• Title/Summary/Keyword: Batch method

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Dispersion Property of Al2O3 Nanosol Prepared by Various Dispersion Factors and Silane Modification under Non-Aqueous Solvent (비수계 용매하에서 다양한 분산인자 및 실란 표면개질에 의해 제조된 Al2O3 나노졸의 분산 특성)

  • Na, Ho Seong;Park, Min-Gyeong;Lim, Hyung Mi;Kim, Dae Sung
    • Korean Journal of Materials Research
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    • v.26 no.12
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    • pp.733-740
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    • 2016
  • $Al_2O_3$ nanosol dispersed under ethanol or N-Methyl-2-pyrrolidone(NMP) was studied and optimized with various dispersion factors and by utilizing the silane modification method. The two kinds of $Al_2O_3$ powders used were prepared by thermal decomposition method from aluminum ammonium sulfate$(AlNH_4(SO_4)_2)$ while controlling the calcination temperature. $Al_2O_3$ sol was prepared under ethanol solvent by using a batch-type bead mill. The dispersion properties of the $Al_2O_3$ sol have a close relationship to the dispersion factors such as the pH, the amount of acid additive(nitric acid, acetic acid), the milling time, and the size and combination of zirconia beads. Especially, $Al_2O_3$ sol added 4 wt% acetic acid was found to maintain the dispersion stability while its solid concentration increased to 15 wt%, this stability maintenance was the result of the electrostatic and steric repulsion of acetic acid molecules adsorbed on the surface of the $Al_2O_3$ particles. In order to observe the dispersion property of $Al_2O_3$ sol under NMP solvent, $Al_2O_3$ sol dispersed under ethanol solvent was modified and solvent-exchanged with N-Phenyl-(3-aminopropyl)trimethoxy silane(APTMS) through a binary solvent system. Characterization of the $Al_2O_3$ powder and the nanosol was observed by XRD, SEM, ICP, FT-IR, TGA, Particles size analysis, etc.

Mediated ID based signature scheme and key updating signature scheme (중재자를 이용한 ID기반 전자서명과 키 업데이팅 전자서명 기법)

  • Ju, Hak-Soo;Kim, Dae-Youb
    • The KIPS Transactions:PartC
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    • v.14C no.6
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    • pp.463-470
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    • 2007
  • Revocation is one of the main difficulties faced in implementing Public Key Infrastructures(PHs). Boneh, Ding and Tsudik first introduced a mediated cryptography for obtaining immediate revocation of RSA keys used in PKIs. Their method is based on the idea that each user's private key can be split into two random shares, one of which is given to the user and the other to an online security mediator(SEM). Thus any signature or decryption must be performed as a cooperation between a user and his/her associated SEM and revocation is achieved by instructing the mediator SEM to stop cooperating the user. Recently, Libert and Quisquater showed that the fast revocation method using a SEcurity Mediator(SEM) in a mRSA can be applied to the Boneh-Franklin identify based encryption and GDH signature schemes. In this paper we propose a mediated identity based signature(mIBS) with batch verification which apply the SEM architecture to an identity based signature. Libert's GDH siganture scheme is not forward secure even though forward security is an important and desirable feature for signature schemes. We propose an efficient key udating mediated signature scheme, mKUS based on mIBS and analyze its security and efficiency.

Investigation of the Optimum Operational Condition of Bio-Hydrogen Production from Waste Activated Sludge (폐활성 슬러지로부터 생물학적 수소 생산을 위한 최적 조건 연구)

  • Kim, Dong-Kun;Lee, Yun-Jie;Yu, Myong-Jin;Pak, Dae-Won;Kim, Mi-Sun;Sang, Byoung-In
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.4
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    • pp.362-367
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    • 2006
  • Waste activated sludge(WAS) collected from domestic wastewater treatment plant is biomass that contains large quantities of organic matter. However, relevant literature show that the bio-hydrogen yield using WAS was too low. In this study, the effect of pretreatment of WAS on hydrogen yield was investigated. Pretreatment includes acid and alkali treatments, grinding, heating, ozone and ultrasound methods. After pretreatment organic matters of WAS were solubilized and soluble chemical oxygen demand(SCOD) was increased by 14.6 times. Batch experiments were conducted to investigate the effects of pre-treatment methods and buffer solution, hydrogen partial pressure, and sodium ion on hydrogen production from WAS by using heated anaerobic mixed cultures. Experimental results showed that addition of buffer solution, efficient pre-treatment method with alkali solution, and gas sparging condition markedly increased the hydrogen yield to 0.52 mmol $H_2/g$-DS.

