• Title/Summary/Keyword: Bi content

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Evolution on Microstructure and Mechanical Property of Ti65Fe35 Hypereutectic Alloys by Adding Low Melting Temperature Elements (저융점 원소의 첨가에 따른 Ti65Fe35 과공정 합금의 미세구조와 기계적 특성의 변화)

  • Hwang, Yun Jung;Hong, Sung Hwan;Kim, Jeong Tae;Kim, Young Seok;Park, Hae Jin;Kim, Hee Jin;Jeong, Yeon Beom;Lee, Young Hoon;Kim, Ki Buem
    • Korean Journal of Materials Research
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    • v.27 no.10
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    • pp.557-562
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    • 2017
  • The microstructural evolution and modulation of mechanical properties were investigated for a $Ti_{65}Fe_{35}$ hypereutectic alloy by addition of $Bi_{53}In_{47}$ eutectic alloys. The microstructure of these alloys changed with the additional BiIn elements from a typical dendrite-eutectic composite to a bimodal eutectic structure with primary dendrite phases. In particular, the primary dendrite phase changed from a TiFe intermetallic compound into a ${\beta}$-Ti solid solution despite their higher Fe content. Compressive tests at room temperature demonstrated that the yield strength slightly decreased but the plasticity evidently increased with an increasing Bi-In content, which led to the formation of a bimodal eutectic structure (${\beta}$-Ti/TiFe + ${\beta}$-Ti/BiIn containing phase). Furthermore, the (Ti65Fe35)95(Bi53In47)5 alloy exhibited optimized mechanical properties with high strength (1319MPa) and reasonable plasticity (14.2 %). The results of this study indicate that the transition of the eutectic structure, the type of primary phases and the supersaturation in the ${\beta}$-Ti phase are crucial factors for controlling the mechanical properties of the ultrafine dendrite-eutectic composites.

Enhancement of Magneto-Optic Figure of Merit of Bi:YIG Films in Blue Wavelengths by La Substitution

  • Lee, Euibok;Jaekyong Cho
    • Journal of Magnetics
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    • v.2 no.2
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    • pp.46-49
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    • 1997
  • This paper reports the first success in enhancement of the magneto-optic figure of merit of garnet films in blue wavelengths. The maximum of the absolute value of the Faraday rotation angle observed at about 500 nm for the films with no La substitution shifted toward shorter wavelength as La content increased, that leads the increase of the absolute value of the Faraday rotation angle in the wavelengths shorter than about 480 nm. The optical absorption coefficient at the wavelengths shorter than 500 nm decreased as La content increased. As a result the magneto-optic figure of merit increased in the wavelengths shorter than 470 nm as La content increased and was about two times larger for the film with La content of 0.6 in formular unit compared to that of the film without La substitution. This might be attributed to the shift of the centers of the charge transfer and crystal field transitions by La substitution.

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Implementation of Bi-directional Optic EtherCAT Communication Module based on WDM Method (WDM 방식의 양방향 광 이더캣 통신 모듈 구현)

  • Moon, Yong-Seon;Roh, Sang-Hyun;Jo, Kwang-Hun;Bae, Young-Chul
    • The Journal of the Korea institute of electronic communication sciences
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    • v.7 no.2
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    • pp.409-415
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    • 2012
  • Recently in industry communication, the efforts that use robot and automation system increased by cooperation with optical communication and industrial Ethernet. In this paper, in order to solve the problem that total network blocking when network fault happens and wiring problem of optical cable, which were big serious disadvantage in industrial optical network systems, we propose bi-directional optical EtherCAT communication technique based on single optical core, which applying WDM method. We describe the content for implementation of WDM bi-directional optical EtherCAT communication module and performance evaluation to verify the performance of related technology as a whole.

