• Nuclear Engineering and Technology
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• v.46 no.1
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• pp.109-116
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• 2014

An electrical resistance tomography (ERT) technique combining the particle swarm optimization (PSO) algorithm with the Gauss-Newton method is applied to the visualization of two-phase flows. In the ERT, the electrical conductivity distribution, namely the conductivity values of pixels (numerical meshes) comprising the domain in the context of a numerical image reconstruction algorithm, is estimated with the known injected currents through the electrodes attached on the domain boundary and the measured potentials on those electrodes. In spite of many favorable characteristics of ERT such as no radiation, low cost, and high temporal resolution compared to other tomography techniques, one of the major drawbacks of ERT is low spatial resolution due to the inherent ill-posedness of conventional image reconstruction algorithms. In fact, the number of known data is much less than that of the unknowns (meshes). Recalling that binary mixtures like two-phase flows consist of only two substances with distinct electrical conductivities, this work adopts the PSO algorithm for mesh grouping to reduce the number of unknowns. In order to verify the enhanced performance of the proposed method, several numerical tests are performed. The comparison between the proposed algorithm and conventional Gauss-Newton method shows significant improvements in the quality of reconstructed images.

• Korean Journal of Soil Science and Fertilizer
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• v.48 no.6
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• pp.666-670
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• 2015

Competition among anion species in solution for same sorption sites and soil surface can be of major significance in determining the effective mobility of any potentially adsorbing species. Major soil anion species include $OH^-$, $F^-$, $Cl^-$, $HCO_3{^-}$, $CO_3{^-}$, $NO_3{^-}$, $SO_4{^{2-}}$, and $PO_4{^{3-}}$. And some micro nutrients such as boron and molybdenum exist as $H_2BO_3{^-}$ and $MoO_4{^{2-}}$, as do some heavy metals such as chrome and arsenic as $CrO_4{^{2-}}$ and $HAsO_4{^{2-}}$. Pesticides such as 2,4,5-T and 2,4-D also exist as anions. Many anion species are retained by more complex mechanisms than the simple electrostatic attractions involved in most cation adsorption reactions. In binary system composed of two anions, the adsorption of one anion is influenced by the other anion due to the competition for the available and limited binding sites in soil constituents. The specifically adsorbed anions may compete more effectively for sorption sites than that of nonspecifically adsorbed anion. In this study, we aim to evaluate the mathematical models to determine the magnitude of concentration variations in adsorption due to competitive interactions between anions introduced to a system in binary mixtures.

• Geomechanics and Engineering
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• v.28 no.6
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• pp.547-557
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• 2022

Dune sands are poorly graded collapsible soils lacking fines. This experimental study explored the technical feasibility of sustainable invigoration of fine waste materials to improve the geotechnical properties of dune sand. The fine waste considered in this study is fine marble waste. The fine waste powder was mixed with dune sand at different contents (5, 10,15, 20, 25, 50%), where the gradation, void ratio, compaction, and shear strength characteristics were assessed for each fine marble waste -dune sand blend. The geotechnical properties of the dune sand-fine marble waste mix delineated in this study reveal the enhancement in compaction and gradation characteristics of dune sand. According to the results, the binary mixture of dune sand with 20% of fine marble waste gives the highest maximum dry density and results in shear strength improvement. In addition, a numerical study is conducted for the practical application of the binary mix in the field and tested for an isolated shallow foundation. The elemental analysis of the fine marble waste confirms that the material is non-contaminated and can be employed for engineering applications. Furthermore, the numerical study elucidated that the shallow surface replacement of the site with the dune sand mixed with 20% fine marble waste gives optimal performance in terms of stress generation and settlement behavior of an isolated footing. For a sustainable mechanical performance of the fine marble waste mixed sand, an optimum dose of 20% fine marble waste is recommended, and some correlations are proposed. Thus, for improving dune sand's geotechnical characteristics, the addition of fine marble waste to the dune sand is an environment-friendly solution.

