• Journal of Applied Biological Chemistry
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• 제43권1호
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• pp.49-53
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• 2000

The in vitro metabolism of a new herbicide pyribenzoxim, {benzophenone O-[2,6-bis[(4,6-dimethoxy-2-pyrimidinyl)oxy]benzoyl]oxime} was studied using rice, barnyardgrass and rat liver microsomes. No metabolism of pyribenzoxim was observed with rice and barnyardgrass microsomes though the cvtochrome P450 was active, which was evidenced by the metabolism of cinnamic acid. With rat liver microsomes, four metabolites (M1, M2, M3, and M4) were produced while parent compound decreased. M1 and M2 were from the hydrolysis reactions and NADPH-dependent metabolites were M3 and M4 (major metabolite) which were hydroxylated by cytochrome P450. They were identified as bispyribac-sodium (M1), benzophenone oxime (M2), {benzophenone O-[2,6-bis[(5-hydroxy-4,6-dimethoxy-2-pyrimidinyl)oxy]-benzoyl]oxime}(M3), and {benzophenone O-[2[(5-hydroxy-4,6-dimethoxy-2l-pyrimidinyl)6-(4,.6dimethoxy-2-pyrimidinyl)oxy]benzoyl]oxime} (M4) through LC/MS/MS analyses. Based on the results obtained metabolic map of pyribenzoxim is proposed.

• Membrane and Water Treatment
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• 제7권6호
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• pp.507-520
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• 2016

The effect of ZnO on cellulose acetate in the removal of benzophenone-3 (BP-3) was investigated. The benzophenone-3 (BP-3) which is an endocrine disrupting chemical (EDC) was completely removed (100%) from the drinking water using Cellulose Acetate (CA) and zinc oxide (ZnO) composite membranes. The membranes were prepared by DIPS method and the filtration experiments were conducted by dead end filtration unit. The macrostructure of the membrane were studied by ATR-IR and XRD Spectra's. Atomic force microscopy (AFM) and Scanning electron microscopy (SEM) were used to study the micro properties of the membranes. The laboratory experiments such as water uptake study and pure water flux performed to confirm the increasing hydrophilicity. The enhancing hydrophilicity was confirmed with respect to higher the concentration of nanoparticles. Evaluation of BP-3 removal was carried in different experimental conditions, such as, different Trans membrane pressure and different concentration of feed. The membrane with low pressure showed better performance by rejecting 100% of BP-3. However, 1 ppm, 3 ppm and 6 ppm of feed solution was used and among them 3 ppm of feed solution gives 100% rejection. The ZnO nanoparticales enhances the performance of CA membrane by showing maximum rejection.

• Environmental Analysis Health and Toxicology
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• 제16권3호
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• pp.121-126
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• 2001

Analytical method of benzophenone (BP) in sediment and soil was developed by gas chromatography/mass selective detector/selected ion monitoring (GC/MSD/SIM). The ultrasonic extraction of US EPA (method 3550B) method and liquid-liquid extraction for sediment and soil samples were used for the analysis of BP from sediment and soil. BP was extracted with n-hexane. Organic layer was washed with 5% sodium chloride solution. 1∼2 l of the concentrated solution of organic layer was applied to GC/MSD. The retention time of BP peak was 11.10 min. Recovery (％) of BP by ultrasonication from sediment and soil samples was 96.0∼100.6％ and 40.0∼83.0％, respectively. Recovery of BP by liquid-liquid extraction was 51∼59％ in soil samples. The detection limit of BP in sediment and soil samples were determined to 0.1 ng/g.

• 분석과학
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• 제18권2호
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• pp.147-153
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• 2005

본 연구는 GC/MS를 이용하여 수질, 토양 및 저질 시료 중의 benzophenone (BP)을 분석하는 방법을 확립하고자 하였다. BP는 수질 시료 (100 mL)에서 n-hexane으로 추출하였으며, 토양 및 저질 시료 (10 g)에서는 먼저 메탄올로 추출한 후 hexane으로 다시 추출하여 농축시켜 분석하였다. 수질 시료 중의 BP 회수율은 71.4% 이상이었으며 토양에서의 회수율은 86.5-94.7%를 보였고 재현성은 19.8% 이하였다. 검정곡선은 상관계수 ($r^2$) 값이 수질과 토양 모두에서 0.998이상의 좋은 직선성을 보여주었다. 수질 시료의 경우 43지역 중 3지역의 수질에서 30-200 ng/L 농도 범위로 BP가 검출되었으며 토양과 저질 시료에서는 모든 지역에서 검출되지 않았다. 이 분석방법은 환경 중에 미량으로 존재하는 BP의 분석과 모니터링에 유용하게 사용할 수 있는 적합한 방법이라 사료된다.

