• Title/Summary/Keyword: Bi-spectrum

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Bayberry Tannin as Stabilizer for the Synthesis of Highly Active and Reusable Heterogeneous Pd Catalysts and Their Application in the Catalytic Hydrogenation of Olefins

  • Chen, Chen;Lv, Guang;Huang, Xin;Liao, Xue Pin;Zhang, Wen Hua;Shi, Bi
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.403-408
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    • 2012
  • In this study, the homogenous Pd nanoparticles (Pd NPs) were first prepared with bayberry tannin (BT) as the stabilizers. Subsequently, the obtained bayberry tannin-stabilized Pd nanoparticles (BT-Pd) were immobilized onto ${\gamma}-Al_2O_3$ to prepare heterogeneous ${\gamma}-Al_2O_3$-BT-Pd catalysts. Fourier Transformation Infrared Spectrum (FTIR) and X-ray Photoelectron Spectroscopy (XPS) analyses confirmed that the Pd NPs were well stabilized by the phenolic hydroxyl groups of BT. Transmission Electron Microscopy (TEM) observation indicated that the diameter of the Pd NPs can be effectively controlled in the range of 4.2-16.0 nm by varying the amount of BT. It is found that the ${\gamma}-Al_2O_3$-BT-Pd catalysts exhibit highly activity for various olefin hydrogenations. For example, the initial TOF (turnover frequency) of the ${\gamma}-Al_2O_3$-BT-Pd in the allyl alcohol hydrogenation is as high as $12804 mol{\cdot}mol^{-1}{\cdot}h^{-1}$. Furthermore, the ${\gamma}-Al_2O_3$-BT-Pd can be reused 5 times without significant loss of activity, exhibiting a superior reusability as compared with conventionally prepared ${\gamma}-Al_2O_3$-Pd catalysts.

Effect of Glass Composition on the Optical Properties of Color Conversion Glasses for White LED (유리조성에 따른 백색 LED용 색변환 유리의 광특성)

  • Huh, Cheolmin;Hwang, Jonghee;Lim, Tae-Young;Kim, Jin-Ho;Lee, MiJai;Yoo, Jong-Sung;Park, Tae-Ho;Moon, Jooho
    • Korean Journal of Materials Research
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    • v.22 no.12
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    • pp.669-674
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    • 2012
  • Yellow phosphor dispersed color conversion glasses are promising phosphor materials for white LED applications because of their good thermal durability, chemical stability, and anti-ultraviolet property. Six color conversion glasses were prepared with high Tg and low Tg specimens of glass. Luminous efficacy, luminance, CIE (Commission Internationale de l'Eclairage) chromaticity, CCT (Correlated Color Temperature), and CRI (Color Rendering Index) of the color conversion glasses were analyzed according to the PL spectrum. Color conversion glasses with high Tg glass frit, sintered at higher temperature, showed better luminous properties than did color conversion glasses with low Tg glass frit. The characteristics of the color conversion glass depended on the glass composition rather than on the sintering temperature. The XRD peaks of the YAG phosphor disappeared in the color conversion glass with major components of $B_2O_3$-ZnO-$SiO_2$-CaO and, in the XRD results, new crystalline peaks of $BaSi_2O_5$ appeared in the color conversion glass with major components of $Bi_2O_3$-ZnO-$B_2O_3$-MgO. The characteristics of CIE chromaticity, CCT, and the CRI of low Tg color conversion glasses showed worse color properties than those of high Tg color conversion glasses. However, these color characteristics of low Tg glasses were improved by thickness variation. So color conversion glasses with good characteristics of both luminous and color properties were attained.

