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Wall Contamination of Teflon Bags Used as a Photochemical Reaction Chamber of Ambient Air (실제 대기의 광화학 반응 챔버로 사용되는 테플론 백의 오염도 평가)

  • Lee, Seung-Bok;Bae, Gwi-Nam;Lee, Young-Mee;Moon, Kil-Choo
    • Particle and aerosol research
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    • v.9 no.3
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    • pp.149-161
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    • 2013
  • Experiments on photochemical reactions of purified air alone in an indoor smog chamber were carried out after flushing Teflon bags with purified air for many hours in order to check the level of contamination on the chamber wall. Ozone concentrations were linearly increased from <4 ppb up to about 8 ppb with irradiation time for four hours. Outgassing of NOx from the chamber wall was found to be less than 1 ppb. New ultrafine particles were formed and grown up to about 70 nm during the photochemical reactions, and then total number and mass concentrations of particles were increased from <10 particles/$cm^3$ up to about 4,000 particles/$cm^3$ and $1.3{\mu}g/m^3$, respectively. The wall conditions of these Teflon bags flushed with purified air might not severly affect the chamber experimental results for photochemical reactions of polluted urban ambient air. The difference of gaseous species between two chambers was 2.4 ppb of ozone at most, indicating that the wall cleaning performance of two chambers was nearly similar.

Experimental and computational analysis of behavior of three-way catalytic converter under axial and radial flow conditions

  • Taibani, Arif Zakaria;Kalamkar, Vilas
    • International Journal of Fluid Machinery and Systems
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    • v.5 no.3
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    • pp.134-142
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    • 2012
  • The competition to deliver ultra-low emitting vehicles at a reasonable cost is driving the automotive industry to invest significant manpower and test laboratory resources in the design optimization of increasingly complex exhaust after-treatment systems. Optimization can no longer be based on traditional approaches, which are intensive in hardware use and laboratory testing. The CFD is in high demand for the analysis and design in order to reduce developing cost and time consuming in experiments. This paper describes the development of a comprehensive practical model based on experiments for simulating the performance of automotive three-way catalytic converters, which are employed to reduce engine exhaust emissions. An experiment is conducted to measure species concentrations before and after catalytic converter for different loads on engine. The model simulates the emission system behavior by using an exhaust system heat conservation and catalyst chemical kinetic sub-model. CFD simulation is used to study the performance of automotive catalytic converter. The substrate is modeled as a porous media in FLUENT and the standard k-e model is used for turbulence. The flow pattern is changed from axial to radial by changing the substrate model inside the catalytic converter and the flow distribution and the conversion efficiency of CO, HC and NOx are achieved first, and the predictions are in good agreement with the experimental measurements. It is found that the conversion from axial to radial flow makes the catalytic converter more efficient. These studies help to understand better the performance of the catalytic converter in order to optimize the converter design.

Feasibility Study of Microturbine CHP and Greenhouse $CO_2$ Enrichment System as Small Scale LFG Energy Project (소규모 매립가스 자원화를 위한 마이크로터빈 열병합발전 및 유리온실 $CO_2$ 농도 증가 시스템의 타당성 연구)

  • Park, Jung-Keuk;Hur, Kwang-Beom;Rhim, Sang-Gyu;Lee, In-Hwa
    • New & Renewable Energy
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    • v.5 no.2
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    • pp.15-24
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    • 2009
  • As new small scale LFG (landfill gas) energy project model which can improve economic feasibility limited due to the economy of scale, LFG-Microturbine combined heat and power system with $CO_2$ fertilization into greenhouses was proposed and investigated including basic design process prior to the system installation at Gwang-ju metro sanitary landfill. The system features $CH_4$ enrichment for stable microturbine operation, reduction of compressor power consumption and low CO emission, and $CO_2$ supplement into greenhouse for enhancement plant growth. From many other researches, high $CO_2$ concentration was found to enhance $CO_2$ assimilation (also known as photosynthesis reaction) which converts $CO_2$ and $H_2O$ to sugar using light energy. For small scale landfills which produce LFG under $3\;m^3$/min, among currently available prime movers, microturbine is the most suitable power generation system and its low electric efficiency can be improved with heat recovery. Besides, since its exhaust gas contains very low level of harmful contaminants to plant growth such as NOx, CO and SOx, microturbine exhaust gas is a suitable and economically advantageous $CO_2$ source for $CO_2$ fertilization in greenhouse. The LFG-Microturbine combined heat and power generation system with $CO_2$ fertilization into greenhouse gas to enhance plant growth is technologically and economically feasible and improves economical feasibility compared to other small scale LFG energy project model.

