• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.1
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• pp.69-73
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• 2001

In this study, we fabricated Bi-2223/Ag high temperature superconducting tapes using PIT(Powder-In-Tube) process to apply the superconducting magnet, cable and etc. It is inevitable to deform the superconducting taps with axial strain for application. Therefore, for the characterization of the strain sensitivity of the superconducting properties, the degradation of Bi-2223/Ag tapes due to axial strain were investigated by measuring the critical current as a function of applied tension strain and external magnetic field. The critical current of Bi-2223/Ag tapes were decreased slightly up to 0.3∼0.4% applied strain but, drastically decreased more than these strains. Superconducting filament cores consisted of brittle ceramic fibers were broken easily by the large strain and current path were decreased simultaneously.

• Transactions of Materials Processing
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• v.13 no.1
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• pp.78-83
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• 2004

High-temperature superconduction materials(Bi2223) possess electrical/electronic and magnetic properties. Because high-temperature superconduction materials is a ceramic powder, that cannot be produced singlehandedly. So Ag sheathed Bi-2223 wire was produced by drawing process using powder-in-tube(PIT) method. This superconductor has many difficulties to produce. The main difficulty is that the mechanical properties of the ceramic powder are very different from those of the Ag sheath. And by these properties, Bi2223 high-temperature superconductor, which has a single filament drawing process and multi-filament drawing process, has a defect like sausaging and bursting at a center. This study analyzed multi-filament drawing process by FEM, and a defect generated during multi-filament drawing was studied by FEH. Specially, in order to prevent a bursting at a center, this study presented a method that inserts a pure Ag at a center of multi-filament wire

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 2003.02a
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• pp.220-223
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• 2003

High-Tc superconducting(HT S) systems are commercialized by many study on high-Tc superconductor. For the successful commercialization of superconducting systems using Bi-2223 wires, the database on the degradation of critical current is essentially needed. In this paper, critical current variation of Bi-2223 wires according to the transport time was investigated. The degradation rate of critical current was also calculated. Solenoid type specimens have the length of 190cm Bi-2223 wire and double-pancake type specimens have the length of l0m wire were tested. Tested Bi-2223 wires are commercialized products of AMSC (American Superconductor) and Innost. When the transportation current was 95% of critical current, the degradation of critical current was appeared after 5 hours of transport time.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 2003.02a
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• pp.105-108
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• 2003

Long length of Bi-2223 superconducting wires were fabricated by stacking, drawing process with different precursor owders and different heat-treatment histories. The precursor powders were 2 kinds of Pb content. And a part of the tapes were experienced pre-annealing process which caused tetragonal structure of Bi-2212 phase to orthorhombic structure of it was during drawing process. We confirmed the transformation of Bi-2212 phase from tetragonal structure to orthorhombic structure and reduction of second phases. We designed and made a continuous Ic measurement system for Bi-2223/Ag HTS tape. We could achieve best Ic of 65 A at the Bi-2223/Ag tape using low Pb content of precursor powder and experienced pre-annealing process.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 1999.02a
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• pp.10-13
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• 1999

For large scale applications of high temperature superconductor(HTS) such as transmission cables, motors and generators, long length of flexible HTS conductors is required. Currently, HTS tape that is capable of being fabricated in long length by industrial processes is the Bi-2223 HTS tape. In this study, we fabricated 19 filamentary Bi-2223($Bi_{1.8}$$Pb_{0.4}$$Sr_{2}$$Ca_{2}$$Cu_{3}$$O_{10+X}$) HTS tape with 100m length by PIT(Powder In Tube) process. Critical current(Ic) of this long length tape was measured 18.5 A at 77 K, self field and short sample Ic is 32.5 A at the same condition. Critical current of 100m length tape was decreased by about 1/3 compared to that of short tape. This was mainly resulted from the increase of non homogeneity in oxide layer.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 2003.10a
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• pp.63-66
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• 2003

