• Title/Summary/Keyword: Batch method

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A Study on the Metadata-Infrastructure of Technology Assessement Information (기술평가정보 메타데이터 구축 방안 연구)

  • Kang, nam-gyu;Lee, seok-hyoung;Yoon, hwa-mook
    • Proceedings of the Korea Contents Association Conference
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    • 2007.11a
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    • pp.327-330
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    • 2007
  • It needs various technology assessment informations to perform reasonable technology valuation. It takes large amount of time and cost to collect technology assessment informations which is same or similar. To provide technology assessment informations efficiently, we develop new system which can batch search and browse all technology assessments gathered from institute of technology valuation, research institute and so on. In this paper, we explain how to use the method such as "metadata integration" and "metadata collection", "mapping for National Science & Technology Standard Classification" as a part of the system.

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A Comparative Study for Leaching Characteristics of Specified By-Products due to Changes in Acid Neutralization Capacities (지정부산물의 산중화능력변화에 따른 용출특성 비교연구)

  • 이현경;박주양
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.206-209
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    • 2001
  • This study presents the leaching characterization of heavy metals according to changes of pH by ANC test on slag produced in electric arc furnace, bottom ash produced in coal-fired plants and their recycling products. Availability test was performed to assess the fraction of the total concentration that under worst environmental conditions could become available for leaching. TCLP, KLT(Korea Leaching Test) and KLTS(Korea Leaching Test of Soil contamination) were carried out to compare the leaching capacity and to estimate the adequacy of regulatory leaching test. Results from regulatory leaching tests could be misleading because the variable ANC of wastes can lead to very different final leachate pHs. The final pH of the regulatory test is not the ambient pH in the disposal environment, the actual solubilities of contaminants in the field may be entirely different from those predicted by these regulatory tests. Leaching behaviour of by-products was changed by recycling processes, therefore acid neutralization capacity and availability of new products, not leaching concentration by one batch regulatory test, are necessary to determine the method of recycling.

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Adsorption of Pb(II) Ions from Aqueous Solution Using Activated Carbon Prepared from Areca Catechu Shell: Kinetic, Isotherm and Thermodynamic Studies

  • Muslim, A.;Aprilia, S.;Suha, T.A.;Fitri, Z.
    • Journal of the Korean Chemical Society
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    • v.61 no.3
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    • pp.89-96
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    • 2017
  • This study proposed adsorption of Pb(II) ions from aqueous solution using activated carbon prepared from areca catechu shell (ACS AC) using Timphan Method. The effects of independent variables on adsorption kinetic and isotherm have been investigated by conducting experiments in batch mode at neutral pH. The structural characterization of adsorbent was done by FT-IR and SEM analysis. The Pb(II) adsorption was correlated very well with the pseudo second-order kinetic (PSOKM) and Langmuir isotherm models (LIM). Increasing NaOH mass for activation and adsorption temperature increased weakly all the parameters of adsorption kinetic and isotherm. The Pb(II) ions adsorption capacity of the ACS AC at 27 and $45^{\circ}C$ was 50.51 and 55.25 mg/g, respectively. Thermodynamic parameters were determined, and the results confirmed the Pb(II) ions adsorption should be endothermic and spontaneous process, and both physical and chemical adsorption should be taken place.

A Study on Escherichia Coli Disinfection by the Electrochemical Method for Small Sewerage System (소규모 오수처리를 위한 전기화학적 방법에 의한 대장균 소독에 관한 연구)

  • Park, Young-Seek;Jeong, No-Sung;Kim, Dong-Seog
    • Journal of Environmental Science International
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    • v.16 no.4
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    • pp.441-447
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    • 2007
  • This study was carried out to investigate the effect of electrochemical (EC) disinfection of artificial wastewater contaminated by Escherichia coli culture. Circulated batch type electrochemical disinfection system using three plates electrodes was used. Also, the several factors (pH, ORP, DO, temperature, current, conductivity) were measured in order to investigate the fundamental design factor in the EC disinfection system. It was demonstrated that the EC process was highly effective for wastewater disinfection. At the constant voltage, the disinfection efficiency was increased according to time. The disinfection efficiency and current increased as the increase of voltage. The variation of conductivity was a little related to the variation of CFU (colony forming units). The differences in disinfection efficiency according to the ice pack and the variation of electrodes were not occurred. The EC disinfection efficiency and current increased according to the increase of circulating flow rate.

