• Journal of the Korean Society of Clothing and Textiles
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• v.19 no.6
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• pp.946-954
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• 1995

The purpose of this study is to modify the hydrophobic property and dyeability of polyethylene terephthalate fiber. Methacrylic acid (2nA) was graftpolymerized with benzoyl peroxide (BPO) as initiator onto polyethylene terephthalate fabrics. The results were as follow; 1. Graft-polymerization exhibited maximum graft ratio at a temperature of 100"C. 2. The polymer was gradually grafted in great amount to the surface of MA-g-PET as graft ration increase; with the cross-section examination of MA-g-PET, it was discovered that graft-polymeriation had also taken place inside the textile core. 3. Dyes absorption of basic dyes and disperse dyes was improved as craft ratio increase; with resistance to laundering, the former showed grade 3-4 and the latter showed grade 5.de 5.

• Elastomers and Composites
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• v.24 no.4
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• pp.265-275
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• 1989

The graft copolymerizations of acrylonitrile (AN) and methyl methacrylate (MMA) onto chloroprene rubber (CR) were carried out with benzoyl peroxide(BPO) as an initiator. The effect of solvent, mole ratio of AN to MMA, reaction time and temperature, and initiator concentration on graft copolymerization were examined. It was observed that the grafting efficiency increased as increasing mole ratio of AN to MMA. the graft copolymer, acrylonitrile- CR-methyl methacrylate (ACM), was identified by infrared spectroscopy and morphology. Thermal stability of ACM was found to be improved when compared with those of CR.

• Journal of the Korean Society of Clothing and Textiles
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• v.10 no.2
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• pp.79-84
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• 1986

Methacrylic acid was graft polymerized with benzoyl peroxide in itiator onto the commercial PET film. Graft polymerization was carried out in emulsion, which consisted of BPO (1), chlorobenzene(8) as swelling agent, tween 80(1) and sodium lauryl sulfate(1) as emulsifier and water(1,000). Original PET film has poor reactivities and, so the film preswdled with benzyl alcohol($150^{\circ}C$, 1hr) was also examined. The graft yield of PET film was increased with reaction temperature and monomer concentration. The graft yield of preswelled PET film was higher than that of no-treated PET film. Moisture regain was linearly increased with graft yield. DSC thermodiagram showed the Tm of grafted PET film was same as that of original PET film. Grafted PET film was dyed with methylene blue solution. The photograph of the cross section showed that grafting was occured not at the center but near surfaces.

• International Journal of Safety
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• v.2 no.1
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• pp.28-33
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• 2003

Thermal decomposition characteristics of ethyl methacrylate (EMA) and Styrene (St.) copolymer was investigated with synthesis at 8$0^{\circ}C$ in a continuous stirred tank reacto (CSTR) using toluene and benzoyl peroxide(BPO) as solvent and initiator, respectively. The thermal decomposition was considered to be side scission at below 30$0^{\circ}C$ and estimated 2nd-order reaction kinetics of EMA/St. copolymer. The activation energies of decomposition on this copolymers were in the ranges of 38-43 kcal/mol for EMA/St. and a good additivity rule was observed in each composition. The thermogravimetric trace curves agreed well with the theoretical calculation.

• Journal of the Korean Applied Science and Technology
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• v.19 no.4
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• pp.273-280
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• 2002

Thermal decomposition of the copolymer of butyl methacylate(BMA) with styrene(St) was investigated. The copolymer Was obtained at 80 $^{\circ}C$ in a continuous stirred tank reactor(CSTR) using toluene and benzoyl peroxide(BPO), as solvent and initiator, respectively. The reactor volume was 0.3 liters and residence time was 3 hours. The thermal decomposition followed the second order kinetics for BMA/St copolymer. The activation energies of thermal decompositon were in the ranges of 38 ${\sim}43$ kcal/mol for BMA with St copolymer and a good additivity rule was observed with the composition of copolymer. The thermogravimetric trace curve agreed well with the theoretical calculation.