Effects of Hydrogen Reduction in Microstructure, Mechanical and Thermoelectric Properties of Gas Atomized n-type Bi2Te2.7 Se0.3 Material

  • Rimal, Pradip;Yoon, Sang-Min;Kim, Eun-Bin;Lee, Chul-Hee;Hong, Soon-Jik
    • Journal of Powder Materials
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    • v.23 no.2
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    • pp.126-131
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    • 2016
  • The recent rise in applications of thermoelectric materials has attracted interest in studies toward the fabrication of thermoelectric materials using mass production techniques. In this study, we successfully fabricate n-type $Bi_2Te_{2.7}Se_{0.3}$ material by a combination of mass production powder metallurgy techniques, gas atomization, and spark plasma sintering. In addition, to examine the effects of hydrogen reduction in the microstructure, the thermoelectric and mechanical properties are measured and analyzed. Here, almost 60% of the oxygen content of the powder are eliminated after hydrogen reduction for 4 h at $360^{\circ}C$. Micrographs of the powder show that the reduced powder had a comparatively clean surface and larger grain sizes than unreduced powder. The density of the consolidated bulk using as-atomized powder and reduced atomized powder exceeds 99%. The thermoelectric power factor of the sample prepared by reduction of powder is 20% better than that of the sample prepared using unreduced powder.

In Vitro Assessment on Biological Activities of Methanol Extracts from Several Compositae Edible Plants

  • Chon, Sang-Uk;Kim, Tae-Soon;Boo, Hee-Ock
    • Korean Journal of Plant Resources
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    • v.21 no.3
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    • pp.196-203
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    • 2008
  • Phytotoxicity, antioxidant activity, and cytotoxicity of the aqueous or methanol extracts from the young sprouts of the six Compositae medicinal plants were determined. Aqueous leachates at 40g dry tissue $L^{-1}$ (g $L^{-1}$) Cirsium japonicum and Aster yomena showed the highest inhibitory effect on alfalfa (Medicago sativa L.). Total phenolic content showed the highest amount in methanol extracts from Ixeris dentata, and followed by A. yomena, and Cephalonoplos segetum. Methanol extracts of C. segetum and I. dentata at 25${\mu}g$ m$L^{-1}$ exhibited the highest DPPH radical scavenging activity by 87.2, and 52.8%, respectively. By means of HPLC analysis, MeOH extracts of C. segetum had the highest amount of antioxidant chlorogenic acid. Based on MTT assay, the methanol extracts from Y. sonchifolia ($IC_{50}$ = 65.7${\mu}g$ $mL^{-1}$) showed the highest cytotoxicity against Calu-6. These results suggest that plant extracts had a dose-dependent biological potentials including phytotoxicity, antioxidant activity, and anticancer activity, and that their activities exhibited differently depending on plant species.

Enhancing Electrical Properties of N-type Bismuth Telluride Alloys through Graphene Oxide Incorporation in Extrusion 3D Printing

  • Jinhee Bae;Seungki Jo ;Kyung Tae Kim
    • Journal of Powder Materials
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    • v.30 no.4
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    • pp.318-323
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    • 2023
  • The thermoelectric effect, which converts waste heat into electricity, holds promise as a renewable energy technology. Recently, bismuth telluride (Bi2Te3)-based alloys are being recognized as important materials for practical applications in the temperature range from room temperature to 500 K. However, conventional sintering processes impose limitations on shape-changeable and tailorable Bi2Te3 materials. To overcome these issues, three-dimensional (3D) printing (additive manufacturing) is being adopted. Although some research results have been reported, relatively few studies on 3D printed thermoelectric materials are being carried out. In this study, we utilize extrusion 3D printing to manufacture n-type Bi1.7Sb0.3Te3 (N-BST). The ink is produced without using organic binders, which could negatively influence its thermoelectric properties. Furthermore, we introduce graphene oxide (GO) at the crystal interface to enhance the electrical properties. The formed N-BST composites exhibit significantly improved electrical conductivity and a higher Seebeck coefficient as the GO content increases. Therefore, we propose that the combination of the extrusion 3D printing process (Direct Ink Writing, DIW) and the incorporation of GO into N-BST offers a convenient and effective approach for achieving higher thermoelectric efficiency.

Microwave Dielectric Properties and Multilayer Characteristics of (1-x)BiNbO4-xCaNb2O6 Ceramics ((1-x)BiNbO4-xCaNb2O6 세라믹스의 마이크파 유전특성 및 적층체 특성)

