• Title/Summary/Keyword: Batch technique

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Non-isothermal Pyrolysis Characteristics of the Mixture of Waste Automobile Lubricating Oil and Polystyrene (폐윤활유와 Polystyrene 혼합물의 비등온 열분해반응 특성)

  • Kim, Seung-Soo;Chun, Byung-Hee;Park, Chan Jin;Kim, Sung Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.6
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    • pp.1063-1072
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    • 2000
  • Kinetic tests on pyrolysis of the mixture of waste automobile lubricating oil and polystyrene were carried out with thermogravimetric technique at the heating rates of 0.5, 1.0, $2.0^{\circ}C/min$ in a stirred batch reactor. The activation energy and the reaction order were determined at conversions of 1 to 100% using differential method. The mixture of waste automobile lubricating oil and polystyrene was pyrolyzed at lower temperature rather than waste automobile lubricating oil and polystyrene. respectively. Also, the thermal decomposition took place in two broad reaction steps. The pyrolyzed oil of mixture represented high selectivity of styrene monomer and dimer like that of polystyrene pyrolyzed products.

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Adsorption properties of activated carbon prepared from pre-carbonized petroleum coke in the removal of organic pollutants from aqueous solution

  • Ahmed, S.A. Sayed;El-Enin, Reham M.M. Abo;El-Nabarawy, Th.
    • Carbon letters
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    • v.12 no.3
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    • pp.152-161
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    • 2011
  • Activated carbon was prepared from pre-carbonized petroleum coke. Textural properties were determined from studies of the adsorption of nitrogen at 77 K and the surface chemistry was obtained using the Fourier-transform infrared spectrometer technique and the Boehm titration process. The adsorption of three aromatic compounds, namely phenol (P), p-nitrophenol (PNP) and benzoic acid (BA) onto APC in aqueous solution was studied in a batch system with respect to contact time, pH, initial concentration of solutes and temperature. Active carbon APC obtained was found to possess a high surface area and a predominantly microporous structure; it also had an acidic surface character. The experimental data fitted the pseudo-second-order kinetic model well; also, the intraparticle diffusion was the only controlling process in determining the adsorption of the three pollutants investigated. The adsorption data fit well with the Langmuir and Freundlich models. The uptake of the three pollutants was found to be strongly dependent on the pH value and the temperature of the solution. Most of the experiments were conducted at pH 7; the $pH_{(PZC)}$ of the active carbon under study was 5.0; the surface of the active carbon was negatively charged. The thermodynamic parameters evaluated for APC revealed that the adsorption of P was spontaneous and exothermic in nature, while PNP and BA showed no-spontaneity of the adsorption process and that process was endothermic in nature.

Equilibrium, kinetic and thermodynamic studies of the adsorption of acidic dye onto bagasse fly ash

  • Shouman, Mona A.;Fathy, Nady A.;El-Khouly, Sahar M.;Attia, Amina A.
    • Carbon letters
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    • v.12 no.3
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    • pp.143-151
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    • 2011
  • Bagasse fly ash (BFA) is one of the important wastes generated in the sugar industry; it has been studied as a prospective low-cost adsorbent in the removal of congo red (CR) from aqueous solutions. Chemical treatment with $H_2O_2$ was applied in order to modify the adsorbability of the raw BFA. Batch studies were performed to evaluate the influence of various experimental parameters such as dye solution pH, contact time, adsorbent dose, and temperature. Both the adsorbents were characterized by Fourier-transform infrared spectrometer, energy-dispersive X-ray spectrophotometer and nitrogen adsorption at 77 K. Equilibrium isotherms for the adsorption of CR were analyzed by Langmuir, Freundlich and Temkin models using non-linear regression technique. Intraparticle diffusion seems to control the CR removal process. The obtained experimental data can be well described by Langmuir and also followed second order kinetic models. The calculated thermodynamic parameters indicate the feasibility of the adsorption process for the studied adsorbents. The results indicate that BFA can be efficiently used for the treatment of waste water containing dyes.