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Development of an Environmental Friendly Hybrid Power System and its Application to Agricultural Machines (친환경 하이브리드 동력 시스템 개발 및 농기계 응용)

  • Kim, Sangcheol;Hong, Youngki;Kim, Gookhwan
    • Journal of Institute of Control, Robotics and Systems
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    • v.21 no.5
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    • pp.447-452
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    • 2015
  • A hybrid power system was developed for agricultural machines with a 20kW output capacity, and it was attached to a multi-purpose cultivator to improve the performance of the cultivator. The hybrid system combined heterogeneous sources: an internal-combustion engine and an electric power motor. In addition, a power splitter was developed to simplify the power transmission structure. The cultivator using a hybrid system was designed to have increased fuel efficiency and output power and reduced exhaust gas emissions, while maintaining the functions of existing cultivators. The fuel consumption for driving the cultivator in the hybrid engine vehicle (HEV) mode was 341g/kWh, which was 36% less than the consumption in the engine (ENG) mode for the same load. The maximum power take off output of the hybrid power system was 12.7kW, which was 38% more than the output of the internal-combustion engine. In the HEV mode, harmful exhaust gas emissions were reduced; i.e., CO emissions were reduced by 36~41% and NOx emissions were reduced by 27~51% compared to the corresponding emissions in the ENG mode. The hybrid power system improved the fuel efficiency and reduced exhaust gas emissions in agricultural machinery. The hybrid system's lower exhaust gas emissions have considerable advantages in closed work environments such as crop production facilities. Therefore, agricultural machinery with less exhaust gas emissions should be commercialized.

Effect of Vanadium Surface Density of SCR Catalyst on Reaction Activity and SO2 Durability (상용 SCR 촉매의 바나듐 표면밀도가 반응활성 및 SO2 내구성에 미치는 영향연구)

  • Won, Jong Min;Park, Kwang Hee;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.28 no.2
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    • pp.158-164
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    • 2017
  • In this study, the reaction activity and XRD, BET, and Raman analysis were performed to verify $NH_3$-SCR reaction characteristics of various commercial SCR catalysts. It can be seen that the reaction rate of each commercial SCR catalyst increased linearly with increasing the vanadium content (1.3-5.4 wt%). In addition, through the above analysis, it was possible to confirm that the addition of WOx in the catalyst increased the Turn over frequency (TOF) within the range where the VOx surface density was more than 8.1 and the crystalloid VOx was not formed through the surface structure analysis. $SO_2$ durability tended to decrease with increasing the vanadium content, and the durability increased the most when W and Si were added.

Characteristics of Entrainment Flow Rate in a Coanda Nozzle with or without Coaxial Contractor (코안다 노즐에서 중심 축소관 유무에 따른 유입량 특성)

  • Ha, Ji Soo;Shim, Sung Hoon
    • Journal of the Korean Institute of Gas
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    • v.18 no.2
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    • pp.21-27
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    • 2014
  • A MILD(Moderate and Intense Low oxygen Dilution) combustion, which is effective in the reduction of NOx, is considerably affected by the recirculation flow rate of hot exhaust gas to the combustion furnace. The present study used a coanda nozzle for the exhaust gas recirculation in a MILD combustor. A numerical analysis was accomplished to elucidate the effect of exhaust gas entrainment toward the furnace with or without a coaxial contractor. The result of the present CFD analysis showed that the entrainment mass flow rate without a coaxial contractor had 18% larger than that with a coaxial contractor when the mixed gas outlet pressure was ambient pressure. On the other hand, if the outlet pressure increased, the mass flow rate with a contractor was larger than that without a contractor. It could be analysed by the entrainment driving force composed with the nozzle throat pressure, inlet and outlet pressures and flow cross sectional area.

GE 7FA+e DLN-2.6 Gas Turbine Combustor : Part Ⅰ Operating Condition Optimization (GE 7FA+e DLN-2.6 가스터빈 연소기 연구 : Part Ⅰ 운전조건 최적화)

  • Oh, Jeong-Seog;Kim, Min-Ki;Heo, Pil-Won;Lee, Jang-Soo;Yoon, Young-Bin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.12 no.5
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    • pp.43-50
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    • 2008
  • DLN-2.6 combustion tuning was carried out for the maintenance of GE 7FA+e gas turbine at Seo-Incheon combined cycle power plant. DLN-2.6 combustion system has the higher level of yellow plume and combustion vibration problem in the initial operating mode than that of the base mode($100{\sim}160MW$). The objectives of this study are to investigate the causes of yellow plume and combustion vibration problems at the starting mode and to suggest the best operating condition for the reliable working of the real combustors. By the analysis of tuning data, we could conclude that a yellow plume is caused by the rich mixture(${\phi}{\sim}1$) in a PM 1 nozzle at mode 3($20{\sim}30MW$). In addition, the combustion vibration($120{\sim}140Hz$) might be related to the cold flow characteristics of PM 3 nozzles at mode 6B($40{\sim}45MW$).