Improvement of Calculating Method of the Officially Assessed Individual House Price of Aged Apartment Remodeling Reflecting Feasibility Analysis (사업성분석을 반영한 공동주택 맞춤형 리모델링의 공시가격 산정방법 개선)

  • Bae, Byungyun;Kim, Kyungrai;Shin, Dongwoo;Cha, Heesung
    • Korean Journal of Construction Engineering and Management
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    • v.18 no.6
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    • pp.89-97
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    • 2017
  • The number of Aged Apartment units is expected to increase as time went on. Living standards are getting better and they want a new apartment space as the economy progresses. Therefore, it is necessary to prepare for the increasing remodeling market through the feasibility evaluation method that can be applied to the remodeling project of the apartment house. The purpose of this study is to analyze the social pricing factors affecting the Officially assessed individual House Price for the analysis model of commercial house remodeling. The collected samples were analyzed using multiple regression analysis of 350 prices included in 127 lots. Middle school level, high school level, total number of households, and floor area ratio were extracted. As a result of comparing the Officially assessed individual House Price by applying to the remodeling case, the difference between the existing Officially assessed individual House Price and the improvement Officially assessed individual House Price is different. The accessibility with the subway station is included in the land price, and there is no change in the number of stories and directions because it is customized remodeling. There was a difference in the disclosure price depending on the type of factor extraction by the evaluator in a batch application of the disclosure price factors. The research can be used as a model for future remodeling business feasibility analysis.

A Experimental Study on the Determination of Construction method of Controled Low-strength Material Accelerated Flow Ability Using Surplus Soil for Underground Power Line (지중송전관로용 급결 유동성 뒤채움재의 시공법 설정에 관한 실험적 연구)

  • Oh, Gi-Dae;Kim, Dae Hong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.3
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    • pp.84-93
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    • 2010
  • Compaction of backfill material of Underground power lines is difficult, especially under pipeline. so it could cause structural problem because of low compaction efficiency. So various methods have been taken to solve the problem and one of them is CLSM(Controled low-strength material accelerated flow ability). But In other countries, these are already in progress for a long time to research and development and recently on practical steps. But, in our country, study for only general structures, not for underground power line structure that is being constructed at night rapidly. In this study, we performed property tests and indoor & outdoor test (3 cases). The tests showed flow ability reached at the limit construction(160 mm) flowability by 9 to 15 minute after starting to mix, and construction buoyant is lowering after placing CLSM by 70 % of theoretical buoyant that is calculated by unit weight of material. In this paper, we performed indoor tests and outdoor tests to estimate mechanical properties and to suggest construction method(using batch plant, setting spacer at 1.8 m and placing at 2m) for CLSM that using surplus soil. And the test showed good results for construction quality, workability and structure safety.

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A Study on the Growth Characteristics of Commercially Developed Nitrifying Bacteria and its Application to Activated Sludge Process (상업용 질산화 박테리아의 성장특성과 활성슬러지 공정에서의 적용 방법에 따른 연구)

