• Title/Summary/Keyword: Binary gas

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Influence of gas mixture He-Ne-Xe on the vacuum ultraviolet intensity in ac-PDPs.

  • Yoo, N.L.;Jung, K.B.;Lee, J.H.;Lee, S.B.;Han, Y.K.;Jeong, S.H.;Lee, H.J.;Son, C.G.;Lim, J.E.;Oh, P.Y.;Moon, M.W.;Jeoung, J.M.;Ko, B.D.;Cho, G.S.;Uhm, H.S.;Choi, E.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1221-1224
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    • 2005
  • The improvement of luminance and luminous efficiency is the one of the most important parts in AC-PDPs. To achieve high luminance and luminous efficiency, high VUV emission efficiency is needed. We measured the emission spectra of the vacuum ultraviolet(VUV) rays in surface discharge AC-PDP with ternary gas mixture of He-Ne-Xe. The influence of He-Ne-Xe gas-mixture ratio on excited $Xe^{\ast}$ resonant atoms and $Xe_2\;^{\ast}$ dimers has been investigated. It is found that luminous efficiency of ternary gas mixture, He-Ne-Xe, is shown to be much higher than that of binary gas mixture of Ne-Xe. For improving discharge luminous efficiency, we have studied VUV emission characteristics of ternary gas mixture, He(50%)-Ne-Xe and He(70%)-Ne-Xe with Xe concentration and filling gas pressure.

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An Evaluation on the Weldability of Al-Li Alloys by Varestraint Testing Method (Varestraint Test법에 의한 Al-Li합금의 용접성 평가)

  • 김형태;이창배;신현식;서창제
    • Journal of Welding and Joining
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    • v.14 no.6
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    • pp.48-57
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    • 1996
  • The weldability of high purity aluminum-lithium binary alloys has been investigated using the Varestraint test. Autogenous GTAW (gas-tungsten-arc-welds) were run along specimens of different lithium concentration using three sets of welding parameters. Welding voltage was held constant at 10 volts. Welding current (70∼100 amps) and travel speed (23∼33 cm/min) were the parameter varied. Hot-tearing susceptibility varied with lithium content and exhibited a steep peak at 2.6 weight percent lithium. Depth of penetration increased with increasing heat input and lithium concentration. The susceptibility is influenced by the wettability of dendrites by the interdendritic eutectic liquid as well as the time available for back-Siting by eutectic liquid. The welding condition of welding current 70A and travel speed 23 cm/min was showed good resistance to cracking in aluminum-lithium alloys. Suggestions for improving weld cracking resistance are also provided.

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Thermal Decomposition Characteristics on Sodium Azide and Metallic Oxide Mixtures (나트륨 아지드와 금속산화물과의 혼합물에 대한 열분해 특성)

  • 이내우;최재욱;박광수;설수덕;왕석주
    • Journal of the Korean Society of Safety
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    • v.12 no.3
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    • pp.106-113
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    • 1997
  • The thermal characteristics of two binary mixtures by sodium azide/manganese dioxide and ferric oxide, two ternary mixtures by sodium azide/silicon dioxide/manganese dioxide and ferric oxide were studied to obtain the basic data of gas-generating agents for air bags. The thermal reaction for all mixtures started at about $420^{\circ}C$, but the temperature at which the reaction rate reached a maximum was different with the states of samples. According to reaction results, nitrogen, nitrogen oxide and nitrogen dioxide were detected by GC-MS and so many kinds of new chemicals from sodium azide and metal oxide mixtures by XRD. NMS is considered as most stable and reasonable mixture for this types of gas-generating agents.

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불평등 전계에서 $SF_6/N_2$의 초고압 AC전압 절연내력 시뮬레이션

  • Heo, Chang-Su;Lee, Byeong-Taek;Choe, Sun-Ho;Sim, Myeong-Seop;An, Jeong-Sik;Hwang, Cheong-Ho;Jang, Yong-Mu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.03b
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    • pp.37-37
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    • 2010
  • In these days $SF_6$ mixtures and alternative gas has been studied because of global warming. so although many studies have been carried out about binary gas mixtures with $SF_6$, few studies were presented about breakdown characteristics of $SF_6/N_2$ mixtures. In this paper, breakdown experiment values and breakdown simulation value are compared. Streamer theory was used for predicting breakdown voltage. For accurate simulation, this simulation apply utilization factor using CST program. AC breakdown experiments in non-uniform field was performed to compare with the breakdown simulation values. But with gap lengths increasing, the breakdown voltage is saturated. So simulation need surface roughness factor.

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An Optimization Method of Series Condenser for Improvement of Transient Stability (과도안정도 향상을 위한 직렬콘덴서의 최적화 방안)

  • You, Seok-Ku;Moon, Byoung-Seo;Kim, Kyu-Ho
    • Proceedings of the KIEE Conference
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    • 1996.07b
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    • pp.890-892
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    • 1996
  • This paper presents a method for optimal placement of series condenser in order to improve the power system transient stability using genetic algorithms(GAs). In applying GAs, this approach utilizes two kinds of strings, one is coded by a binary finite-length for the selection of lines to install series condenser, the other is coded by a real value for the determination of injected condenser capacitance. For the formulation. this paper considers multi-objective function which is the critical energy as decelerating energy in power systems and the total injected condenser capacitance. The proposed method is applied to 9-bus, 18-line, 3-machine model system to show its effectiveness in determining the locations to install series condenser and the series condenser capacitance to be injected, simultaneously.

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A study for an association of acetic acid with n-heptane based on the chemical theory (초산과 n-heptane 이성분계의 회합성에 대한 화학적 이론을 이용한 연구)

  • Hong Sungho;Lee Jinyub;Lee Taejong
    • Journal of the Korean Institute of Gas
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    • v.3 no.3 s.8
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    • pp.34-38
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    • 1999
  • To propose a model equation, an acetic acid and n-heptane binary vapor liquid equilibrium system were investigated at 298.15K and 318.15K. Pressure was theoretically estimated using an association model based on the chemical theory, in conjunction with Margules, Wilson, NRTL models. Results were compared with those of calculated values without considering association. The theoretically calculated results of association model equations show a good agreement with the experimentally observed values.

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Scattering of Noble Gas Ions from a Si(100) Surface at Hyperthermal Energies (20-300 eV)

  • 이현우;Kang, H.
    • Bulletin of the Korean Chemical Society
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    • v.16 no.2
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    • pp.101-104
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    • 1995
  • In an attempt to understand the nature of hyperthermal ion-surface collisions, noble gas ion beams (He+, Ne+, Ar+, and Xe+) are scattered from a Si(100) surface for collision energies of 20-300 eV and for 45°incidence angle. The scattered ions are mass-analyzed using a quadrupole mass spectrometer and their kinetic energy is measured in a time-of-flight mode. The scattering event for He+ and Ne+ can be approximated as a sequence of quasi-binary collisions with individual Si atoms for high collision energies (Ei > 100 eV), but it becomes of a many-body nature for lower energies, Ar+ and Xe+ ions undergo mutliple large impact parameter collisions with the surface atoms. The effective mass of a surface that these heavy ions experience during the collision increases drastically for low beam energies.

The Measurement and Estimation of Minimum Flash Point Behavior for Binary Mixtures Using Tag Open-Cup Tester (Tag 개방식 장치를 이용한 이성분계 혼합물의 최소인화점 현상의 측정 및 예측)

  • Ha, Dong-Myeong;Lee, Sung-Jin
    • Journal of the Korean Institute of Gas
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    • v.12 no.3
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    • pp.50-55
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    • 2008
  • The flash points for the systems, ethlybenzene+n-butanol and ethlybenzene+n-hexanol, were measured by using Tag open-cup tester (ASTM D1310-86). These binary mixtures exhibited MFPB (minimum flash point behavior), which leads to the minimum on the flash point vs composition curve. The experimental data were compared with the values calculated by the Raoult's law, the UNIQUAC equation and the NRTL equation. The calculated values based on the UNIQUAC and NRTL equations were found to be better than those based on the Raoult's law. It was concluded that the UNIQUAC and NRTL equations were more effective than the Raoult' law at describing the activity coefficients for nonideal solution such as the ethlybenzene+n-butanol and ethlybenzene+n-hexanol systems. And the predictive curve of the flash point prediction model based on the NRTL equation described the experimentally-derived data more effectively than was the case when the prediction model was based upon the UNIQUAC equation.

