• Title/Summary/Keyword: Binary gas

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Hydrodynamic Characteristics of Fine Powders in the Conical Powder-Particle Fluidized Beds (원추형 분립유동층에서 미세 분체의 수력학적 특성)

  • Lee Dong Hyun;Shin Moon Kwon;Kim Eun Mi;Son Seong Yong;Park Byung Sub;Han Gui Young;Yoon Ki June
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.310-313
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    • 2005
  • The conical fluidizing system of a binary mixture of Geldart C powders and Geldart A particles was defined as the conical powder-particle fluidized bed. We used a cold conical powder-particle fluidized bed model having a 0.104m-I.D. and 0.6m-high with an apex angle of $10^{\circ}$ for fluidization of a binary powder-particle mixture of 50 $vol\%$ fine carbon black powders (HI-900L, Korea Carbon Black Co.) and coarse alumina particles $(90{\mu}m)$ under different superficial gas velocities (0-0.1 m/s). The differential bed pressure drop increases with increasing gas velocity, and it goes from zero to a maximum value with increasing or decreasing gas velocity. In the conical fluidized beds of fine powders, demarcation velocities of the partial fluidization, full fluidization, partial defluidization was not observed.

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The characteristics of AC-PDPs According to binary and ternary gas mixtures of He-Ne-Xe_

  • Lee, H.J.;Son, C.G.;Lee, S.B.;Han, Y.K.;Jeoung, S.H.;You, N.L.;Lim, J.E.;Lee, J.H.;Moon, M.W.;Oh, P.Y.;Jeoung, J.M.;Choi, E.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1195-1198
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    • 2005
  • The improvement of efficiency is the one of the most important part in AC PDPs . To achieve high efficiency, high VUV emission efficiency and High ion induces secondary electron emission coefficient are needed. We have measured the emission spectra of vacuum ultraviolet rays and ion induced secondary electron emission coefficient of MgO protective layer in surface discharge AC-PDP with binary and ternary gas mixtures. We have investigated electro-optical characteristics of AC-PDPs to optimum gas mixture for high efficient.

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A Study on the Vapor-Liquid Equilibria for the Binary Sustem of Carbon Dioxide and Ethane (이산화탄소와 에탄 이성분계의 기액 상평형 연구)

  • Kim, Dong-Sun;Cho, Jung-Ho
    • Journal of the Korean Institute of Gas
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    • v.14 no.5
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    • pp.32-37
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    • 2010
  • In this study, vapor-liquid equilibrium (VLE) data at several isothermal temperatures for carbon dioxide and ethane binary systems were estimated using binary interaction parameters (BIP's) in Peng-Robinson (PR) equation of state built-in PRO/II with PROVISION (PRO/II) process simulator. Moreover, BIP's in PR equation of state were newly determined by regressing the experimental VLE data for carbon dioxide and ethane systems for each different isothermal temperatures using the summation of squares of the bubble point deviations as an objective function. Comparative works have been performed for absolute average deviation % (AAD(%)) between experimental and predicted bubble pressures using built-in BIP's in PRO/II and newly regressed one, respectively. Our calculation results gave a better estimation result than the simulation result using an existing parameter built-in PRO/II.

A Study of the Formation of Binary Intermediate Layer on Pd-based Hydrogen Separation Membrane Using Various Types of Metal Oxides (다양한 형태의 금속 산화물을 이용한 Pd계 복합 수소분리막의 2원계 중간층 형성에 관한 연구)

  • Hwang, In-Hyuck;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.196-200
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    • 2018
  • In this study, the intermediate layer in Pd-based hydrogen separation membrane was synthesized to minimize the surface roughness and defects using powder-type and sol-type metal oxides. The surface properties and gas permeation characteristics were analysed by SEM and $N_2$ gas permeation test. The coating layer composed of sol type metal oxides has smooth surface, especially the layer coated by $TiO_2$ sol has little pin holes, cracks and defects. The binary layer composed of powder type and sol type metal oxides has similar flux characteristics to a single sol type layer. The Pd-based composite membrane improved by the binary intermediate layer exhibited $0.32mol/m^2s$ of the hydrogen permeation flux with a selectivity ($H_2/N_2$) of ~10,890 at 672 K and a pressure difference of 1 bar.

Binary Vapor-Liquid Equilibria and Ternary Liquid-Liquid Equilibria for NMF Contained Systems (NMF를 포함하는 이성분계의 등온 기-액 평형과 삼성분계 액-액 평형)

  • Park, So-Jin;Han, Kyu-Jin;Won, Dong-Bok;Oh, Jong-Hyeok;Choi, Young-Yoon
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.259-265
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    • 2005
  • Binary isothermal vapor-liquid equilibrium(VLE) data were measured for water+n-methylformamide(NMF), benzene+NMF and toluene+NMF systems by using headspace gas chromatography(HSGC) at 353.15K. Additionally, the ternary liquid-liquid Equilibrium(LLE) data were determined by measuring of tie-line for the systems of NMF+benzene+n-heptane and NMF+toluene+n-heptane at 298.15 K. The measured isothermal binary VLE data have no azeotropes and were correlated well with $g^E$ model equations of Margules, van Laar, Wilson, NRTL and UNIQUAC. The experimental ternary tie line data were also correlated well with NRTL and UNIQUAC models. Besides their accuracy was analyzed by Hirata-Fujita and Maior-Swenson equations.