• Journal of the Korean Chemical Society
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• v.20 no.3
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• pp.185-192
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• 1976

Equivalent conductances of ammonium salts such as $NH_4Cl,\;CH_3NH_3Cl,\;(CH_3)_2NH_2Cl,\;(CH_3)_3NHCl\;and\;(CH_3)_4NCl$ have been measured in methanol-water mixtures of various composition (0.0${\sim}$0.6-mole frcation: m. f.) in the concentration range from 0.01 to 0.04 M at $25^{\circ}C$, and limiting equivalent conductances (${\Lambda}_0$) are determined by the analysis of Fuoss Onsager's semiempirical equation.The experimental results are discussed in terms of varing the size of ${\Lambda}_0$ due to the salts species and solvent composition. It has been observed in quite common over all salts that ${\Lambda}_0$ decreases with the increase of m. f. methanol, and the maximum decrement in ${\Lambda}_0$ shows between water and 0.1 m. f., while the plot of ${\Lambda}_0$ vs. m. f. goes through a minimum at 0.4 m. f. and then turns slightly upward. On the other hand, the ${\Lambda}_0$ decrease with the increase of the size of ammonium cation and the larger values ${\Lambda}_0$ are showed in comparison with those of values observed for the corresponding $n-RNH_3Cl$ under the same experimental procedure. All these behaviors are considered to be closely correlated with the structures of solvents and solutes and the significant similarities are compared with the behaviors of partial molar volumes for amine salts in same solvent system.

• Fire Science and Engineering
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• v.30 no.6
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• pp.31-36
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• 2016

The flash point is one of the most important properties for characterizing the fire and explosion hazard of liquid solutions. In this study, the flash points of two flammable binary mixtures, n-pentanol + n-propanol and n-pentanol + n-heptanol systems were measured using a Seta flash closed cup tester. The flash point was estimated using the methods based on Raoult's law and multiple regression analysis. The measured flash points were also compared with the predicted flash points. The absolute average errors (AAE) of the results calculated by Raout's law were $1.3^{\circ}C$ and $1.3^{\circ}C$ for the n-pentanol + n-propanol and n-pentanol + n-heptanol mixtures, respectively. The absolute average errors of the results calculated by multiple regression analysis were $0.4^{\circ}C$ and $0.3^{\circ}C$ for the n-pentanol + n-propanol and n-pentanol + n-heptanol mixtures, respectively. According to the AAE, the calculated values based on multiple regression analysis were better than those based on Raoult's law.

• Clean Technology
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• v.24 no.3
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• pp.239-248
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• 2018

In this study, pervaporation experiments of water, ethanol and IPA (Isopropyl alcohol) single components and water/ethanol, water/IPA mixtures were carried out using zeolite 4A membranes developed by Fine Tech Co. Ltd. Those membranes were fabricated by hydrothermal synthesis (growth in hydrothermal condition) after uniformly dispersing the zeolite seeds on the tubular alumina supports. They have a pore size of about $4{\AA}$ by ion exchange of $Na^+$ to the LTA structure with Si/Al ratio of 1.0, and shows strong hydrophilic property. Physical characteristics of prepared membranes were evaluated by using SEM (surface morphology), porosimetry (macro- or meso- pore analysis), BET (micropore analysis), and load tester (compressive strength). Pervaporation experiments with various temperature and concentration conditions confirmed that the zeolite 4A membrane can selectively separate water from ethanol and IPA. Water/ethanol separation factor was over 3,000 and water/IPA separation factor was over 1,500 (50 : 50 wt%, initial feed concentration). Pervaporation behaviors of single components and binary mixtures were predicted using ACM (activity coefficient model), GMS (generalized Maxwell Stefan) model and DGM (Dusty Gas Model). The adsorption and diffusion coefficients of the zeolite top layer were obtained by parameter estimation using GA (Genetic Algorithm, stochastic optimization method). All the calculations were carried out using MATLAB 2018a version.

• Solar Energy
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• v.15 no.3
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• pp.75-90
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• 1995

This paper is concerned about alternative refrigerants for HCFC22 used in room air conditioners and heat pumps. Computer simulation of residential air conditioners using refrigerant mixtures is carried out. Following refrigerants are selected as the pure refrigerants constituting the mixtures studied: R32, R124, R125, R134, R134a, R143a and R152a. Simulation results are presented fur the following mixtures: R32/R134a, R32/R152a, R32/R134, R32/R124, R143a/R134a, R143a/R152a, R143a/R124, R125/R134a, R125/R152a, R125/R124, R32/R152a/R134a, R32/R152a/R134, R32/R152a/R124. The best fluid is found to be the ternary mixture of R32/R152a/R124. For that mixture, the coefficient of performance(COP) and volumetric capacity for refrigeration(VCR) are 13.7% larger and 23% smaller than the respective values for HCFC22. R32/R124 mixture is the best binary fluid pair whose COP and VCR are 13.4% larger and 9.6% smaller than those for HCFC22.

