• Title/Summary/Keyword: Basic Metals

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A Study on the Production of Tile using Waste Activated Carbon and its Character Evaluation (폐 활성탄을 이용한 타일 제조 및 특성 평가에 관한 연구)

  • Park, Heung-Jai;Kim, Min-Su;Jeong, Jing-Wun;Jeong, Un;Lee, Bong-Hun;Kim, Young-Sik;Park, Yeon-Kyu;Jung, Sung-Uk
    • Journal of Environmental Health Sciences
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    • v.27 no.1
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    • pp.8-13
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    • 2001
  • The tiles were manufactured using a mixture of the TK material(a raw material in making tile) and Cu-Cr-Ag impregnated activated carbon(ASC Charcoal). The extraction character of heavy metals in making tile was evaluated and the manufacturing conditions of tile were studied. The heavy metals in the mixture-before and after the tile was production of tiles was successful and as a result of heavy metal analysis, the tile showed that the concentration of heavy metal after the production of tiles was lower than that of the before one. The concentration of eluted heavy metal by acidic and basic solutions was low and the quality of the produced tile was similar to the commercial one. The result of this study suggested that the waste ASC charcoal was used to produce good tiles and it also might reduce soil pollution.

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Content of Heavy Metals in Coal Fly Ash from the Samcheonpo and the Seocheon Power Plant (삼천포와 서천 화력발전소에서 발생하는 석탄회중의 중금속 함량에 관한 연구)

  • Yoon, Chung-Han;Oh, Keun-Chang;Kim, Yong-Woong;Shin, Bang-Sup
    • Economic and Environmental Geology
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    • v.28 no.2
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    • pp.147-154
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    • 1995
  • Coal fly ashes collected from the Samcheonpo and the Seocheon Power Plants were analyzed for major and minor components and heavy metals such as As, Cd, Co, Cr, Cu, Ga, Hg, Mo, Ni, Pb, Sb, V and Zn in order to suggest basic data to apply coal fly ash as fertilizer or soil ameliorator. The specific gravity of the samples was less than 2.0, and amounts of organic matter range from 5.0% to 12.3%. The identified minerals by XRD were mainly quartz, mullite and pyrite in anthracite coal, and mainly quartz and mullite in bituminous coal. Generally, the contents of heavy metal elements analyzed were lower less than those of soil, though higher in some samples. Element couples of some elements( e.g., As-Mo, Zn ; Mo-As, Sb, V, Zn ; Sb-Zn ) show positive correlations with each other, but the high correlations of toxic elements such as As, Pb, Cd and Hg indicate to give attention to apply coal fly ash as fertilizer or soil ameliorator.

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CMAC (Cerebellar Model Arithmetic Controller)

  • Hwang, Heon;Choi, Dong-Y.
    • 제어로봇시스템학회:학술대회논문집
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    • 1989.10a
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    • pp.675-681
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    • 1989
  • As an adaptive control function generator, the CMAC (Cerebellar Model Arithmetic or Articulated Controller) based learning control has drawn a great attention to realize a rather robust real-time manipulator control under the various uncertainties. There remain, however, inherent problems to be solved in the CMAC application to robot motion control or perception of sensory information. To apply the CMAC to the various unmodeled or modeled systems more efficiently, It is necessary to analyze the effects of the CMAC control parameters an the trained net. Although the CMAC control parameters such as size of the quantizing block, learning gain, input offset, and ranges of input variables play a key role in the learning performance and system memory requirement, these have not been fully investigated yet. These parameters should be determined, of course, considering the shape of the desired function to be trained and learning algorithms applied. In this paper, the interrelation of these parameters with learning performance is investigated under the basic learning schemes presented by authors. Since an analytic approach only seems to be very difficult and even impossible for this purpose, various simulations have been performed with prespecified functions and their results were analyzed. A general step following design guide was set up according to the various simulation results.

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Properties and Application as the Indicator of N-4-Salicyloamido-2-Amino-6-Piperidinopyrimidine 3-Oxide Fe(III) Complex (N-4-살리실로아미도-2-아미노-6-피페리디노피리미딘 3-옥사이드${\cdot}$철(III) 착체의 물성 및 지시약적 응용성)

  • Lee, