• Title/Summary/Keyword: Batch method

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Fabrication of Iron Oxide Nanotubes by Anodization for Phosphorus Adsorption in Water (양극산화 공정을 이용한 Iron Oxide Nanotubes의 제조 및 수중 인 흡착)

  • Lee, Won-Hee;Lim, Han-Su;Kim, Jong-Oh
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.6
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    • pp.691-698
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    • 2016
  • This study was carried out to investigate the characterization of iron oxide nanotubes (INTs) by anodization method and applied adsorption isotherms and kinetic models for phosphate adsorption. SEM analysis was conducted to examine the INTs surface formation. Further XRD and XPS analysis were performed to observe the crystal structure of INTs before and after phosphate adsorption. AFM analysis was conducted to determine of Fe foil surface before and after anodization. Phosphate stock solution for adsorption experiment was prepared by $KH_2PO_4$. The batch experiment was conducted using 20 ml phosphate stock solution and $40cm^3$ of INTs in 50 ml conical tube. Adsorption isotherms were applied Langmuir and Freundlich models for adsorption equilibrium test of INTs. Pseudo first order and pseudo second order models were applied for interpretation of adsorption rate by reaction time. The determination coefficient ($R^2$) values of Langmuir and Freundlich models were 0.9157 and 0.8876 respectively.

Sludge Thickening using Electro-Flotation in Water Treatment Plant (전해부상에 의한 상수 슬러지 농축효율)

  • Lee, Jun;Han, Mooyoung;Dockko, Seok;Park, Yonghyo;Kim, Tschungil;Kim, Mikyung
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.2
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    • pp.155-160
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    • 2005
  • Gravity thickening process has been widely used in WTP sludge thickening at domestic water treatment plant. The operation method of the process is very simple, however, the process requires long detention time about 24~48 hours for sludge thickening, uses polymer, and low total solids of thickened sludge to increase sludge thickening efficiency. To solve there problems, we studied about flotation process, especially, electro-flotation (EF) process in WTP sludge thickening. Electro-flotation process is simpler than dissolved-air-flotation(DAF) process because EF needs only electrode and current to generate micro-bubbles and the operation is easy. This study was performed at two batch columns to compare interface height, total solids, effluent turbidity between an electro-flotation thickening and a gravity thickening. According to the result, an electro-flotation thickening was that interface height was decreasing, total solids had high concentration, and effluent turbidity was low in comparison with a gravity thickening. Also, it will make the high efficiency of following process, such as a dehydrating process and digestive process. because of high total solids and low moisture content in the sludge.

Study for Improvement of Laser Induced Damage of 1064 nm AR Coatings in Nanosecond Pulse

  • Jiao, Hongfei;Cheng, Xinbing;Lu, Jiangtao;Bao, Ganghua;Zhang, Jinlong;Ma, Bin;Liu, Huasong;Wang, Zhanshan
    • Journal of the Optical Society of Korea
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    • v.17 no.1
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    • pp.1-4
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    • 2013
  • For the conventionally polished fused silica substrate, an around 100 nm depth redeposition polishing layer was formed on the top of surface. Polishing compounds, densely embedded in the redeposition polishing layer were the dominant factor that limited the laser induced damage threshold (LIDT) of transmission elements in nanosecond laser systems. Chemical etching, super-precise polishing and ion beam etching were employed in different ways to eliminate these absorbers from the substrate. After that, Antireflection (AR) coatings were deposited on these substrates in the same batch and then tested by 1064 nm nano-pulse laser. It was found that among these techniques only the ion beam etching method, which can effectively remove the polishing compound and did not induce extra absorbers during the disposal process, can successfully improve the LIDT of AR coatings.

Ammonia and Hydrogen Sulfide Removal from Swine House Exhaust Air Using a Dip Injection Wet Scrubber

  • Shin, Myeongcheol;Lee, Seunghun;Wi, Jisoo;Ahn, Heekwon
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.6
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    • pp.615-622
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    • 2017
  • This study was conducted to evaluate the odor reduction efficacy of the dip injection wet scrubber (DIWS) using tap water as washing fluid. The $NH_3$ and $H_2S$ removal efficiency of 7 day batch operated DIWS was evaluated twice over a total of 14 days of experiment. The $NH_3$ removal efficiency ranged from 26 to 37%. The $H_2S$ removal efficiency was between 22 and 30%. The pH of the washing fluid maintained below 8 and the $NH_4{^+}$ concentration tended to keep constant around 350 ppm after 5 days of washing-fluid replacement. Therefore, the 5-day washing fluid replacement interval is more preferable than the 7-day interval. The $NH_4{^+}$ concentration and the electrical conductivity (EC) showed a high correlation. The EC measurement can be used as an alternative to conventional $NH_4{^+}$ concentration measurement method for real time monitoring of washing fluid condition.

