• 전기의세계
• /
• v.53 no.8
• /
• pp.39-42
• /
• 2004

초전도 재료는 선재의 형태로 가공하면 송전선이나, 변압기, 발전기 및 전력 저장장치와 같이 전력 응용의 효율을 극대화시킬 수 있는 재료로서 널리 활용되고 있다. 1987년 개발된 고온 산화물 초전도체는 액체질소 의 비등점인 77K 이상에서 초전도 현상을 나타내어 초전도 현상의 응용에 대한 기대를 고조시켜 이에 대한 연구 개발을 더욱 향상시키고 있다. 초전도 선재에 관한 연구는 주로 PIT( Powder in Tube )공정을 이용한 Ag/Bi 2223 선재가 우수한 전기적 특성과 가공의 우수성으로 인하여 개발되어 왔다. 그러나 Ag/Bi 2223 선재는 강한 자기장 하에서 통전 특성이 현저하게 저하되는 결점이 있다. (중략)

• Korean Journal of Materials Research
• /
• v.7 no.2
• /
• pp.140-144
• /
• 1997

The effects of the particle size of precursor powder on the microstructure and Jc of Ag-sheathed Ri-2223 tapes were investigated. The calcined powder with overall composition of $Bi_{1-89}Pb_{0-41}Sr_{2-01}Ca_{2-23}Cu_{3-03}O_{y}$ was milled for various times using planetary ball mill. The transport property of the tapes were found to depend strongly on the particle size of the precursor powder Enhanced reactivity of the milled powder facilitated the formation of 2223 phase and resulted in an increase of Jc. Excessive milling, however, led to the amorphisation of the powder and degraded the electrical property of the tapes.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.11 no.11
• /
• pp.1028-1034
• /
• 1998

Bi-2223 superconductor is known as one of the candidates for practical superconducting wires. Ag-sheathed Bi-2223 superconducting wires were fabricated using the powder-in-tube(PIT) method. When the 19-filaments wire was immersed in liquid nitrogen(77K), maximum critical current density Jc of 62 A/$mm_2$ at 0T was achieved. The critical current density has been shown to depend on the mechanical properties such as tensile stress and bending strain in Ag-sheathed Bi-2223 superconducting wires. The tensile strain for Jc degradation onset was in the range of 0.12~0.3%. In the case of 19-filaments wire, the bending strain is estimated to be smaller than 0.3% for the reasonable Jc value. The observed degradation of the critical current density due to strain effect is inevitable and can be attributed to the formation of microcracks within the superconducting core.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.13 no.8
• /
• pp.718-723
• /
• 2000

The critical characteristics of Bi-2223 HTS tapes made by PIT method are influenced by the heat treatment and the mechanical processing. In this study firstly we investigated the influence o rolling reduction rate in mechanical process for improving Jc of HTS tapes. As a result the optimized rolling reduction rate that we obtained was 10%-50% and 30%-30% (1st-2nd). And then we fabricated the stacking type HTS tapes that made of the multi-filamentary tapes with various length(3, 5, 10cm) and with various number of stacking (1, 5, 10 layer). Measuring the critical current and observing the structure of grain we concluded that the stacking type tapes will be able to operate more stably by adding the number of stacking tapes. And we could expect that by minimizing the gap between Ag-sheath of tapes mechanical strength of stacking HTS tapes is enhanced and current in tapes will flow more stably.

• Proceedings of the Korea Crystallographic Association Conference
• /
• 2003.05a
• /
• pp.24-24
• /
• 2003

