• 제목/요약/키워드: Bath Composition

검색결과 154건 처리시간 0.027초

Float 공법을 고려한 Plasma Display Panel용 기판유리 용융체의 특성 (Melt Properties of Plasma Display Panel Substrate Glasses Based on Float Process)

  • 김기동;정우만;정현수;권성구;최세영
    • 한국세라믹학회지
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    • 제43권7호
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    • pp.433-438
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    • 2006
  • In order to examine the working condition of melts in tin bath of float process it was investigated Sn diffusion behavior and solidification rate of melts for alkali-alkaline earth-silica PDP substrate glasses such as commercial CaO rich CS-77 glass, commercial $Al_2O_3$ rich PD-200 glass and self developed $SiO_2$ rich T-series (T-2, T-4, T-6) glasses. In the case of Sn depth and concentration created in glass surface by ion exchange between Sn and alkali, T-series showed lower value than CS-77, especially T-2 is more excellent than PD-200. The solidification rate of melts expressed by cooling time between $log{\eta}=4\;and\;7.6dPa{\cdot}s$ was low for T-series comparing with CS-77 and PD-200. Therefore, it was concluded that T-series is desirable considering forming condition in the tin bath of the float process.

Morphology of Membranes Formed from Polysulfone/Polyethersulfone/N-methyl-2-pyrrolidone/Water System by Immersion Precipitation

  • Baik, Ki-Jun;Kim, Je-Young;Lee, Jae-Sung;Kim, Sung-Chul;Lee, Hwan-Kwang
    • Macromolecular Research
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    • 제9권5호
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    • pp.285-291
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    • 2001
  • The polysulfone(PSf)/polyethersulfone(PES) blend membranes were prepared by an immersion precipitation method. N-methyl-2-pyrrolidone(NMP) was used as a solvent and water as a nonsolvent. The composition of the coagulation bath and the dope polymer concentration as well as the blend ratio of two polymers were varied. The membrane morphologies were interpreted on the basis of the phase diagram of the PSf/PES/NMP/water system. As the solvent content in the coagulation bath increased in the single polymer system, the number of macrovoids decreased and the morphology was changed from finger-like to cellular structure. In the given bath condition phase separation occurs earlier for the solutions of PSf/PES blend than for those of single polymer. A horizontally layered structure and horizontal protuberances inside the macrovoid were observed for the membranes formed from PSf/PES blend solutions. This peculiar structure formation can be interpreted by a PSf-rich/PES-rich phase separation followed by a polymer-rich/polymer-lean phase separation during the exchange of solvent and nonsolvent.

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착화제와 pH가 무전해 Ni-Co-P 도금 피막의 석출거동에 미치는 영향 (Effects of Complex Agents and pH on the Deposition Behavior of Electroless Ni-Co-P Film)

  • 최벽근;양승기;신지웅;황운석
    • Corrosion Science and Technology
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    • 제13권3호
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    • pp.107-111
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    • 2014
  • Electroless plated Ni-Co-P films have been used to suppress the electromagnetic waves from magnetic recording media, and the suppression is known to be achieved with films made with optimized plating composition and plating condition. Effects of complexing agents on the deposition rate and bath stability of Ni-Co-P film were studied using sodium citrate, sodium tartrate and multi-complex agents containing both of them. Deposition of electroless Ni-Co-P platings was dependent upon the complexing agents. Deposition rate was twice when using sodium tartrate compared to that using sodium citrate. And it was slightly slower with multi-complex agents than with sodium tartrate, bath stability being declined in the former. Deposition rate increased with increasing pH until pH 11. Excellent bath stability and good deposition rate were obtained using multi-complex agent as sodium citrate 0.10 mol/L and sodium tartrate 0.15 mol/L in the electroless Ni-Co-P plating films.