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AC Breakdown Voltage Characteristics of $SF_6/CF_4$ and (E/P)crit in quasi-uniform Field (준평등전계에서 $SF_6/CF_4$ 혼합가스의 절연 파괴 전압 및 임계전계 특성)

  • Lee, Byung-Taek;Hwang, Cheong-Ho;An, Jung-Sik;Huh, Chang-Su
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1455_1456
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    • 2009
  • $SF_6$ is the most commonly used insulating gas in electrical systems. But In these days $SF_6$ mixtures and alternative gas has been studied because of global warming. so although many studies have been carried out about binary gas mixtures with $SF_6$, few studies were presented about breakdown characteristics of $SF_6/CF_4$ mixtures. At present study the breakdown characteristics of $SF_6/CF_4$ mixtures in quasi-uniform field was performed. This experiments were carried out under AC voltages. The rod-rod electrode was used with 5 mm gap distance. The mixture of $SF_6/CF_4$ containing 20%,50%,70% of $SF_6$ were compared with pure $SF_6$ and $CF_4$ gas and gas pressure ranged from 0.1 to 0.5 MPa. The show that the breakdown voltages of gas were linearly increased according to the pressure in quasi-uniform field. For breakdown vlotage values of $(E/P)_{crit}$ are important. Because If values of (E/P) is a little more than $(E/P)_{crit}$, electrons rapidly increase and streamer discharge gernerates. Through this experiments values of $(E/P)_{crit}$ are found to vary with the ratio of $SF_6/CF_4$ mixture according to the following relationship. $V_b=(E/P)_{crit}{\cdot}p{\cdot}d$

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Hydrogen Separation of binary gas mixture Using Templating Silica Membrane (유기 템플레이팅 실리카 막을 이용한 이성분 수소 혼합기체 분리 메커니즘)

  • Bae, Ji-Han;Han, Yoon-Jin;Lee, Chang-Ha
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.522-525
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    • 2008
  • 최근 세라믹 막은 우수한 화학적, 열적 안정성으로 기체 분리 공정에 각광을 받아 왔다. 특히 혼합기체에서 고 순도의 수소를 분리해 내는 기술은 연료전지 공정에서 화학 에너지를 전기화학 에너지로 전환시키는데 중요한 역할을 차지한다. 본 연구에서는MTES 템플레이팅 막을 이용하여 이 막 공정의 흡착 및 투과 특성을 규명하고, 이성분 혼합기체에서 고 순도의 수소를 추출해 낼 수 있는 최적 조건을 도출해 내었다. 또한, 기체 분리 거동을 살펴보기 위해 Gproms Dynamic Simulator를 이용하였으며, 이때 기체상의 물질전달을 모사하기 위해 Dust Gas Model(DGM)을, 표면 확산 거동을 모사하기 위해 Generalized Stefan-Maxwell(GSM)식을 적용하였다. 이를 통해 평형론적 흡착 뿐 아니라 속도론적 흡착을 동시에 적용할 수 있게 하였다. MTES 템플레이팅 막의 흡착 및 분리능을 규명하기 위해 본 연구에서는 혼합기체의 투과, 분리 실험이 선행되었다. 실험 조건은 온도범위 323$\sim$473 K, 압력범위 0$\sim$7 atm에서 수행되었으며, 혼합기체는2성분으로 수소-메탄, 수소-이산화탄소, 수소-질소로 기체의 구성비는 각각 50:50 이다. 본 연구를 통해 각 혼합 기체들이 정상상태에 도달하는 시간과 분리능을 계산해 내었으며, 이 분리능을 다시 온도와 압력에 따른 결과로 분석하여 어느 조건에서의 수소 분리도가 최고치를 보이는지를 규명했으며, 시뮬레이션과 비교,대조하여 예측도를 검사하였다.

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