Controlled Conversion of Sodium Metal From Nuclear Systems to Sodium Chloride

  • Herrmann, Steven;Zhao, Haiyan;Shi, Meng;Patterson, Michael
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.2
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    • pp.233-241
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    • 2021
  • A series of three bench-scale experiments was performed to investigate the conversion of sodium metal to sodium chloride via reactions with non-metal and metal chlorides. Specifically, batches of molten sodium metal were separately contacted with ammonium chloride and ferrous chloride to form sodium chloride in both cases along with iron in the latter case. Additional ferrous chloride was added to two of the three batches to form low melting point consolidated mixtures of sodium chloride and ferrous chloride, whereas consolidation of a sodium-chloride product was performed in a separate batch. Samples of the products were characterized via X-ray diffraction to identify attendant compounds. The reaction of sodium metal with metered ammonium chloride particulate feeds proceeded without reaction excursions and produced pure colorless sodium chloride. The reaction of sodium metal with ferrous chloride yielded occasional reaction excursions as evidenced by temperature spikes and fuming ferrous chloride, producing a dark salt-metal mixture. This investigation into a method for controlled conversion of sodium metal to sodium chloride is particularly applicable to sodium containing elevated levels of radioactivity-including bond sodium from nuclear fuels-in remote-handled inert-atmosphere environments.

An Adaptive Face Recognition System Based on a Novel Incremental Kernel Nonparametric Discriminant Analysis

  • SOULA, Arbia;SAID, Salma BEN;KSANTINI, Riadh;LACHIRI, Zied
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.13 no.4
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    • pp.2129-2147
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    • 2019
  • This paper introduces an adaptive face recognition method based on a Novel Incremental Kernel Nonparametric Discriminant Analysis (IKNDA) that is able to learn through time. More precisely, the IKNDA has the advantage of incrementally reducing data dimension, in a discriminative manner, as new samples are added asynchronously. Thus, it handles dynamic and large data in a better way. In order to perform face recognition effectively, we combine the Gabor features and the ordinal measures to extract the facial features that are coded across local parts, as visual primitives. The variegated ordinal measures are extraught from Gabor filtering responses. Then, the histogram of these primitives, across a variety of facial zones, is intermingled to procure a feature vector. This latter's dimension is slimmed down using PCA. Finally, the latter is treated as a facial vector input for the advanced IKNDA. A comparative evaluation of the IKNDA is performed for face recognition, besides, for other classification endeavors, in a decontextualized evaluation schemes. In such a scheme, we compare the IKNDA model to some relevant state-of-the-art incremental and batch discriminant models. Experimental results show that the IKNDA outperforms these discriminant models and is better tool to improve face recognition performance.

Fabrication of a solid catalyst using coal fly ash and its utilization for producing biodiesel

  • Go, Young Wook;Yeom, Sung Ho
    • Environmental Engineering Research
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    • v.24 no.2
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    • pp.324-330
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    • 2019
  • To recycle raw fly ash (RFA), a waste from thermal power plants, it was used to prepare solid catalysts which have many advantages compared with homogenous catalysts. When biodiesel was produced from soybean oil using RFA, only 1.2% of biodiesel conversion was obtained. A metal hydroxide, NaOH, KOH or $Ca(OH)_2$, was mixed with the acid-treated fly ash (ATFA), and the mixture was calcined at $700^{\circ}C$ for 3 h to prepare the solid catalyst. The solid catalyst prepared by mixing ATFA with NaOH, designated as SC-Na, showed a better performance than those prepared by mixing ATFA with KOH or $Ca(OH)_2$, respectively. The optimal mass ratio of ATFA with NaOH was 1:3, at which the proportion of $Na_2O$ increased to 60.2% in SC-Na, and 97.8% of biodiesel conversion was achieved under optimal reaction conditions (2 w% SC-Na relative to oil and 5 mL-methanol/g-oil at $50^{\circ}C$ for 4 h). Finally, a batch operation was repeatedly carried out to test the feasibility of reusing the solid catalyst, and more than 96% biodiesel conversion was stably achieved for the third round of operations. This study shows that RFA was successfully recycled to solid catalysts through a simple preparation method, and the solid catalyst was reused for the production of biodiesel with high conversion.

