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http://dx.doi.org/10.5012/jkcs.2002.46.2.139

Nickel Catalyzed Silylation Reaction of Carbonyl Compounds with 1,1'-Bis(dimethylsilyl)ferrocene  

Gong, Yeong-Geon (Department of Chemistry, Kyonggi University)
Lee, Jeong-Hyeon (Department of Chemistry, Kyonggi University)
Publication Information
Journal of the Korean Chemical Society / v.46, no.2, 2002 , pp. 139-144 More about this Journal
Abstract
The nickel-catalyzed reation of 1,1'-bis(dimethysilyl)ferrocene[1] with carbonyls such as benzaldehyde, 4-cyaonbezaldehyde, trimethylacetaldehyde, acethon, and benzophenone afforded 3-oxa-2,5-disilacyclo-1,1'-ferrocene. In contrast, the reation of [1] with isobutyraldehyde under the same reation condition yielded the diinsertion products formed via the insertion of two aldehyde ligands into the Si-H bond of 1,1'-bis(dimethy)ferrocene.
Keywords
1,1'-Bis(dimethylsilyl)ferrocene; silylation; Ni catalyst;
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