A Study on the Mixing Characteristics in Complex Turbulent Flow by a Laser Induced Fluorescence Method (레이저 형광여기법(LIF)를 이용한 복잡 난류유동장의 혼합특성에 관한 연구)

  • Kim, Kyung-Chun;Jeong, Eun-Ho
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.542-547
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    • 2001
  • A non-intrusive Planar Laser-Induced Fluorescence(PLIF) technique was applied to study the turbulent mixing process in a Rushton turbine reactor. Instantaneous and ensemble averaged concentration fields are obtained by measuring the fluorescence intensity of Rhodamine B tracer excited by a thin Nd:Yag laser sheet illuminating the whole center plane of the stirred tank. The gray level images captured by a 14-bit cooled CCD camera can be transformed to the local concentration values using a calibration matrix. The dye injection point was selected at the tank wall with three quarter height (3/4H) from the tank bottom to observe the mixing characteristics in upper bulk flow region. There exist distinct two time scales: the rapid decay of mean concentration in each region after the dye infusion reflects the large scale mixing while the followed slow decay reveals the small scale mixing. The temporal change of concentration probability functions conjectures the two sequential processes in the batch type mixing. An inactive column of water existed above the impeller disk, in which the fluid rotates with the shaft but is isolated from the mean bulk flow.

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Pseudomonas oleovorans의 유가식 배양에 의한 medium chain length Polyhydroxyalkanoates (MCL-PHA) 생산

  • Kim, Beom-Su;Im, Hui-Yeon
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.207-210
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    • 2000
  • Pseudomonas oleovorans was cultivated to produce medium chain length polyhydroxyalkanoates (MCL-PHA) fram octanoic acid and ammonium nitrate as carbon and nitrogen source, respectively, by a pH-stat fed-batch culture technique. The octanoate concentration of the culture broth was maintained below 4 g/L by feeding the mixture of octanoic acid and ammonium nitrate when the culture pH rose above high limit. The effect of the ratio of octanoic acid to ammonium nitrate (C/N ratio) in the feed on the PHA production was examined. The final cell concentrations of 62.5, 54.7, and 9.5 g/L, PHA contents of 62.9, 75.1, and 67.6% of dry cell weight, and productivities of 1.03, 0.632, and 0.161 g/L/h were obtained when the C/N ratio in the feed were 10, 20, and 100 g octanoic acid/g ammonium nitrate, respectively.

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Eye Pattern Detection Using SVD and HMM Technique from CCD Camera Face Image (CCD 카메라 얼굴 영상에서의 SVD 및 HMM 기법에 의한 눈 패턴 검출)

  • Jin, Kyung-Chan;Miche, Pierre;Park, Il-Yong;Sohn, Byung-Gi;Cho, Jin-Ho
    • Journal of Sensor Science and Technology
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    • v.8 no.1
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    • pp.63-68
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    • 1999
  • We proposed a method of eye pattern detection in the 2-D image which was obtained by CCD video camera. To detect face region and eye pattern, we proposed pattern search network and batch SVD algorithm which had the statistical equivalence of PCA. We also used HMM to improve the accuracy of detection. As a result, we acknowledged that the proposed algorithm was superior to PCA pattern detection algorithm in computational cost and accuracy of defection. Furthermore, we evaluated that the proposed algorithm was possible in real-time face pattern detection with 2 frame images per second.

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A Study on the Mixing Characteristics in a Rushton Turbine Reactor by a Laser Induced Fluorescence Method (레이저 형광여기법(LIF)를 이용한 러쉬톤 터빈 교반기의 혼합특성에 관한 연구)

  • Jeong, Eun-Ho;Kim, Gyeong-Cheon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.8
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    • pp.1145-1152
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    • 2002
  • A non-intrusive Planar Laser-Induced Fluorescence(PLIF) technique was applied to study the turbulent mixing process in a Rushton turbine reactor. Instantaneous and ensemble averaged concentration fields was obtained by measuring the fluorescence intensity of Rhodamine B tracer excited by a thin Nd:Yag laser sheet illuminating the whole center plane of the stirred tank. The gray level images captured by a 14-bit cooled CCD camera could be transformed to the local concentration values using a calibration matrix. The dye injection point was selected at the tank wall with three quarter. height (3/4H) from the tank bottom to observe the mixing characteristics in upper bulk flow region. There exist distinct two time scales: the rapid decay of mean concentration after the dye infusion reflects the large scale turbulent mixing while the fellowed slow decay reveals the small scale molecular mixing. The temporal change of concentration variance field conjectures the two sequential processes for the batch type mixing. An inactive column of water is existed above the impeller disk, in which the fluid rotates with the shaft but is isolated from the mean bulk flow.