Prediction of Strength of High-Strength Concrete by the Maturity Method (적산온도 방식을 이용한 고강도 콘크리트의 강도 예측)

  • 길배수;김태근;한장현;권영진;남재현;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.259-264
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    • 1999
  • The aim of this study of to compare the development of compressive strength of high-strength concrete with maturity and investigate the applicability the strength prediction models. An experiment was attempted on the high-strength concrete mixes using portland cement replaced by silica fume of 10% by weight of cement, the water-binder ratios of mixes being 0.30 and 0.35, the curing temperatures being 30, 20, 10, 5$^{\circ}C$. Test results of mixes are statistically analyzed to infer the correlation coefficient between the maturity and the compressive strength of high-strength concrete. The constant of strength prediction equation were determined from test results, and the equation was adopted to predict the strength of slab(W80$\times$D100$\times$H20cm). The slab was cast in the laboratory from the same batch water-binder ratio of 0.30, and cores were cut from slab in order to estimate the actual strength. These values are used to compare with predicted value. The present study allows more realistic determination of early age compressive strength of high-strength concrete and can be efficiently used to control the quality in actual construction.

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Redox Equilibrium of Antimony by Square Wave Voltammetry Method in CRT Display Glass Melts

  • Jung, Hyun-Su;Kim, Ki-Dong;Kim, Hyo-Kwang;Kim, Young-Ho
    • Journal of the Korean Ceramic Society
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    • v.44 no.1 s.296
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    • pp.1-5
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    • 2007
  • Fining and homogenization of melts during batch melting is closely related to the redox reaction of polyvalent element M (M: Sb, As etc), $M^{(x+n)+}+n/2O^{2-}{\rightarrow}M^{x+}+n/4O_2$. In this study, square wave voltammetry (SWV) measurements were performed to examine the redox behavior of an antimony ion in cathode ray tube (CRT) glass melts. According to results, well-separated two peaks are shown at low temperature while only one peak is shown at high temperature in voltammograms, which reveals that redox reaction of antimony consist of two steps: $Sb^{5+}/Sb^{3+}\;and\;Sb^{3+}/Sb^0$, depending on the temperature. Based on the peak potential shown in the voltammogram, the thermodynamic data and the redox ratio for two redox couple were determined.

Adsorption Kinetics of Cupper and Zinc Ion with Na-A Zeolite Synthesized by Coal Fly Ash (석탄 비산재로 합성한 Na-A형 제올라이트에 의한 구리와 아연 이온의 동역학적 흡착 특성)

  • Lee, Chang-Han
    • Journal of Environmental Science International
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    • v.20 no.12
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    • pp.1607-1615
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    • 2011
  • The adsorption performance of cupper and zinc ions($Cu^{2+}$ and $Zn^{2+}$) in aqueous solution was investigated by an adsorption process on reagent grade Na-A zeolite(Z-WK) and Na-A zeolite (Z-C1) prepared from coal fly ash. Z-C1 was synthesized by a fusion method with coal fly ash from a thermal power plant. Batch adsorption experiment with Z-C1 was employed to study the kinetics and equilibrium parameters such as initial metal ions concentration and adsorption time of the solution on the adsorption process. Adsorption rate of metal ions occurred rapidly and adsorption equilibrium reached at less than 120 minutes. The kinetics data of $Cu^{2+}$ and $Zn^{2+}$ ions were well fitted by a pseudo-second-order kinetics model more than a pseudo-first-order kinetics model. The equilibrium data were well fitted by a Langmuir model and this result showed $Cu^{2+}$ and $Zn^{2+}$ adsorption on Z-C1 would be occupied by a monolayer adsorption. The maximum adsorption capacity($q_{max}$) by the Langmuir model was determined as $Cu^{2+}$ 99.8 mg/g and $Zn^{2+}$ 108.3 mg/g, respectively. It appeared that the synthetic zeolite, Z-C1, has potential application as absorbents in metal ion recovery and mining wastewater.

