• 제목/요약/키워드: Bi2223 superconductor

검색결과 102건 처리시간 0.023초

고온 초전도 케이블용 Bi-2223 선재의 기계적 특성 (Mechanical Characteristics of Bi-2223 Wire for High-Tc Superconducting Cable)

  • 백승명;김영석;정순용;김상현
    • 한국전기전자재료학회논문지
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    • 제11권11호
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    • pp.1028-1034
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    • 1998
  • Bi-2223 superconductor is known as one of the candidates for practical superconducting wires. Ag-sheathed Bi-2223 superconducting wires were fabricated using the powder-in-tube(PIT) method. When the 19-filaments wire was immersed in liquid nitrogen(77K), maximum critical current density Jc of 62 A/$mm_2$ at 0T was achieved. The critical current density has been shown to depend on the mechanical properties such as tensile stress and bending strain in Ag-sheathed Bi-2223 superconducting wires. The tensile strain for Jc degradation onset was in the range of 0.12~0.3%. In the case of 19-filaments wire, the bending strain is estimated to be smaller than 0.3% for the reasonable Jc value. The observed degradation of the critical current density due to strain effect is inevitable and can be attributed to the formation of microcracks within the superconducting core.

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확산법에 의한 Bi-2223 초전도상의 제조 및 성장기구에 관한 연구 (Study on the fabrication and the growth mechanism of Bi-2223 superconducting phase by diffusion method)

  • 최성환;최효상;한태희;황종선;한병성
    • E2M - 전기 전자와 첨단 소재
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    • 제7권4호
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    • pp.281-288
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    • 1994
  • According to spread volume of B(BiPbCuO) layer, composition ratio and each stage of sintering process, we studied stability of high Tc superconductor phase and generation and growth movement of superconducting phase. The dual layer composed of SrCaCuO and BiPbCuO compound were prepared to develop the Bi-2223 superconductor[108K] through interaction and diffusion during sintering process. The dual layer samples were sintered at 830.deg. C for 0-210 hours. From the result, the optimum conditions were : spread volume(A:B=1:0.6), sintering time(210h) and composition ratio(A:S $r_{2}$C $a_{2}$C $u_{2}$- $O_{x}$, B:B $i_{1.9}$P $b_{0.5}$C $u_{3}$ $O_{y}$) at 830.deg. C.. C.C.C.

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BSCCO계 초전도체에서 서냉 열처리에 의한 2차상 석출 (The Precipitation of Second Phases by Annealing Heat Treatment in the $(Bi,Pb)_2$${Sr_2}{Ca_2}{Cu_3}{O_{10}}$ Superconductor System)

  • 이상희;김철진;유재무
    • 한국세라믹학회지
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    • 제37권12호
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    • pp.1212-1220
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    • 2000
  • Bi-2223 초전도체계에서 석출물을 flux-pinning center로 이용할 수 있는지 가능성을 타진하기 위하여 $Bi_{1.8}$P $b_{0.4}$S $r_{2}$C $a_{2.2}$C $u_3$ $O_{8}$ 조성을 가진 Bi-2223/Ag 선재를 반응온도, 산소분압, 시간 등을 변화시키면서 열처리를 행하였다. 열처리 후 석출물들은 XRD, SEM, TEM, EDS로 분석하였다. Bi-2223 모상내의 (Ca, Sr)$_2$(Pb,Bi) $O_4$, B $i_{0.5}$ P $b_3$S $r_2$C $a_2$Cu $O_{12+}$$\delta$/ (3221)와 같은 2차상들의 크기와 분포는 2223 입자들의 연결성을 파괴하지 않고 열처리 조건에 의해서 조절할 수 있었다. 서냉 열처리가 된 시편은 임계전류밀도( $J_{c}$)값이 증가하였는데, 이는 2223 입자내 나노미터 크기로 형성된 석출물들이 flux-pinning sites로 작용한 것으로 추정된다.다.

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유한요소법에 의한 Bi2223 고온 초전도 선재의 다심 인발에 대한 연구 (Study for multi-filament drawing of Bi2223 high-temperature superconductivity wire by FE method)

  • 박동인;김병민;오상수
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2003년도 추계학술대회논문집
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    • pp.273-276
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    • 2003
  • High-temperature superconduction materials(Bi2223) possess electrical/electronic and magnetic properties. Because high-temperature superconduction materials is a ceramic powder, that can not be produced singlehandedly. So Ag sheathed Bi-2223 wire was produced by drawing process using powder-in-tube(PIT) method. This superconductor has many difficulties to produce. The main difficulty is that the mechanical properties of the ceramic powder are very different from those of the Ag sheath. Bi2223 high-temperature superconductivity have a single filament drawing process, and multi-filament drawing process. This study analysed multi-filament drawing process by FEM, a defects during multi-filament drawing was studied by FEM.

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Bi-2223 고온초전도 선의 상용화 공정 연구 (Study on commercialization process of Bi-B223 HTS tape)

  • 하동우;김상철;오상수;하홍수;이동훈;양주생;황선역
    • 한국초전도ㆍ저온공학회논문지
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    • 제6권1호
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    • pp.1-5
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    • 2004
  • Long length of Bi-2223/Ag superconducting wives were fabricated by stacking and drawing process with advanced heat-treatment schedules. Intermediate annealing was carried out to increase the homogeneity and uniformity of the superconducting filaments embedded in the silver matrix. Phase modification from tetragonal to orthorhombic Bi-2212 by pre heat treatment(PHT) was executed to improve the texture and phase transformation of Bi-2223. Drawing stress was measured to predict the sausaging and stress limit. Rolling Parameters such as thickness. width and winding tension were investigated to roll the tape with uniformity. 1 km length of Bi-2223/Ag superconducting wires were fabricated without any breakage. Critical current (Je) of 270 m length of superconducting tapes was measured over than $70 A/cm^2$ continuously after final sintering.

