• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.07b
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• pp.1208-1211
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• 2003

High quality $Bi_2Sr_2Ca_nCu_{n+1}O_x$ superconducting thin films fabricated by using the evaporation method at various substrate temperatures, $T_{sub}$, and ozone gas pressures, $pO_3$. The correlation diagrams of the $Bi_2Sr_2Ca_nCu_{n+1}O_x$ phases with $T_{sub}$ and $pO_3$ are established in the 2212 and 2223 compositional films. In spite of 2212 compositional sputtering, Bi2201 and Bi2223 as well as Bi2212 phases come out as stable phases depending on $T_{sub}$ and $pO_3$. From these results, the thermodynamic evaluation of ${\Delta}H$ and ${\Delta}S$, which are related with Gibbs' free energy change for single Bi2212 or Bi2223 phase, was performed.

• Progress in Superconductivity
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• v.4 no.1
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• pp.94-98
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• 2002

Two kinds of multifilament Bi-2223／Ag tapes, which are different in the precursor calcination temperatures, were heat treated for different time (12, 20, 30, 50, 70, or 100 h) firstly to obtain varied B2223 contents, and then followed by the same pressing and sintering cycles. The relation of the 2223 phase contents after the first sintering and the transport property of the fully processed tapes was studied. The results show that 75-80% 2223 phase formed in tapes before the first cold pressing is beneficial to get a high $I_{c}$ in the final tapes. Compensating the total heat treatment time of the tapes first sintered for 20 h to the same length as that first sintered for 50 h in the subsequent sintering stages, different $I_{c}$ enhancements were observed in these two tapes. No improvement on $I_{c}$ was found in the tape made from the powder calcined at higher temperature, whereas for the tape prepared with the lower temperature calcined powder, the $I_{c}$ was increased to the same level as that first sintered for 50 h. The 2223 contents before the intermediate mechanical work is related to the residual reactants, especially to the liquid phase, which is of vital importance to the phase conversion and healing microcracks, meanwhile, to the size and distribution of the non-superconducting secondary phases. The lower temperature calcined powder resulted in slow formation of 2223 phase, but also provided more reactants and liquid phase for the further phase conversion, as a consequence, for the Improvement of $I_{c}$. c/.

• 한국초전도학회:학술대회논문집
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• v.12
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• pp.77-77
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• 2002

• Proceedings of the Korean Ceranic Society Conference
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• 2003.04a
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• pp.86.1-86
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• 2003

• 한국초전도학회:학술대회논문집
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• v.14
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• pp.30-30
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• 2004

• 한국초전도학회:학술대회논문집
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• v.11
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• pp.56-56
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• 2001

• 한국초전도학회:학술대회논문집
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• v.12
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• pp.64-64
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• 2002

• Proceedings of the Korean Ceranic Society Conference
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• 2002.10a
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• pp.189.1-189
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• 2002

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1996.05a
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• pp.252-255
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• 1996

Superconducting current lead is one of the promising applications of the oxide high-Tc superconductors, because they have the advantage of decreasing heat conduction to low temperature region, comparing with a conventional cooper alloy lead. High critical current density is a key factor for the applications such as current lead. (Bi,Pb)$_2$Sr$_2$Ca$_2$Cu$_3$O$\_$x/ high Tc superconductor haute been investigated in terms of critical current density. Bi-2223 superconducting current lead made by CIP and solid state sintering process. Bi-2223 current lead that heat treated at 836$^{\circ}C$ for 240 h in 1/13 P$\_$O$_2$/ had over 150 A/$\textrm{cm}^2$ of critical current density at 77K. We knew that the superconducting properties of tube type current leads were better than rods type of them. And we investigated the relation of Bi-2223 formation and heat treatment condition by XRD and SEM analysis.

• Progress in Superconductivity
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• v.3 no.2
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• pp.247-251
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• 2002

In general, the bubbling, generated during the fabrication of the tapes, breaks the superconducting filament, and critical current of the tapes will be decreased. Heat-treatment schemes of Bi-2223/Ag HTS tapes were modified, such as pre-annealing of multi-stacked billet, 2-step main sintering and ramp rate etc. The generation of bubbling was drastically decreased from 20 bubbles/m to 0 ~ 1 bubble/m by the modified heat-treatment. Therefore, the value of critical current of the tapes without bubbling was increased almost twice higher than that of already existing tapes. Critical current up to 42 A in 40 m length Bi-22231Ag tapes have been measured at 77K, self-field, 1$mutextrm{V}$/cm criterion. It could be confirmed that elimination of bubbling is effective to maintain the superconducting property along the tape length.