고온초전도 BSCCO 2223 ((Bi, Pb)₂Sr₂Ca₂Cu₃O/sub x/) 선재의 특성을 향상시키기 위해서는 반복적인 인발 및 압연과정을 통한 texturing향상, BSCCO 2223입자의 배향성 증대, 피복재내 초전도체의 충진율(밀도)향상, 이차상의 부피분율 감소등이 이루어져야 한다. 최적 열처리 조건을 통하여 열처리 시에 형성되는 이차상인 (Bi,Pb)₂Sr₂CuO/sub y/ (2201, amorphous phase)를 조절하면서, (Ca,Sr)₂CuO₃ (2/1 AEC), (Ca,Sr)/sub 14/Cu/sub 24/O/sub 41/ (14/24 AEC)와 같은 이차상들의 부피분율 및 크기를 감소시켜야만 한다. 본 실험에서는 BSCCO 2223 선재의 특성을 향상시킬수 있는 최적의 열처리 조건 확립 및 기계적 공정시 나타나는 여러 가지 문제점을 개선하여 높은 임계전류를 가지는 선재의 특성을 분석하고자 하였다. 최종적으로 제조된 선재는 2223상 결정이 피복재(Ag)와 평행하게 길게 성장하며, AEC상의 크기와 부피분율이 감소할수록 더 높은 임계전류특성을 나타내었다(I/sub c/～70A, J/sub c/～42,000 A/㎠). 또한 이 선재에서 나타나는 여러 가지 이차상들을 분석하기 위하여 XRD, SEM, EDS 분석을 행하였다.

• Proceedings of the KIEE Conference
• /
• summer
• /
• pp.833-835
• /
• 2004

초전도 선재를 전력 기기에 적절히 응용하기 위하여 사고 시 과전류에 대한 안전성 여부를 확인할 필요가 있다. 본 논문에서는 임계전류 이상의 영역에서 Bi-2223 선재의 저항 및 온도변화 특성을 알아보았다. 임계전류가 57 A인 Bi-2223 선재에 임계 전류 이상의 과전류를 인가한 후 전류 크기 및 사고시간에 따른 저항 변화를 조사하였다. 또한 열전대를 사용하여 과전류 인가에 따른 선재의 온도 변화를 측정하여 저항에 의해 유추한 결과와 상호 비교하였다. 이로부터 Bi-2223 선재에 과전류 인가 시 발생된 저항으로부터 간접적으로 얻은 선재의 온도와 측정된 줄열은 매우 잘 일치하였으며, 이로부터 과전류 인가 시간과 크기에 따른 선재의 온도 변화를 예측할 수 있었다.

• Journal of the Korean Ceramic Society
• /
• v.35 no.2
• /
• pp.137-144
• /
• 1998

High-temperature superconducting joints between 61 filaments of Bi-2223 tapes were fabricated by chem-ical corrosion and repeated thermomechanical process. The silver sheath of the superconducting tape was chemically removed using chemical etchant(NH4OH:H2O2=1:1) from one side of each tape without altering the form of lap joint. The joined region was formed by uniaxial pressing and a series of thermomechanical process and then subjected to properties measurement and microstructural analysis. The critical current(Ic) variation and I-V characteristics along the joint were mesured with several configuration of proble points. Ic value of the transition region of the joint inthe multifilament tape which limit the total current carring capacity of the superconducting tape was higher than that of monofilament tape. But the transition ex-ponent n-value of the multi-filament tape was lower than that of monofilament wire due to the interaction of the individual superconducting core of the multi-filament. The critical current through the joint area was improved by respeated press and reaction annealing treatment.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 1997.05a
• /
• pp.44-44
• /
• 1997

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
• /
• 2000.02a
• /
• pp.101-103
• /
• 2000

In the present work, we have investigated the combined effect of high-energy milling and Agb addition on microstructure and superconducting properties for Bi-2223/Ag. tape. The addition of siver plays an important role in enhancing liquid phase formation, Resulting in densification and cracking during solidification. Further study is needed for the optimization of Ag content and heat-treatment which can reduce the cracking.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2002.07a
• /
• pp.527-530
• /
• 2002

A lot of efforts have been focused on the optimization of PIT parameters for Bi-2223/Ag wire. In this paper, initial annealing of Bi-2223/Ag wire to transform Bi-2212 orthorhombic from Bi-2212 tetragonal Precursor was investigated. This initial annealing step at low oxygen partial pressure were to transform Bi-2212 orthorhombic structure and to reduce the formation of second phases at superconducting wire. However Bi-2223 Phases were appeared at higher annealing temperature. Critical currents(Je) of Bi-2223/Ag tapes were sintered at low oxygen Partial pressure were higher than that of the wires sintered at atmosphere condition. In order to investigate the effect of rolling reduction ratio, Bi-2223/Ag HTS tapes were rolled with different reduction ratio. There were no clear difference of Je and filaments shape with various rolling reduction ratio.