Fabrication and characteristics for the organic light emitting device from single layer poly(N-vinylcarbazole) (단층 poly(N-vinylcarbazole) 유기물 전기발광 소자의 제작 및 특성)

  • 윤석범;오환술
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.11
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    • pp.55-61
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    • 1998
  • Organic light emitting devices from a single layer thin film with a hole transport polymer, poly(N-vinylcarbazole) (PVK) doped with 2-(4-bi phenyl)-5-(4-t-butyl-phenyl) -1,3,4-oxadiazole (Bu-PBD) as electron transporting molecules and Coumurine 6(C6), 1,1,4,4-tetraphenyl-1,3-butadiene (TPB), Rhodamine B as a emitter dye were fabricated. The sing1e layer structure and the use of soluble materials simplify the fabrication of devices by spin coating technique. The active layer consists of one polymer layer that is simply sandwiched between two electrodes, indium-tin oxide (ITO), and aluminum. In this structure, electron and hole inject from the electrodes to the PVK : Bu-PBD active layer. Respectively, Blue, green and orange colored emission spectrum by the use of TPB, C6, Rhodamine B dye emitted at 481nm, 500nm and 585nm were achieved during applied voltages. PVK materials can be useful as the host polymer to be molecularly doped with other organic dyes of the different luminescence colors. And EL color can be tuned to the full visible wavelength.

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Dual-Band Filtering Method Considering to Efficiency of Performance and Complexity in DBO-CSS System (DBO-CSS 시스템에서 성능과 복잡도의 효율성을 고려한 이중 대역 필터링 방법)

  • Jeong, Jin-Doo;Jin, Yong-Sun;Chong, Jong-Wha
    • 전자공학회논문지 IE
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    • v.47 no.2
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    • pp.60-65
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    • 2010
  • In this paper, we propose a dual-band filtering method optimized to DBO-CSS systems which are alternatively transmitted in low and high bands. The conventional channel filter which passes entire signal bandwidth causes a problem that excessive noise in neighboring sub-band is added while one of signals in two sub-bands is received. The dual-band filtering proposed in this paper can overcome the performance degradation in the conventional filtering method without increase of hardware complexity. The proposed method is based on two filters to be matched with DBO-CSS signals receiving alternatively and can exclude the undesired noise in neighboring sub-band. Simulation results for the proposed method show better performance about 2.5dB than the conventional one.

Spectrum Characteristics and Stress Induced Birefringence of Fiber Bragg Grating Embedded into Composite Laminates (복합재 평판에 삽입된 광섬유 브래그 격자의 스펙트럼특성과 응력유도복굴절)

  • Lee, Jung-Ryul;Kim, Chun-Gon;Hong, Chang-Sun
    • Composites Research
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    • v.15 no.3
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    • pp.30-38
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    • 2002
  • Fiber Bragg grating(FBG) like other optical fiber sensors also has the merit of embedding capability. To increase their actual value related to embedding capability, this paper reported the reliability and signal characteristics of FBGS embedded in composite laminates. The microphotographs of embedded optical fibers visualized the embedding environments of stripped optical fibers and coated optical fibers. Based on these microphotographs and cure monitoring performed using FBGs, we could understand that the main cause breaking the unique Bragg condition of low-birefrigence FBG were residual stress artier curing and reported the stale of stress/strain of optical fiber quantitatively. The cure monitoring also showed the history of splitting peak of a stripped FBG along cure processing. In addition, we could obtain a transverse insensitive grating(TIG) with ease by recoating a stripped FBG. TIG has good advantage for real-time signal processing.

Effect of Rubber Damper of Flywheel on the Vibration of Diesel Engine (플라이휠의 고무댐퍼가 기관(機關)의 진동(振動)에 미치는 영향(影響))