Effects of phosphating bath compositions on the formation and structure of zinc phosphate conversion coatings on magnesium alloy AZ31

  • Phuong, Nguyen Van;Lee, Kyuhwan;Chang, Doyon;Moon, Sungmo
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2012년도 춘계학술발표회 논문집
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    • pp.322-323
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    • 2012
  • This study discussed the formation of phosphate conversion coatings on AZ31 Mg alloy (AZ31) from the zinc phosphating bath with various concentrations of sodium fluoride (NaF). The effects of NaF on the formation, structure, composition and electrochemical behavior of the phosphate coatings were examined using scanning electron microscopy (SEM), X-ray diffraction (XRD) weight balances, open circuit potential (OCP) transients, potentiodynamic polarization curves and immersion test. The coatings were composed of two layers: an outer $Zn_2(PO_4)_3.4H_2O$ (hopeite) crystal layer and an inner amorphous of $MgZn_2(PO_4)_2$. NaF concentration is emphasized to be highly effective in the formation of the hopeite crystal and etching and coating rates. Potentiodynamic polarization and immersion test showed that the coatings formed in the zinc phosphating bath with addition of NaF have much higher corrosion resistance than bare AZ31.

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CBD법에 의한 ZnS 박막 성장의 하이드라진 효과 (Effect of Hydrazine as a Complex Agent on the Growth of ZnS Thin Film by Using Chemical Bath Deposition (CBD))

  • 이차란;김제하
    • 한국전기전자재료학회논문지
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    • 제31권3호
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    • pp.177-181
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    • 2018
  • We prepared ZnS thin films via chemical bath deposition (CBD) in an aqueous solution of ammonia ($NH_3$) and hydrazine ($N_2H_4$). The composition ratio of hydrazine used was 0%, 17%, 22%, 29%, or 50%. We investigated the effects of hydrazine and ammonia on the growth, and the structural and optical properties of ZnS in terms of surface uniformity, voids, and grain size. We found that during the growth of ZnS films, hydrazine was very effective for improving the surface morphology and layer uniformity with fast layer formation, while it had no effect on the bandgap energy, $E_g$.

Electroless Copper Plating For Metallization of Electronic Devices

  • Lee Jae-Ho
    • 마이크로전자및패키징학회지
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    • 제11권4호
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    • pp.75-80
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    • 2004
  • In copper metallization, resistivity of copper seed layer is very important. Conventionally MOCVD has been used for this purpose however electroless copper plating is simple process and the resistivity of copper deposit is less than that of copper prepared by MOCVD. In this study electroless copper plating was conducted on different substrate to find optimum conditions of electroless copper plating for electronic applications. To find optimum conditions, the effects and selectivity of activation method on several substrates were investigated. The effects of copper bath composition on morphology were investigated. The effects of pH and stabilizer on deposition rate were also investigated. The optimum pH of the bath was 12 with addition of stabilizer. The resistivity of copper was decreased with addition of stabilizer and alter heat treatment.

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Optical and Optoelectric Properties of PbCdS Ternary Thin Films Deposited by CBD

  • Mohammed, Modaffer. A.;Mousa, Ali M.;Ponpon, J.P.
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제9권2호
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    • pp.117-123
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    • 2009
  • $Pb_{x}Cd_{1-x}S$ films are prepared in the composition range of 0.05${\leq}x{\leq}$0.25, using a chemical bath deposition growth technique under optimum conditions amide at realizing good photo response. The x-ray diffraction results show that the films are of PbS-CdS composite with individual CdS and PbS planes. The films exhibit two direct band gaps, 2.4 eV attributed to CdS, while the other varies continuously from 2.4 eV to 1.3 eV. The films surface morphology is smooth with crystallite, whose grain size increases with increasing mole fraction (x). The decrease in band gap with increase in lead concentration suggests inter-metallic compound of PbS (Eg=0.41 eV) with CdS (Eg=2.4 eV)

맞벌이가족 라이프스타일 유형에 따른 공간구성 만족도에 관한 연구 (A Study on the Satisfaction of Spatial Composition by Double-income Households Considering their Life Style)