Performance and Emission Characteristics of a Diesel Engine Operated with Wood Pyrolysis Oil (목질 열분해유를 사용하는 디젤엔진의 성능 및 배기특성에 관한 연구)

  • Lee, Seok-Hwan;Park, Jun-Hyuk;Choi, Young;Woo, Se-Jong;Kang, Kern-Yong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.5
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    • pp.102-112
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    • 2012
  • The vast stores of biomass available in the worldwide have the potential to displace significant amounts of fuels that are currently derived from petroleum sources. Fast pyrolysis of biomass is one of possible paths by which we can convert biomass to higher value products. The wood pyrolysis oil (WPO), also known as the bio crude oil (BCO), have been regarded as an alternative fuel for petroleum fuels to be used in diesel engine. However, the use of BCO in a diesel engine requires modifications due to low energy density, high water contents, low acidity, and high viscosity of the BCO. One of the easiest way to adopt BCO to diesel engine without modifications is emulsification of BCO with diesel and bio diesel. In this study, a diesel engine operated with diesel, bio diesel (BD), BCO/diesel, BCO/bio diesel emulsions was experimentally investigated. Performance and gaseous & particle emission characteristics of a diesel engine fuelled by BCO emulsions were examined. Results showed that stable engine operation was possible with emulsions and engine output power was comparable to diesel and bio diesel operation. However, in case of BCO/diesel emulsion operation, THC & CO emissions were increased due to the increased ignition delay and poor spray atomization and NOx & Soot were decreased due to the water and oxygen in the fuel. Long term validation of adopting BCO in diesel engine is still needed because the oil is acid, with consequent problems of corrosion and clogging especially in the injection system.

Establishing HP/LP-EGR System and Founding Operating Strategy of Low Temperature Combustion Engine to Improve Fuel Consumption (연료소비율 개선을 위한 고압/저압 배기재순환 시스템 구축 및 저온연소 엔진의 운전전략 수립)

  • Shin, Seunghyup;Han, Youngdeok;Shim, Euijoon;Kim, Duksang
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.3
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    • pp.81-89
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    • 2014
  • This study researched on the effect of HP/LP-EGR system to improve fuel consumption of Low Temperature Combustion Engine. Firstly, low temperature combustion engine with HP/LP-EGR system was established using 6.0L wastegate turbocharger HDDI engine. And suppliable EGR rate of the engine was proven to be enough to realize stable low temperature combustion. Then, optimum operating strategy was founded to develop fuel consumption of the engine. Control parameters were HP/LP-EGR valve and IPCV(Intake Pressure Control Valve) duty. Experiments method was that characteristics of the engine were measured and analyzed according to HP/LP-EGR strategies while EGR rate was fixed. Operating range for the strategy were divided into three parts, low load for low temperature combustion, high load for conventional diesel combustion, and transient condition. Finally, with the above strategy of this study, BSFC of the engine was improved about 2% compared to the base engine, and emission level, NOx and PM, met Tier4Final emission regulation.

The Experimental Study on Characteristics of Valve System using Hole Type Valve Lift Sensor (밸브 거동 특성 파악을 위한 hole 센서의 적용에 관한 실험적 연구)

  • Moon, Gun-Feel;Lee, Yong-Gyu;Lee, Seong-Jin;Choi, Kyo-Nam;Jeong, Dong-Soo;Park, Sung-Young
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.3
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    • pp.80-86
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    • 2008
  • Recently, controlled auto ignition(CAI) in gasoline engines are drawing more attentions due to its extremely low level of NOx emissions and potentials in lowering the fuel consumption rate. The one of the key techniques for realizing CAI combustion in engines is the control of valve system. Since the valve linkage system with higher complexity, or even earn-less valve systems, such as electro-hydraulic and electro-magnetic system, are adopted in CAI engines, it is not easy to estimate the valve lift profile from earn profiles. Therefore new measurement techniques for valve lift in CAI engines have been tried and tested. In this paper, hole type valve lift sensor was developed and tested to check the applicability in CAI engines. The valve lifts could be obtained from the sensor signal, which depends on the distance from the sensor to magnet attached to valve. Various engine speeds, ranging from 2,000 to 6,000 rpm, and valve lifts, maximum up to 9.7 mm, were tested. It was found that the sensor output for valve lift had accuracy of 98% in comparison with the basic specifications of valve lift through improvements of sensor driving circuit.