  • Myung, B.S.;Kim, S.R.
    • Journal of Biosystems Engineering
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    • v.18 no.3
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    • pp.239-251
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    • 1993
  • Data acquisition system and computer program developed in this study could be well used in engine vibration analysis. The system and program developed were also operated to be able to control measuring interval, number of channels, number of data. The flywheel was specially studied to provide the proper weight with rubber damper for the engine design at low level of vibration. This study was conducted to obtain basic data which affect the engine vibration. The experiment of this study was performed on original weight flywheel, weight-reduced flywheel, weight-reduced and rubber-coated flywheel, weight-reduced and damper-attached flywheel. Avarage of peak value, maximum vibration, power spectrum density based on FFT analysis are major factors of this experiment. Results were obtained as follows : 1. When rubber was inserted in the flywheel rim of which weight was reduced from 32.2kgf to 24.4 kgf, maximum vibration of the engine was decreased 48.3% at X axis, 35.5% at Y axis and 34.6% at Z axis in comparison with the flywheel of original weight. 2. When the flywheel of rubber damper was compared with the original flywheel, the average of absolute vibration for rubber damped flywheel was decreased at X, Y, Z axis and especially its decreasing rate was so high at X-axis comparing with the other flywheel, which implied that rubber damper was very useful to reducing the vibration of the engine at X axis. 3. Hysteresis losses of X, Y, Z axis were greatly decreased in the flywheel with rubber damper on rim. 4. Damped oscillation effect on X and Y axis vibration above average peak vibration by the flywheel of rubber damper on rim was larger than those by the other flywheels. 5. Power spectrums of vibration at real and imaginery part were bi-mode type. The vibration frequency of rubber dampered flywheel which weight is decreased was slightly increased as compared with original flywheel.

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A Probabilistic Study on Seismic Response of Seismically Isolated Nuclear Power Plant Structures using Lead Rubber Bearing (LRB 면진장치를 적용한 원전구조물의 지진응답에 따른 확률론적 연구)

  • Kim, Hyeon-Jeong;Song, Jong-Keol;Moon, Ji-Ho
    • Journal of the Earthquake Engineering Society of Korea
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    • v.22 no.2
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    • pp.45-54
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    • 2018
  • The seismically isolated nuclear power plants shall be designed for design basis earthquake (DBE) and considered to ensure safety against beyond design basis earthquake (BDBE). In order to limit the excessive displacement of the seismic isolation system of the seismically isolated structure, the moat is installed at a certain distance from the upper mat supporting the superstructure. This certain distance is called clearance to stop (CS) and is calculated from the 90th percentile displacement of seismic isolation system subjected to BDBE. For design purposes, the CS can be obtained simply by multiplying the median displacement of the seismic isolation system against DBE by scale factor with a value of 3. The DBE and BDBE used in this study were generated by using 30 sets of artificial earthquakes corresponding to the nuclear standard design spectrum. In addition, latin hyper cube sampling was applied to generate 30 sets of artificial earthquakes corresponding to maximum - minimum spectra. For the DBE, the median displacement and the 99th percentile displacement of the seismic isolation system were calculated. For the BDBE, the suitability of the scale factor was assessed after calculating the 90th percentile displacement of the seismic isolation system.

Background Reduction for the ${\gamma}$-Ray Spectrometry of Environmental Radioactivity (환경방사능의 감마선 분광분석을 위한 백그라운드 소멸)

  • Seo, Bum Kyoung;Lee, Kil Yong;Yoon, Yoon Yeol;Lee, Dae Won
    • Analytical Science and Technology
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    • v.14 no.3
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    • pp.212-220
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    • 2001
  • This study was performed to establish the analytical method of radium and radon in various environmental samples with the ${\gamma}$-ray spectrometry. The major problem in the measurements of low level ${\gamma}$-ray, such as environmental radioactivity, is the fluctuation of ${\gamma}$-ray background spectrum. To overcome this problem, a nitrogen gas was filled up in the detector chamber to reduce the background counts due to airborne radioactivities, i.e., $^{214}Pb$ and $^{214}Bi$, the daughters of $^{222}Rn$ in air. When nitrogen gas flowed around the detector, peak counts of ${\gamma}$-rays from the daughters of $^{222}Rn$ decreased about 80% below 1 MeV and about 20~50% above 1 MeV. The use of nitrogen purging results in approximately tenfold increment of sensitivity.