  • Kim, Eung-Soo;Choi, Woong;Kim, Jong-Dae;Kang, Seung-Gu;Shim, Kwang-Bo
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1190-1196
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    • 2002
  • Microwave dielectric properties and multilayer characteristics $(1-x)BiNbO_4-xCaNb_2O_6$ (0${\le}$x${\le}$1.0) ceramics were investigated as a function of $CaNb_2O_6$ content. In the composition range of 0.25${\le}$x${\le}$0.75, the mixture phases of $BiNbO_4$ with stibotantalate structure and $CaNb_2O_6$ with columbite structure were detected and secondary phase or phase transition were not detected. Dielectric constant (K) of $(1-x)BiNbO_4-xCaNb_2O_6$ ceramics was largely dependent on the existing phase and could be estimated by the dielectric mixing rule calculated from maxwell equation. Typically, dielectric constant (K) of 26, quality factor (Qf) of 4300 GHz and Temperature Coefficient of resonant Frequency (TCF) of -18 ppm/${\circ}C$ were obtained for $0.5BiNbO_4-0.5CaNb_2O_6$ specimens with 0.8 wt% $CuV_2O_6$ sintered at 1000${\circ}C$ for 3h. The deviation of X-Y shrinkage and camber value of the multilayers obtained from $0.5BiNbO_4-0.5CaNb_2O_6$ green sheet sintered at 850∼950${\circ}C$ for 20 min. were smaller than those of $BiNbO_4$ multilayers.

Effect of the $SiO_2$ Addition on the Electrical and Degradation Property of Bi based ZnO Varistor (비스무스계 ZnO 바리스타의 $SiO_2$ 첨가에 따른 전기적특성 및 열화특성)

  • Heo, Jong-Cheol;Kim, Hyung-Sik;Park, Tae-Gone
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1522-1524
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    • 1998
  • Experimental results on the effect of $SiO_2$ addition to Bi based ZnO varistor show that secondary phases in microstructure and nonlinear coefficient are increased, and that leakage current is decreased with $SiO_2$ additive content. The varistor with 0.1 mol%-$SiO_2$ additive exhibits lower resistive current than other specimen at ($E_{1mA}$ x 0.6) applied voltage and temperature of $115^{\circ}C$ for 350h.

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A Study on the Microwave Dielectric Properties of A1$_2$O$_3$ Ceramics Resonator added with Impurities (불순물 첨가에 따른 A1$_2$O$_3$ 세라믹 공진기의 마이크로파 유전특성에 관한 연구)

  • 이문기;박인길;류기윈;이성갑;이영희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.64-67
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    • 1997
  • Microwave dielectric properties of A1$_2$O$_3$ ceramics resonator were investigated with impurity addition. Increasing the contents of Bi$_2$O$_3$Q-value and Q $\times$ f were increased. In the specimen with the content of Bi$_2$O$_3$(0.3wt%), dielectric constant, quality factor and temperature coefficient of resonant frequency(TCRF, $\tau$$_{f}$) had a good values of 10.76,23,253(at 9.68[GHz]) and -39.09(ppm/$^{\circ}C$), respectively. The TCRF value was decreased with MnO$_2$ and increased with Sm$_2$O$_3$. La$_2$O$_3$.>.

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In Vitro Cytotoxicity against Human Cancer Cell and 3T3-L1 Cell, Total Polyphenol Content and DPPH Radical Scavenging of Codonopsis lanceolata according to the Concentration of Ethanol Solvent

  • Boo, Hee-Ock;Park, Jeong-Hun;Lee, Moon-Soon;Kwon, Soo-Jeong;Kim, Hag-Hyun
    • Korean Journal of Plant Resources
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    • v.31 no.3
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    • pp.195-201
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    • 2018
  • This study was executed to evaluate the phenolic content, DPPH radical scavenging rate, and the cytotoxic effect in human cancer cell, 3T3-L1 cell from C. lanceolata extracts at various ethanol concentration. Total polyphenol and flavonoid content of the C. lanceolata at various ethanol concentration showed the high amount in 70%, 100% ethanol extract. The DPPH radical scavenging activity progressively increased in a dose-dependent manner, and showed the highest in 100% ethanol extract. The cytotoxic effect against human cancer cell of the C. lanceolata was higher in 50% and 70% ethanol extracts. In particular, the cytotoxic effect in MCF-7 cell was relatively higher than in other cells. The $IC_{50}$ (concentration causing 50% cell death) value showed the highest on MCF-7 cell ($538.39{\mu}g/m{\ell}$ in 70% ethanol extract, and exhibited significant activity against Hela cell ($637.87{\mu}g/m{\ell}$, Calu-6 cell ($728.64{\mu}g/m{\ell}$. The extract of 70% ethanol at $1,000{\mu}g/m{\ell}$ exhibited a pronounced cytotoxic effect on 3T3-L1 cell comparable to that of the other extracts, and reduced in a concentration-dependent manner.