  • Whang, Gyu-Dae;Lee, Bong-Hee
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.4
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    • pp.595-604
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    • 2006
  • The growth characteristics of Commercially Developed Nitrifying Bacteria (CDNB) were studied in laboratoryscale. CDNB, a pure, artificially isolated bacterium, was cultivated to produce Cultivated Nitrifying Bacterium Group (CNBG). The average ammonia removal rate of CDNB was 0.0234g $NH_4^+-N/g$ MLSS/hr. CNBG was produced in the batch reactor and Specific Nitrification Rate (SNR) was determined at 0.0107g $NH_4^+-N/g$ MLSS/hr. The SNR of CNBG was lower than the SNR of CDNB because the diverse and multi-cultured microbial growth took place during cultivation. The effect of the temperatures and the mixing ratios of sewage and culture solution on the SNR of CNBG was studied. The SNR of CNBG, 0.0107g $NH_4^+-N/g$ MLSS/hr at $27^{\circ}C$, decreased to 0.0048g $NH_4^+-N/g$ MLSS/hr at $15^{\circ}C$, and temperature coefficient (${\Theta}$) was calculated to be 1.07. With the varied sewage mixing ratios, the SNR of CNBG remained unchanged. Activated sludge reactors maintaining an MLSS of 2,000mg/L at HRT of 4 h were operated under conditions in which dosage of Concentrated CNBG Solution (CCNBGS, 10,000mg MLSS/L) and application method of CNBG were varied. The reactor with 20mL of CCNBGS took shorter time to oxidize $NH_4^+-N$ reaching 1mg/L than the reactor with 5mL of CCNBGS showing that higher dosages were associated with greater mass removal of $NH_4^+-N$. However, the total removal was not great. In terms of different methods of CNBG application, reactor seeded with 20mL of CCNBGS took 3days to reach 1mg/L of effluent ammonia concentration while reactor dosed with 20% (v/v) CNBG implanted media took 2days. Both the control reactor and the reactor dosed with 20% (v/v) media only did not reach 1mg $NH_4^+-N/L$ after operating 18days. The reactor with CNBG implanted media had the highest $NH_4^+-N$ removal rate because of maintaining high concentration of Nitrifying Oxidizing Bacteria (NOM), and is regarded as an appropriate method for the activated sludge process.

A Study on Electrodeionization for Purification of Primary Coolant of a Nuclear Power Plant (원자력 발전소의 일차 냉각수 정화를 위한 전기탈이온법의 기초연구)

  • Yeon, Kyeong-Ho;Moon, Seung-Hyeon;Jeong, Cheorl-Young;Seo, One-Sun;Chong, Sung-Tai
    • Journal of Radiation Protection and Research
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    • v.24 no.2
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    • pp.73-86
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    • 1999
  • The ion-exchange method for the purification of primary coolant has been used broadly in PWR(pressurized water reactor)-type nuclear power plants due to its high decontamination efficiency, simple system, and easy operation. However, its non-selective removal of metal and non-radionuclides shortens its life, resulting in the generation of a large amount of waste ion-exchange resin. In this study, the feasibility of electrodeionization (EDI) was investigated for the purification of primary cooling water using synthetic solutions under various experimental conditions as an alternative method for the ion exchange. The results shows that as the feed flow-rate increased, the removal efficiency increased and the power consumption decreased. The removal rate was observed as a 1000 decontamination factor(DF) at a nearly constant level. For the synthetic solution of 3 ppm TDS (Total Dissolved Solid), the power consumption was 40.3 mWh/L at 2.0 L/min of feed flow rate. The higher removal rate of metal species and lower power consumption were obtained with greater resin volume per diluting compartment. However, the flow rate of the EDI process decreased with the elapsed time because of the hydrodynamic resistivity of resin itself and resin fouling by suspended solids. Thus, the ion-exchange resin was replaced by an ion-conducting spacer in order to overcome the drawback. The system equipped with the ion-conducting spacer resolved the problem of the decreasing flow rate but showed a lower efficiency in terms of the power consumption, the removal rate of metal species and current efficiency. In the repeated batch operation, it was found that the removal efficiency of metal species was stably maintained at DF 1000.