하수슬러지의 토양개량재 적용시 유기인계 농약의 흡착능력에 관한 연구

  • 임은진;이재영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.125-130
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    • 2004
  • This study has been assessed the influence of applying sewage sludge to soil amendments on the sorption properties, and leaching potential of three commonly used organophosphorus pesticides, Diazinon, Fenitrothion, and Chlorpyrifos. A sandy soil with a low content of organic carbon was treated with sewage sludge with a ratio sandy soil : sludge ratio of 30:1. The sorption was determined with the batch equilibrium technique. The sorption isotherms could be described by Freundlich equation. The Freundlich constant, K value which measures sorption capacity, were 3.97, 9.94, 22.48 for Diazinon, Fenitrothion, Chlorpyrifos in non-amended soil. But in amended soil, K value was 12.58, 28.47, and 61.21 for Diazinon, Fenitrothion, and Chlorpyrifos. The overall effect of sewage sludge addition to soil was to increase pesticides adsorption, due to the high sorption capacity of the organic matter. The effect of sludge on tile leaching of pesticides in the soil was studied using packed soil columns. Total recoveries of pesticides in soil and leachate with leaching in soil column, were in the range of about 73~84%, was reduced with the passage of time. Diazinon moved more rapidly than Chlorpyrifos in the unamended soil due to greater sorption and lower water solubility of Chlorpyrifos. Total amounts of pesticides leached from the sewage sludge amended soils were significantly reduced when compared with unamended soils. This reduction may be mainly due to and increase in sorption in amended soils, as a consequence of the increase in the organic matter content.

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A Case Study for a Process/Layout Design of a Sikhye Production Line (식혜(食醯) 생산(生産)라인의 공정(工程)/배치(配置) 설계(設計)에 대한 사례 연구)

  • Yang, Moon-Hee
    • IE interfaces
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    • v.16 no.4
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    • pp.450-462
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    • 2003
  • In this paper, we deal with a process and layout design for producing a planned amount of Sikhye in a given limited time period under a reasonable production schedule. We represent a Sikhye production line as a vector N, the element of which denotes the number of tanks required in each process and our objective is to find an appropriate vector which minimizes the total investment cost. We suggest a systematic method for finding an appropriate N and an appropriate layout to N. In detail, first, we decide the required sequence of processes and the required operations for each process and we estimate standard operating times. Second, constructing a precedence diagram, we find a critical path in order to reduce the total production lead time for a batch of Sikhye. Third, given a limited N space, we manage to construct manually each production schedule using both the processing times of the critical operations and transfer times. Finally, we find an optimal vector N which gives a minimum investment cost and meets both the time constraint and quantity constraint. In addition, with the estimated relative size of each tank, we suggest an appropriate conceptual layout design including an expansion area for future demands, based on the span technique used in the field of architectural design.

Efficient Update Method for Cloud Storage System

  • Khill, Ki-Jeong;Lee, Sang-Min;Kim, Young-Kyun;Shin, Jaeryong;Song, Seokil
    • International Journal of Contents
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    • v.10 no.1
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    • pp.62-67
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    • 2014
  • Usually, cloud storage systems are developed based on DFS (Distributed File System) for scalability and reliability reasons. DFSs are designed to improve throughput than IO response time, and therefore, they are appropriate for batch processing jobs. Recently, cloud storage systems have been used for update intensive applications such as OLTP and so on. However, in DFSs, in-place update operations are not carefully considered. Therefore, when updates are frequent, I/O performance of DFSs are degraded significantly. DFSs with RAID techniques have been proposed to improve their performance and reliability. Their performance degradation caused by frequent update operations can be more significant. In this paper, we propose an in-place update method for DFS RAID exploiting a differential logging technique. The proposed method reduces the I/O costs, network traffic and XOR operation costs for RAID. We demonstrate the efficiency of our proposed in-place update method through various experiments.