• Bulletin of the Korean Chemical Society
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• 제34권7호
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• pp.2191-2194
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• 2013

• Korean Chemical Engineering Research
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• 제52권3호
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• pp.321-327
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• 2014

고분자 분산형 액정 렌즈는 40 wt%의 NOA65 prepolymer와 60 wt%의 E7 액정 균일 혼합물에 추가적으로 광개시제를 첨가하여 $11{\mu}m$와 $30{\mu}m$의 두께로 제작 되었다. 광개시제로 사용된 벤조페논은 상업적으로 판매되는 NOA65에 기본적으로 5.0 wt%의 함량으로 포함되어있다. 이 논문에서는 NOA65에 포함되어 있는 벤조페논의 농도가 스마트 전자 안경을 위한 고분자 분산형 액정 렌즈에 미치는 영향에 대해서 알아보았다. 광개시제는 NOA65와 E7 액정 혼합물 무게의 1, 2, 4, 8, 16 wt%씩 추가로 첨가되었다. 벤조페논이 첨가된 샘플이 가지는 구동 전압, 직선 구간의 기울기, 응답 시간, 명암비와 같은 전기-광학적 특성들은 벤조페논의 첨가 없이 NOA65 만을 사용해 만든 샘플에 비해 모두 개선되었다. 이러한 개선들은 벤조페논의 첨가로 인해 샘플 내부에 존재하는 액정 방울의 평균 직경 크기가 증가하는 것에 기인하였다. 액정 방울의 평균 직경 크기는 벤조페논을 0 wt%에서 8 wt%로 첨가함에 따라 $5.3{\mu}m$에서 $12.2{\mu}m$로 증가하였다. 광개시제의 농도 범위에 대해 구동 전압은 11.1 V에서 17.3 V의 범위를 보였고, 직선 구간에서의 기울기는 10.35 %T/V에서 13.96 %T/V의 범위를 보였다. 이 두 특성은 벤조페논의 첨가 없이 기본 NOA65로 만들어진 샘플에 비해 더욱 개선되었다. 벤조페논을 첨가하지 않고 샘플의 셀 간격을 $30{\mu}m$에서 $11{\mu}m$로 감소시킴에 따라 상승응답 시간은 0.47 ms에서 1.05 ms로, 하강 응답 시간은 18.64 ms에서 45.3 ms로 각각 증가하였고 명암비는 86.5에서 5.7로 크게 감소하였다. 두 특성 모두 셀 간격의 영향으로 저하되는 것을 확인하였으나 벤조페논의 첨가에 따라 상승 응답 시간은 0.77 ms, 하강 응답 시간은 41.04 ms로 각각 감소하였고 명암비는 16.7로 증가하여 다소 개선되는 것 또한 확인되었다.

• Macromolecular Research
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• 제14권3호
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• pp.300-305
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• 2006

The chemical structure of a semi-aromatic polyimide-I, which was prepared by the chemical imidization of cyclopentanetetracarboxylic dianhydride and 2,2-bis(4-aminophenyl)hexafluoropropane, was characterized by $^{13}C-NMR$ spectroscopy. The chemically imidized polyimide-I was used for the preparation of a photosensitive polyimide (PSPI) through the addition of benzophenone and benzophenone oxime hexamethylene diurethane (BOHD), a photobase generator containing oxime-urethane groups. The polyimide-I film containing benzophenone and BOHD was not soluble in 2.38 wt% tetrabutylammonium hydroxide solution in $H_2O$. However, it became soluble following irradiation with 310 nm UV light. A positive tone image with a resolution of $5{\mu}m$ was obtained with this PSPI, having sensitivity($D_c$) of $1.2J/cm^2$ and contrast(${\gamma}_p$) of 1.08. Thus, a polyimide, which is not intrinsically photosensitive, can become photosensitive through the addition of a photobase generator containing oxime-urethane groups as a photosensitive compound.

• 분석과학
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• 제16권1호
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• pp.59-69
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• 2003

Benzophenone (BZP) and 4-nitrotoluene (4-NT) listed as endocrine disrupting chemicals are suspected to contaminate ground water sites and soil. Analytical method for simultaneous determination of the two chemicals in soil and ground water was developed by gas chromatography-mass spectrometry. Water (100 ml) was extracted with hexane, and soil (10 g) was extracted with methanol and hexane. Recovery in water was >72% for BZP and 90-118% for 4-NT. Recovery for 4-NT and BZP in soil was 51-59% with coefficient variation of less than 19.5%. Calibration curves showed a good linearity with $r^2=0.997$. In water and soil collected at nation-wide sites, BZP was found at 5 sites among 43 water sites at the concentration of $14.87{\pm}3.83ng/100 ml$. No 4-NT was found. It is suggested that this method is appropriate to the simultaneous quantitation of 4-NT and BZP in ground water and soil samples.

• 한국염색가공학회지
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• 제22권3호
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• pp.214-219
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• 2010

Polyethylene(PE) films were photocrosslinked by continuous UV irradiation. Benzophenone addition as low as 1wt% into the PE film increased the gel fraction up to 96%. The photocrosslinking was attributed to the recombination of PE radicals generated upon UV irradiation, which was enhanced by the hydrogen abstraction of the added benzophenone. Also the crossliked PE showed higher thermal stability and decreased crystallinity with increasing UV energy as shown by TGA, XRD and DSC analysis. It was also possible to fix 5.4% octadecane into PE by the photocrosslinking. The crosslinked PE film containing octadecane showed lower tensile strength and modulus coupled with higher extension compared to that without octadecane, which can be used as a new plasticizing method for the crosslinked PE film.

• 대한화학회지
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• 제46권2호
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• pp.139-144
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• 2002

니켈 착물을 촉매로 사용한 1,1´-Bis(dimethylsilyl)ferrocene [1]과 carbonyl 화합물 -benzaldehyde, 4-cyanobenzaldehyde, trimethylacetaldehyde, acetophenone과 benzophenone-은 3-oxa-2,5-disilacyclo-1,1′-ferrocene을 생성하였다. 이와 대비되게 동일한 반응조건에서 화합물 [1]과 isobutyraldehyde의 반응에는 1,1′-bis(dimethylsilyl)ferrocene의 Si-H 결합에 2개의 aldehyde ligand가 이중 삽입된 생성물이 형성되었다.