Determination of the Intracellular Concentrations of Metabolites in Escherichia coli Collected during the Exponential and Stationary Growth Phases using Liquid Chromatography-Mass Spectrometry

  • Park, Chang-Hun;Park, Chang-Hun;Lee, Youn-Jin;Lee, Sang-Yup;Oh, Han-Bin;Lee, Jin-Won
    • Bulletin of the Korean Chemical Society
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    • v.32 no.2
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    • pp.524-530
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    • 2011
  • In the present study, we demonstrate that SRM LC-MS/MS method developed by Luo et al. (ref. 10) can be successfully applied to the quantitative analysis of intracellular metabolites in E. coli that are collected at the exponential and stationary growth phases. A focus is given on measuring the changes in the concentrations of intracellular metabolites in batch cultures, which were induced during both the dynamically changing exponential and stationary growth phases. The following intracellular metabolites are quantified in the exponential and stationary phases of E. coli growth, using the SRM mode of a triple quadrupole mass spectrometer: glucose-1-phosphate, fructose-1,6-bisphosphate, phosphoenolpyruvate, pyruvate, acetyl-coenzyme A, 6-phosphogluconate, ribulose-5-phosphate, xylulose-5-phosphate, erythrose-4-phosphate. The determined intracellular metabolite concentration profiles are shown to be in a good agreement with the growth profiles of E. coli, which clearly indicates that SRM LC-MS/MS can be successfully used for following the metabolite changes induced at different growth stages.

Removal of Uranium from Uranium Plant Wastewater Using Zero-Valent Iron in an Ultrasonic Field

  • Li, Jing;Zhang, Libo;Peng, Jinhui;Hu, Jinming;Yang, Lifeng;Ma, Aiyuan;Xia, Hongying;Guo, Wenqian;Yu, Xia
    • Nuclear Engineering and Technology
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    • v.48 no.3
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    • pp.744-750
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    • 2016
  • Uranium removal from uranium plant wastewater using zero-valent iron in an ultrasonic field was investigated. Batch experiments designed by the response surface methodology (RSM) were conducted to study the effects of pH, ultrasonic reaction time, and dosage of zero-valent iron on uranium removal efficiency. From the experimental data obtained in this work, it was found that the ultrasonic method employing zero-valent iron powder effectively removes uranium from uranium plant wastewater with a uranium concentration of $2,772.23{\mu}g/L$. The pH ranges widely from 3 to 7 in the ultrasonic field, and the prediction model obtained by the RSM has good agreement with the experimental results.

Innovative Remediation of Arsenic in Groundwater by Nano Scale Zero-Valent Iron

  • Kanel, Sushil-Raj;Kim, Ju-Yong;Park, Heechul
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.87-90
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    • 2003
  • This research examines the feasibility of using laboratory-synthesized nano scale zero-valent iron particles to remove arsenic from aqueous phase. Batch experiments were performed to determine arsenic sorption rates as a function of the nano scale zero-valent iron solution concentration. Rapid adsorption of arsenic was achieved with the nano scale zero-valent iron. Typically 1 mg $L^{-1}$ arsenic (III) was adsorbed by 5 g $L^{-1}$ nano scale zero-valent iron below the 0.01 g $L^{-1}$ concentration within 7min. The kinetics of the arsenic sorption followed pseudo-first-order reaction kinetics. Observed reaction rate constants ( $K_{obs}$) varied between 11.4 to 129.0 $h^{-1}$ with respect to different concentrations of nano scale zero-valent iron. A variety of analytical techniques were used to study the reaction products including HGAAS (hydride generator atomic adsorption spectrophotometer), SEM (scanning electron microscopy) and TEM (transmission electron microscopy). Our experimental results suggest novel method for efficient removal of arsenic Iron groundwater.r.

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