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DEVELOPMENT OF THE FAST IMAGING SOLAR SPECTROGRAPH FOR 1.6 m NEW SOLAR TELESCOPE (1.6 m 신태양망원경용 고속영상태양분광기 개발)

  • Nah, Ja-Kyoung;Chae, Jong-Chul;Park, Young-Deuk;Park, Hyung-Min;Jang, Bi-Ho;Ahn, Kwang-Su;Yang, Hee-Su;Cho, Kyung-Suk;Kim, Yeon-Han;Kim, Kwang-Dong;Cao, Wenda;Gorceix, Nicolas;Goode, Philip. R.
    • Publications of The Korean Astronomical Society
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    • v.26 no.1
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    • pp.45-54
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    • 2011
  • KASI and Seoul National University developed the Fast Imaging Solar Spectrograph (FISS) as one of major scientific instruments for the 1.6 m New Solar Telescope (NST) and installed it in the Coude room of the NST at Big Bear Solar Observatory (BBSO) in May, 2010. The major objective of the FISS is to study the fine-scale structures and dynamics of plasma in the photosphere and chromosphere. To achieve it, the FISS is required to take data with a spectral resolution higher than $10^5$ at the spectrograph mode and a temporal resolution less than 10 seconds at the imaging mode. The FISS is a spectrograph using Echelle grating and has characteristics that can observe dual bands (H${\alpha}$ and CaII 8542) simultaneously and perform fast imaging using fast raster scan and two fast CCD cameras. In this paper, we introduce briefly the whole process of FISS development from the requirement analysis to the first observations.

Febrile urinary tract infection in children: changes in epidemiology, etiology, and antibiotic resistance patterns over a decade

  • Suh, Woosuck;Kim, Bi Na;Kang, Hyun Mi;Yang, Eun Ae;Rhim, Jung-Woo;Lee, Kyung-Yil
    • Clinical and Experimental Pediatrics
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    • v.64 no.6
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    • pp.293-300
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    • 2021
  • Background: Understanding the epidemiology and prevalence of febrile urinary tract infection (fUTI) in children is important for risk stratification and selecting appropriate urine sample collection candidates to aid in its diagnosis and treatment. Purpose: This study aimed to analyze the epidemiology, etiology, and changes in antibiotic susceptibility patterns of the first fUTI in children. Methods: This retrospective observational cohort study included children younger than 19 years of age who were diagnosed and treated for their first fUTI in 2006-2016. Electronic medical records were analyzed and radiologic images were evaluated. Results: A total of 359 patients (median age, 5.1 months; interquartile range, 3.0-10.5 months) fit the inclusion criteria; of them, 78.0% (n=280) were younger than 12 months old. The male to female ratio was 5.3:1 for patients aged 0-2 months, 2.1:1 for those 3-5 months, and 1.6:1 for those 6-11 months. Beyond 12 months of age, there was a female predominance. Escherichia coli was the leading cause (83.8%), followed by Enterococcus species (6.7%), and Klebsiella pneumoniae (3.6%). Significant yearly increases in the proportions of multidrug-resistant strains (P<0.001) and extended-spectrum beta-lactamase (ESBL) producers (P<0.001) were observed. In patients with vesicoureteral reflux (VUR), the overall recurrence rate was 53.6% (n=15). A significantly higher recurrence rate was observed when the fUTI was caused by an ESBL versus non-ESBL producer (75.0% vs. 30.0%, P=0.03). Conclusion: fUTI was most prevalent in children younger than 12 months of age and showed a female predominance in patients older than 12 months of age. The proportion of ESBL producers causing fUTI is increasing. Carbapenems, rather than noncarbapenems, should be considered for treating fUTI caused by ESBL-producing enteric gram-negative rods to reduce short-term recurrence rates in children with VUR.