• Title/Summary/Keyword: Baylis-Hillman adducts

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Baylis-Hillman Reaction and Chemical Transformations of Baylis-Hillman Adducts

  • Lee, Ka-Young;Gowrisankar, Saravanan;Kim, Jae-Nyoung
    • Bulletin of the Korean Chemical Society
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    • v.26 no.10
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    • pp.1481-1490
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    • 2005

  • Carbon-carbon single bond-forming reaction is the most useful and fundamental reaction in organic synthesis. Most of the basic carbon-carbon single bond-forming reactions, thus, developed in the past. In these respects, conceptually new C-C bond formation reaction can be highlighted. The Baylis-Hillman reaction was found at the early 1970’s. However, extensive studies on this highly potential reaction were started only before 15 years. This review has been written to shed more lights to the importance of Baylis-Hillman reaction. We have focused mainly on the reaction mechanism, conceptually related reactions, and chemical transformations of the Baylis-Hillman adducts.

  • https://doi.org/10.5012/bkcs.2005.26.10.1481 인용 PDF KSCI

An Efficient Synthesis of Phospha-Morita-Baylis-Hillman Adducts via Michaelis-Arbuzov Reaction of the DABCO Salt of Morita-Baylis-Hillman Bromide

  • Kim, Sung Hwan;Kim, Se Hee;Lee, Hyun Seung;Kim, Jae Nyoung
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.133-138
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    • 2013

  • An efficient synthesis of phospha-Morita-Baylis-Hillman adducts was carried out in good yields via the Michaelis-Arbuzov reaction of the DABCO salts of MBH bromides. Instead of a DABCO salt, a phosphonium salt could be effectively used for some substrates which showed some problems in the presence of DABCO.

  • https://doi.org/10.5012/bkcs.2013.34.1.133 인용 PDF KSCI