• Journal of the Mineralogical Society of Korea
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• v.7 no.1
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• pp.62-79
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• 1994

The quanttative and structural analysis of the binary standard mixtures of albite and quartz, and microcline and albite were carried out using the Rietveld refinement method in order to investigate the accuracy and precision of the method. The quantitative analysis using the Rietveld method results in a standard deviation of 4 wt % for the albite-quartz standard mixtures and 1 wt % for the microcline-albite standard mixtures, suggesting that its accuracy is far better than that of the conventional XRD method in which only a few selected peaks are utilized. Furthermore, the unit-cell parameters of component minerals in mixtures were also estimated accurately during the analysis. It was observed that the refined weight fractions deviate systematically from their measured values when the method is applied to the mixtures that contain minerals with different degrees of preferred orientation, such as albite-quartz mixtures. The preferred orientation parameters and R-values suggest that the systematic deviation is caused as a result of the preferred orientation effect of feldspar crystallites. It is evident that the preferred orientation corrections are of help for the accurate determination of unit-cell parameters, although they may not improve the result of quantitative analysis significantly. The refined weight fraction of the mineral with higher degree of preferred orientation in mixture is greater than the measured one. This is apparently caused by the effect of geometry of feldspar crystallites in the surface of the mounted sample. The Rietveld refinement method minimizes the problems inherent in the traditional XRD methods, such as the line overlap, primary extinction, and preferred orientation effect, by fitting every data point in a whole pattern explicitly. Furthermore, accurate unit-cell parameters as well as scale factors that can be obtained from the Rietveld refinement are used for the quqantification. The present stdudy demonstrates that the Rietveld method yields far more accurate analytical result than the conventional XRD quantitative analysis method does.

• Korean Chemical Engineering Research
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• v.46 no.1
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• pp.175-183
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• 2008

Adsorption equilibria of the gases $CO_2$, CO, $CH_4$ and $H_2$ and their binary mixtures on Li-X zeolite (UOP) were obtained by static volumetric method in the pressure range of 0 to 20 bar at temperatures of 293.15, 303.15, and 313.15 K. Using the parameter obtained from single-component adsorption isotherm. Multicomponent adsorption equilibra could be predicted and compared with experimental data. Extended Langmuir isotherm, Extended Langmuir-Freundlich isotherm (L-F) and dual-site Langmuir isotherm (DSL) were used to predict the experimental results for binary adsorption equilibria of $H_2/CO_2$, $H_2/CO$, and $H_2/CH_4$ on Li-X Zeolite. Extended Langmuir-Freundlich isotherm predicted equilibria of $CH_4$ and $H_2$ better than any other isotherm. One the other hand DSL isotherm predicted equilibria of $CO_2$ and CO very well.

• International Journal of Air-Conditioning and Refrigeration
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• v.11 no.2
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• pp.61-66
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• 2003

In order to prevent roll-over and a rapid boil-off of LNG in tanks, the phase equilibria of carbon dioxide in liquefied natural gas components as binary mixtures at cryogenic temperatures have been experimentally measured using Fourier transform infrared spectroscopy in conjunction with a specially designed variable pressure/temperature cryostat cell (pathlength 2 mm; pressures up to 30 bar). Solid carbon dioxide has been found to be comparatively soluble in liquid nitrogen (3.25$\times$${10}^{-6}$ mole fraction), liquid methane (1.04$\times$${10}^{-4}$ mole fraction), liquid ethane (3.1$\times$${10}^{-2}$ mole fraction) and liquid propane (6.11$\times$${10}^{-2}$ mole fraction) at their normal boiling temperatures. The solubilities of carbon dioxide in various cryogens, which increased with increasing temperature, are much lower than those obtained by others using gas chromatography. The differences are attributed to infrared spectroscopy selectively measuring dissolved solute in situ whereas gas chromatography measures microscopic particulate solid in addition to dissolved solute.