Sensing Characterization of Metal Oxide Semiconductor-Based Sensor Arrays for Gas Mixtures in Air

  • Jung-Sik Kim
    • Korean Journal of Materials Research
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    • v.33 no.5
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    • pp.195-204
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    • 2023
  • Micro-electronic gas sensor devices were developed for the detection of carbon monoxide (CO), nitrogen oxides (NOx), ammonia (NH3), and formaldehyde (HCHO), as well as binary mixed-gas systems. Four gas sensing materials for different target gases, Pd-SnO2 for CO, In2O3 for NOx, Ru-WO3 for NH3, and SnO2-ZnO for HCHO, were synthesized using a sol-gel method, and sensor devices were then fabricated using a micro sensor platform. The gas sensing behavior and sensor response to the gas mixture were examined for six mixed gas systems using the experimental data in MEMS gas sensor arrays in sole gases and their mixtures. The gas sensing behavior with the mixed gas system suggests that specific adsorption and selective activation of the adsorption sites might occur in gas mixtures, and allow selectivity for the adsorption of a particular gas. The careful pattern recognition of sensing data obtained by the sensor array made it possible to distinguish a gas species from a gas mixture and to measure its concentration.

Analysis of Insulating Characteristics of Cl2-He Mixture Gases in Gas Discharges

  • Tuan, Do Anh
    • Journal of Electrical Engineering and Technology
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    • v.10 no.4
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    • pp.1734-1737
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    • 2015
  • Insulating characteristics of Cl2-He mixture gases in gas discharges were analysed to evaluate ability of these gases for using in medium voltage and many industries. These are electron transport coefficients, which are the electron drift velocity, density-normalized longitudinal diffusion coefficient, and density-normalized effective ionization coefficient, in Cl2-He mixtures. A two-term approximation of the Boltzmann equation was used to calculate the electron transport coefficients for the first time over a wide range of E/N (ratio of the electric field E to the neutral number density N). The limiting field strength values of E/N, (E/N)lim, for these binary gas mixtures were also derived and compared with those of the pure SF6 gas.

Microscopic investigation on the binary ethanol + $CH_4$ Hydrate system (ethanol + $CH_4$ 하이드레이트 시스템의 미세 분광학적 연구)

  • Lee, Jong-Won;Kang, Seong-Pil
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.149.1-149.1
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    • 2010
  • 가스 하이드레이트는 작은 고체 부피 내에 막대한 양의 가스를 저장할 수 있다는 특징으로 인하여 최근 주목을 받고 있지만, 엔지니어링 분야에서는 천연가스 수송 파이프라인에 blockage problem을 일으키는 해로운 물질로 처음 관심을 받았다. 이러한 문제를 해결하기 위한 방법으로 초기에는 하이드레이트 형성영역을 벗어나도록 온도, 압력을 유지하기도 하였으나, 최근에는 다양한 형성 억제제가 사용되고 있다. 본 연구에서는 기존에 억제제로 알려져 있는 대표적인 알코올 화합물인 에탄올을 이용하여 고압의 메탄과 binary 하이드레이트의 형성 연구를 수행하였다. 다양한 농도의 에탄올을 이용하여 형성된 하이드레이트 샘플은 고체 NMR 분석을 통하여 분자 거동을 자세히 측정하였으며, 분말 XRD 분석을 통하여 헝성된 미세 결정 구조도 확인하였다. 본 연구에서 얻어진 결과는 에탄올 및 알코올 화합물의 가스 하이드레이트 형성 거동 및 binary guest 시스템에서의 tuning 효과에 대한 유용한 정보를 제시할 수 있을 것이라 판단된다.

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Identification of Gas Mixture with the MEMS Sensor Arrays by a Pattern Recognition

  • Bum-Joon Kim;Jung-Sik Kim
    • Korean Journal of Materials Research
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    • v.34 no.5
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    • pp.235-241
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    • 2024
  • Gas identification techniques using pattern recognition methods were developed from four micro-electronic gas sensors for noxious gas mixture analysis. The target gases for the air quality monitoring inside vehicles were two exhaust gases, carbon monoxide (CO) and nitrogen oxides (NOx), and two odor gases, ammonia (NH3) and formaldehyde (HCHO). Four MEMS gas sensors with sensing materials of Pd-SnO2 for CO, In2O3 for NOX, Ru-WO3 for NH3, and hybridized SnO2-ZnO material for HCHO were fabricated. In six binary mixed gas systems with oxidizing and reducing gases, the gas sensing behaviors and the sensor responses of these methods were examined for the discrimination of gas species. The gas sensitivity data was extracted and their patterns were determined using principal component analysis (PCA) techniques. The PCA plot results showed good separation among the mixed gas systems, suggesting that the gas mixture tests for noxious gases and their mixtures could be well classified and discriminated changes.