Phase Stability of Bi2212 and Bi2223 Thin Films Fabricated by Ion Beam Sputtering

  • Lee, Hee-Kab;Park, Yong-Pil;Kim, Jeong-Ho
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2000년도 추계학술대회논문집
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    • pp.108-111
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    • 2000
  • Bi2212 and Bi2223 thin films are fabricated by ion beam sputtering method. Three phases of Bi2201, Bi2212 and Bi2223 appear as stable ones in spite of the condition for thin film fabrication of Bi2212 and bi2223 compositions, depending on substrate temperature(T$\sub$sub/) and ozone pressure (PO$_3$). It is found out that these phases show similar T$\sub$sub/ and PO$_3$dependence, and that the stable regions of these phases are limited within very narrow temperature.

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Phase Stability of Bi2212 and Bi2223 Thin Films Fabricated by ion Beam Sputtering

  • Lee, Hee-Kab;Park, Yong-Pil;Kim, Jeong-Ho
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.108-111
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    • 2000
  • Bi2212 and Bi2223 thin films are fabricated by ion beam sputtering method. Three phases of Bi2201, Bi2212 and Bi2223 appear as stable ones in spite of the condition for thin film fabrication of Bi2212 and bi2223 compositions, depending on substrate temperature(T$\sub$sub/) and ozone pressure (PO$_3$). It is found out that these phases show similar T$\sub$sub/ and PO$_3$ dependence, and that the stable regions of these phases are limited within very narrow temperature.

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100 m급 Bi-2223 고온초전도 선재 제조 및 특성 (Fabrication and performance of 100 m Class Bi-2223 High Temperature Superconducting Tape)

  • 하홍수;오상수;하동우;장현만;이남진;류강식;이준석
    • 한국초전도ㆍ저온공학회논문지
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    • 제1권2호
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    • pp.15-19
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    • 1999
  • For large scale applications of high temperature superconductor (HTS) such as transmission cables, motors and generators, long length of flexible HTS conductor is required. Currently, Bi-2223 HTS tape is capable of being fabricated in longer than 100 m length by industrial processes. In this study, we fabricated 100 m 19 filamentary Bi-2223 ($Bi_{1.8}Pb_{0.4}Sr_2Ca_2O_{10+x}$) HTS tape by PIT (Power in Tube) process. Critical current(IC) of this long length tape was measured 18.5 A at 77K, self field. Critical current of 100 m length tape was mainly resulted from the increase of inhomogeneity in oxide from the increase of inhomogeneity in oxide layer. Engineering critical current (Je=Ic/total tape cross-section area) that is important factor for practical applications and fabrication cost was measured 2.2 kA/cm2.

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Ultrasonic Spray Pyrolysis 법에 의한 Bi2Sr2Ca2Cu3Ox 분말합성 및 특성평가 (Synthesis and Characterization of Bi2Sr2Ca2Cu3Ox Powders by Ultrasonic Spray Pyrolysis Method)

  • 배병수;정상진;이봉;문창권;최희락
    • 한국해양공학회지
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    • 제24권6호
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    • pp.86-91
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    • 2010
  • Superconductor material $Bi_2Sr_2Ca_2Cu_3O_x$(Bi-2223) powders were synthesized by ultrasonic spray pyrolysis method. It is clear that Bi-2223 phase more than Bi-2212 phase was acquired at sufficient synthesized time. Best condition for Bi-2223 phase was synthesizing temperature at $860^{\circ}C$. We also investigated the effects for concentrations and viscosities of starting liquid precursor as well as temperature distribution of reacting furnace. The size of synthesized powder was decreased by decreasing the concentration of starting liquid precursor. Modified reacting furnace with four different temperature heating zones gave us successful results for desirable nano-powder including $Bi_2Sr_2Ca_2Cu_3O_x$ phase. Citric acid addition to starting liquid precursor showed increasing of the size for synthesized powder. Bi-2223 single phase was acquired from Bi2223 and Bi-2212 mixed phases through heat treatment in box furnace at 24 hours.

Twisting된 Bi-2223 선재의 미세조직 관찰 및 교류손실 특성평가 (The effect of twisting on microstructure and AC losses of Bi-2223 superconductor tapes)

  • 장석헌;임준형;김정호;김규태;주진호;나완수;정재훈;류경우
    • 한국초전도저온공학회:학술대회논문집
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    • 한국초전도저온공학회 2003년도 학술대회 논문집
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    • pp.126-128
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    • 2003
  • The effect of twisting on the microstructure and AC losses of Bi-2223 superconductor tape has been evaluated. Twisting pitches of the tapes are in the range of 12~60 mm and uniformly deformed. The critical current of the tapes was measured to decreased with decreased pitch. This reduction is believed to be due to the irregular interface, poor grain alignment. In addition, AC losses of the tape reduced as the pitch decreased probably due to combined effects of lower critical current and electrically decoupled filament of twisted tape.

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