  • 이세나;이현수
    • 한국주거학회:학술대회논문집
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    • 한국주거학회 2006년도 추계학술발표대회 논문집
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    • pp.92-96
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    • 2006
  • With the change of family type and diversify of life style, residents need various unit plan in Quality. A rate of economically productive women has increased, and generally double-income households will continuously increase in the future. So a research is requested to consider the double-income households's satisfaction for a unit plan based on their life characteristics. The purpose of this study is to find out double-income households's lifestyles, and to search and analyze users' needs for spatial composition according to their lifestyles, and then, embody spatial composition of Apartment Unit plans. The findings are as follows. (1) Housing lifestyles of users living in apartment are categorized into 5 types: seeking the way to make housework easy and comfortable, making the best use spatial composition, pursing the universalism, housework oriented, pursing the leisure. (2) The type of seeking the way to make housework easy and comfortable requests facility with home appliances and a shower bath, the type of making the best use spatial composition requests storage space and trial about new plan, the type of pursing the universalism is concerned about the protection of environment and a memorial service, the type of housework oriented wants a talk with their family and discuss some problem, and the type of pursing the leisure requests division of household with their family and likes traveling and sports.

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최근 공동주택 설계경기에 나타난 단위세대 계획개념 및 공간 계획 특성 - 2007년도 이후의 수도권 설계경기 당선작을 중심으로 - (A Study on the Planning Concept and Spatial Characteristics of the Multi-housing Units in Design Competition - Focused on the prize-wining works of design competition in Seoul and Kyunggi Area since 2007 -)

  • 김미경;문영아
    • 한국실내디자인학회논문집
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    • 제18권5호
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    • pp.137-146
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    • 2009
  • The purpose of this study is to analyze the planning concept and spatial characteristics of the multi-housing units in prize-wining works of design competition since 2007. Literature review and content analysis were used for this study and 199units over $59m^2$ were analyzed to review the planning concept, spatial composition and layout. The results of this study were as follows; 1)The planning concept of these units were divided into three aspects; that is, eco-friendly, rational and sustainable unit plan by means of functional, environmental-friendly and future-oriented aspects. 2)Most unit plans had 3LDK+2bath and 4Bay types including family room as a public space. This results shows that family-room and bathroom has recently become more important than number of rooms in multi-housing units planning. 2)In terms of the spatial composition of LDK and Master Bed room, LDK area become large, open type and master-zone were showed 'bed room+dress and powder room+bath' type. 3)The entrance has a intermediated space as a balcony or a former space and the privacy of LDK space was protected from the entrance. This study has a significant moaning on grasping current trend in Korean multi-housing and to provide Information for future direction on housing-unit design.

구리 도금층의 기계적 성질에 미치는 집합조직의 융합연구 (Convergent Study of Texture on the Mechanical Properties of Electrodeposits)

  • 강수영
    • 한국융합학회논문지
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    • 제7권6호
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    • pp.193-198
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    • 2016
  • 전기 도금한 도금 층의 집합조직은 전해조건에 의해 변화하는 것으로 알려져 있다. 도금층의 집합조직은 도금층의 미세조직과 표면 형상과 관계가 있으며 도금층의 기계적인 성질에 영향을 미친다. 그러므로 도금층의 집합조직의 변화양상의 이해는 매우 중요하다. 또한 전기도금 층은 열처리 됐을 때 재결정이 일어난다. 그 재결정 집합조직은 도금 층의 초기 성장 집합조직과 다르게 된다. 전기 도금한 도금 층의 그 미세조직, 표면 형상, 집합조직과 기계적인 성질은 용액조성, 과전압, pH, 전류밀도와 용액온도 등의 전해조건에 의해 변화한다. (111)과 (110)집합조직을 갖는 구리도금 층을 융합연구를 통해 황산 욕으로부터 얻을 수 있었다. 이 연구에서는 (110) 또는 (111)집합조직을 갖는 구리도금 층을 황산 욕에서 얻고, 그 (110) 또는 (111)집합조직으로의 변화와 기계적 성질을 설명할 수 있는 모델을 제시하였다.