity and porosity increased with increasing plastic pigment particle size, but the gloss decreased. The ink gloss of the uncalendered model coatings applied onto commercial sheet offset coated papers was shown to be affected by both the coating gloss and porosity: the higher the coating gloss, the higher the ink gloss, but the higher the coating porosity, the lower the ink gloss. Their printability was also studied in terms of the number of passes-to-fail and the rate of ink setting as a function of both plastic pigment volume fractions and plastic pigment particle sizes. A minimum crack-free temperature(MCR) of latex-bound coatings was proposed to better predict the behaviors of latexes as coating binders. The wet state of model coating dispersions, the surfaces of consolidated model coatings, and their internal structure were examined by both electron and atomic force microscopy, and their micrographs were found to be consistent with our immobilization and consolidation models.

Sensitivity analysis of missing mechanisms for the 19th Korean presidential election poll survey (19대 대선 여론조사에서 무응답 메카니즘의 민감도 분석)

  • Kim, Seongyong;Kwak, Dongho
    • The Korean Journal of Applied Statistics
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    • v.32 no.1
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    • pp.29-40
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    • 2019
  • Categorical data with non-responses are frequently observed in election poll surveys, and can be represented by incomplete contingency tables. To estimate supporting rates of candidates, the identification of the missing mechanism should be pre-determined because the estimates of non-responses can be changed depending on the assumed missing mechanism. However, it has been shown that it is not possible to identify the missing mechanism when using observed data. To overcome this problem, sensitivity analysis has been suggested. The previously proposed sensitivity analysis can be applicable only to two-way incomplete contingency tables with binary variables. The previous sensitivity analysis is inappropriate to use since more than two of the factors such as region, gender, and age are usually considered in election poll surveys. In this paper, sensitivity analysis suitable to an multi-dimensional incomplete contingency table is devised, and also applied to the 19th Korean presidential election poll survey data. As a result, the intervals of estimates from the sensitivity analysis include actual results as well as estimates from various missing mechanisms. In addition, the properties of the missing mechanism that produce estimates nearest to actual election results are investigated.