1 km length of Bi-2223/Ag superconducting wires were fabricated by stacking, drawing process with advanced heat-treatment schedules. Intermediate annealing was carried out to increase the homogeneity and uniformity of the superconducting filaments embedded in the silver matrix. Phase modification from tetragonal to orthorhombic Bi-2212 by pre heat treatment(PHT) was executed to improve the texture and phase transformation of Bi-2223. Drawing stress was measured to Predict the sausaging and stress limit, Rolling parameters such as thickness, width and winding tension were investigated to roll the tape with uniformity. Critical current of 1 km length of superconducting tapes was measured about 50 A continuously after final sintering.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.05a
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• pp.25-29
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• 2003

Pre-treatment of Bi-2223/Ag tapes has been investigated to improve the superconducting property and grain alignment. However, rolling deformability of Bi-2223/Ag wires was degraded by the breakage of Ag alloy sheath after pre-treatment. Various pre-treatment conditions were tried to prevent the problem of sliver sheath and improve the superconducting property of Bi-2223/Ag tapes. Filament precursor of Bi-2223/Ag tapes was modified to be textured easily during main sintering by the optimum pre-treatment with low oxygen pressure and up to $800^{\circ}C$. Critical current was also increased up to 20% than that of no pre-treated tape.

• Progress in Superconductivity
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• v.4 no.2
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• pp.176-179
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• 2003

A lot of efforts have been focused on the optimization of PIT parameters for Bi-2223/Ag wire. Bi-2223 superconducting wires with 55 filaments were fabricated by stacking, drawing process. Before rolling process, round wires were pre -annealed at 760 - 820 $^{\circ}C$ and low oxygen partial pressure. We confirmed that pre-annealing step was to transform Bi-2212 orthorhombic structure from Bi-2212 tetragonal structure and to reduce the formation of second phases. However Bi-2223 phases also were formed at higher than 76$0^{\circ}C$ of pre-annealing temperature. The engineering critical current densities (Je) of Bi-22231Ag tapes were sintered at low oxygen partial pressure were higher than t hat of the wires sintered at air. We could achieve 6500 A/${cm}^2$ of Je for the tape that was initially kept at slightly higher temperature than that of normal heat treatment.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2003.05a
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• pp.311-314
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• 2003

Superconduction materials possess electrical/electronic and magnetic properties. Because superconduction materials is a ceramic powder, that can not be produced singlehandedly. So Ag sheathed Bi-2223 wire was produced by drawing process using powder-in-tube(PIT) method This superconductor has many difficulties to produce. The main difficulty is that the mechanical properties of the ceramic powder are very different from those of the Ag sheath. Actually, the fabrication of Ag sheathed Bi-2223 superconductor by PIT tends to lead to non-uniformity in the core thickness during drawing process. That is so called “Sausaging”. This study analyzed a sausaging using the finite-element method. Also, Effects of drawing process parameters on a sausaging has been carried out using finite element method. Finally, A way to prevent a sausaging has been discussed.

• Progress in Superconductivity
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• v.5 no.2
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• pp.124-127
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• 2004

Many of research efforts have been focused on the improvement of critical current density (Jc) of silver-sheathed Bi-2223 tapes far practical applications. In this study, the transformation of Bi-2212 phase was investigated, which was transformed to orthorhombic from tetragonal through pre-annealing during powder packing and drawing process. The relationship between hardness of Bi-2212 orthorhombic phase and workability of Bi-2223/Ag tape was investigated. Bi-2223 superconducting wires with 55 filaments were fabricated by stacking and drawing process with different heat-treatment histories. Before rolling process, round wires were pre-annealing at 76$0^{\circ}C$ and in a low oxygen partial pressure. We confirmed that pre-annealing step was to transform to Bi-2212 orthorhombic structure from Bi-2212 tetragonal structure and to reduce the formation of second phases. However the breakages were created at Ag-alloy clad during rolling for pre-annealed Bi-22231Ag tapes. Several pre-annealing scenarios were introduced to reduce the breakages during rolling process. Microstructure and critical current density of pre-annealed Bi-2223 superconducting tapes were investigated. We could achieve proper pre-annealing conditions for Ag-alloy clad Bi-2223 superconducting tapes.