Removal of Methylene blue from saline solutions by adsorption and electrodialysis

  • Lafi, Ridha;Mabrouk, Walid;Hafiane, Amor
    • Membrane and Water Treatment
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    • v.10 no.2
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    • pp.139-148
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    • 2019
  • In this study, the removal of MB from saline solutions was evaluated by two methods by adsorption and electrodialysis; the adsorption of the mixture dye/salt on dried orange peel waste (OPW) was studied in batch method. In this study the biosorption of cationic dye by OPW was investigated as a function of initial solution pH, and initial salt (sodium chloride) concentration. The maximal dye uptake at $pH{\geq}3.6$ in the absence and in the presence of salt and the dye uptake diminished considerably in the presence of increasing concentrations of salt up to 8 g/L. The Redlich Peterson and Langmuir were the most suitable adsorption models for describing the biosorption equilibrium data of the dye both individually and in salt containing medium. As well, this work deals with the electrodialysis application to remove the dye. Synthetic solutions were used for the investigation of the main operational factors affecting the treatment performance; such as applied voltage, pH, initial dye concentration and ionic strength. The experimental results for adsorption and electrodialysis confirmed the importance of electrostatic interactions on the dye. The electrodialysis process with standard ion exchange membranes enabled efficient desalination of cationic dye solutions; there are two main factors in fouling: electrostatic interaction between cations of dyes and the fixed charged groups of the CEM, and affinity interactions.

Influence of Device Parameters Spread on Current Distribution of Paralleled Silicon Carbide MOSFETs

  • Ke, Junji;Zhao, Zhibin;Sun, Peng;Huang, Huazhen;Abuogo, James;Cui, Xiang
    • Journal of Power Electronics
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    • v.19 no.4
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    • pp.1054-1067
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    • 2019
  • This paper systematically investigates the influence of device parameters spread on the current distribution of paralleled silicon carbide (SiC) MOSFETs. First, a variation coefficient is introduced and used as the evaluating norm for the parameters spread. Then a sample of 30 SiC MOSFET devices from the same batch of a well-known company is selected and tested under the same conditions as those on datasheet. It is found that there is big difference among parameters spread. Furthermore, comprehensive theoretical and simulation analyses are carried out to study the sensitivity of the current imbalance to variations of the device parameters. Based on the concept of the control variable method, the influence of each device parameter on the steady-state and transient current distributions of paralleled SiC MOSFETs are verified separately by experiments. Finally, some screening suggestions of devices or chips before parallel-connection are provided in terms of different applications and different driver configurations.

Application of radiotracer technique in remediation of Zn(II) from aqueous solutions by dry cowdung powder

  • Shaikh, Sabrina Afzal;Bagla, Hemlata Kapil
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.456-461
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    • 2022
  • Heavy metal pollution is caused due to anthropogenic activities and is considered as a serious environmental problem which endangers human health and environment. The present study deals with biosorption, an eco-friendly technique for the removal of heavy metal Zn(II) from aqueous medium. Various natural materials have been explored for the uptake of metal ions, where most of them are physically or chemically enhanced. Dry cowdung powder (DCP) has been utilized as a low-cost, environmentally friendly humiresin without any pre-treatment, thus demonstrating the concept of Green Chemistry. Batch biosorption studies using 65Zn(II) tracer were performed and the impact of different experimental parameters was studied. Results revealed that at pH 6, 94 ± 2% of Zn(II) was effectively biosorbed in 5 min, at 303 K. The process was spontaneous and exothermic, following pseudo-second-order reaction. The mechanism of heavy metal biosorption employing green adsorbent was therefore elucidated in order to determine the optimal method for removing Zn(II) ions. DCP has a lot of potential in the wastewater treatment industry, as seen by its ability to meet 3A's affordability, adaptability, and acceptability criteria. As a result, DCP emerges as one of the most promising challengers for green chemistry and the zero-waste idea.