• Elastomers and Composites
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• v.32 no.1
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• pp.11-19
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• 1997

[ ${\gamm}-Glycidoxy$ ] propyl trimethoxy silane, CTBN rubber(carboxyl terminated butadiene acrylonitrile rubber) and GMA(glycidyl methacrylate) were reacted on the surface of silica one by one in existence of TEA(triethylamine) or BPO(benzoyl peroxide). The amount of reactant was $2.5{\sim}5.8%$ of treated silica weight. The treated silica was mixed with epoxy resin and MTHPA(methyl tetrahydro phthalic anhydride) in the range of $0{\sim}60%$(wt.%) of total component. The thermal properties were tested for cured products. By using silica treated with silane/rubber or silane/rubber/vinyl, comparing with 3% of rubber mixed directly, it had 13% higher $T_g$ and 10% lower thermal expansion coefficient at $35{\sim}55%$ of silica contents.

• Journal of Physiology & Pathology in Korean Medicine
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• v.24 no.4
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• pp.653-660
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• 2010

Pulsatillae Radix and Cicadidae Periostracum have long been used for treatment of injuries, inflammations or itchiness in Korea. This study was carried out to examine the acne-remedy effects of the mixture made with equal parts of Pulsatillae Radix extract and Cicadidae Periostracum extract (PRCP) compared with 2%-benzoyl peroxide (Standard) used commercially as anti-acne. The results showed the mixture (PRCP) was more effective than each crude drug extract. The 10%-PRCP showed significant antimicrobial activity against Propionibacterium acnes, the major cause of acne, and also showed significant inhibition from type 1 $5{\alpha}$-reductase ($5{\alpha}R$), another cause of acne, And the cream made with PRCP demonstrated anti-sebum and acne-improvement effects on examinee's facial skin.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.12
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• pp.1033-1038
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• 2002

In this study, urethane acrylate macromer was synthesized and it was used in a gel polymer electrolyte (GPE), and then its electrochemical performances were evaluated. LiCoO$_2$/GPE/graphite cells were Prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor consisting of urethane acrylate (UA), hexanediol dimethacrylate (HDDA) and benzoyl peroxide (BPO) had a low viscosity relatively ionic conductivity of the gel polymer electrolyte with UA at room temperature and -20$\^{C}$ was ca. 4.5 $\times$ 10$\^$-3/S$.$cm$\^$-1/ and 1.7 x 10$\^$-3/ S$.$cm$\^$-1/, respectively GPR was stable electrochemically up to potential of 4.i V vs. Li/Li$\^$+/. LiCoO$_2$/GPE/graphite cells showed good a high-rate and a low-temperature performance.

• Macromolecular Research
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• v.17 no.1
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• pp.14-18
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• 2009

The acceleration effect of various organic acids, such as methanesulfonic acid (MSA), ethanesulfonic acid (ESA), 4,4'-sulfonyldibenzoic acid (SDA), diphenylacetic acid (DPAA), and $\rho$-toluenesulfonic acid (TSA), on the rate of styrene bulk polymerization with 2,2,6,6-tetramethylpiperidinyloxy (TEMPO) and benzoyl peroxide (BPO) was investigated. The addition of organic acids significantly accelerated the rate. Among these organic acids, DPAA showed an efficient rate-accelerating effect with living nature of polymerization. When DPAA was used as a rate-accelerating additive for TEMPO-mediated living free radical polymerization (LFRP), the rate of polymerization was dramatically enhanced, the linearity of reaction kinetics was successfully maintained, and the polydispersity was effectively controlled.

• Elastomers and Composites
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• v.26 no.4
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• pp.296-303
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• 1991

Surface of crystalline silica was sequentially reacted with silane(A 187), liquid $rubber(CTBN{\times}8)$, and vinyl monomer(GMA) in existence of TEA(triethylamine) or BPO(benzoyl peroxide). It was mixed with epoxy resin at a ratio $0{\times}60%$ (vol. % ) of total component. For mixtures, viscous properties were investigated experimentally. 1) Coating ratio depended on pH of mixture and quantity of catalyst. 2) Treated silica represented lower viscosity than untreated. 3) Thixotropic index represented best at silica_content $15{\sim}23%$ and showed more large deviation over $120^{\circ}C$. 4) Relative viscosity followed kernel's at $0{\times}10%$ of silica content and get out of Mooney's at more than 15%.