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Effects of Sm:Ba:Cu Composition Ratio on the Superconducting Properties of SmBCO Coated Conductor Prepared by using a Composition Gradient Method (SmBCO 초전도 선재 특성에 대한 Sm:Ba:Cu 조성비의 영향)

  • Kim, H.S.;Oh, S.S.;Jang, S.H.;Min, C.H.;Ha, H.S.;Ha, D.W.;Ko, R.K.;Youm, D.J.;Moon, S.H.;Chung, K.C.
    • Progress in Superconductivity
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    • v.13 no.1
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    • pp.7-11
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    • 2011
  • The effects of Sm:Ba:Cu composition ratio in SmBCO coated conductor on their superconducting properties were investigated. The SmBCO coated conductors were fabricated by reactive co-evaporation method using EDDC(Evaporation using Drum in Dual Chamber) system. In this system, we could obtain various samples with different composition ratios in a batch by the technique providing composition gradient at deposition zone. From the specimens prepared by EDDC system, we found that composition ratio is uniform parallel to the drum axis, but gradient along the circumferential direction of the drum. We installed a shield having parallelogram open area between the deposition chamber and the evaporation chamber in EDDC system, and attached a 30 cm long template, which is parallel to drum axis, onto the drum surface. In this configuration, we could obtain SmBCO coated conductors having a gradient composition along the length of template. We measured the composition ratios and surface morphologies with periodic interval by SEM and EDAX, and confirmed the profile of composition ratio. We also measured critical current using non-contact Hall probe critical current measurement system and thereby could plot composition ratio vs. critical current. The maximum critical current was obtained, and the surface morphology with the shape of roof tile was observed at the corresponding composition ratio of Sm:Ba:Cu = 1.01:1.99:4.87. It was also found that composition ratio had an effect on not only critical current but also surface morphology.

Study on the Pretreatment of Rice Hull to Enhance Enzymatic Saccharification Efficiency (효소 당화효율 증진을 위한 왕겨의 전처리 방법 연구)

  • Bark, Surn-Teh;Koo, Bon-Cheol;Moon, Youn-Ho;Cha, Young-Lok;Yoon, Young-Mi;Kim, Jung Kon;An, Gi Hong;Park, Kwang-Geun;Park, Don-Hee
    • Applied Chemistry for Engineering
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    • v.23 no.4
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    • pp.399-404
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    • 2012
  • The objective of this study was to investigate the efficient pretreatment method for bioethanol production from rice hull. Ammonia and sodium hydroxide as an alkaline solution and dilute sulfuric acid as an acidic solution were used in a batch reactor under high-temperature and high-pressure conditions. The highest enzymatic saccharification efficiency of 82.8% and ash removal rate of 94.7% were obtained in the dilute sulfuric acid treated sample after the sodium hydroxide solution treatment. The enzymatic saccharification efficiencies and ash removals of pretreated rice hull samples have very similar variation tendency. This means that the maximum obstructive factor for the enzymatic saccharification of rice hull is the ash (silicate) content in biomass. The findings suggest that the combined sodium hydroxide-dilute sulfuric acid treatment system under high-temperature and high-pressure conditions is a promising pretreatment method to enhance the enzymatic saccharification of the silica-rich biomass.

Optimization of Esterification of Jatropha Oil by Amberlyst-15 and Biodiesel Production (Amberlyst-15를 이용한 자트로파 오일의 에스테르화 반응 최적화 및 바이오디젤 생산)

  • Choi, Jong-Doo;Kim, Deog-Keun;Park, Ji-Yeon;Rhee, Young-Woo;Lee, Jin-Suk
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.194-199
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    • 2008
  • In this study, the effective method to esterify the free fatty acids in jatropha oil was examined. Compared to other plant oils, the acid value of jatropha oil was remarkably high, 11.5 mgKOH/g. So direct transesterification by a base catalyst was not suitable for the oil. After the free fatty acids were esterified with methanol, jatropha oil was transesterified. The activities of four solid acid catalysts were tested and Amberlyst-15 showed the best activity for the esterification. After constructing the experiment matrix based on RSM and analyzing the statistical data, the optimal esterification conditions were determined to be 6.79% of methanol and 17.14% of Amberlyst-15. After the pretreatment, jatropha biodiesel was produced by the transesterification using KOH in a pressurized batch reactor. Jatropha biodiesel produced could meet the major specifications of Korean biodiesel standards; 97.35% of FAME, 8.17 h of oxidation stability, 0.125% of total glycerol and $0^{\circ}C$ of CFPP.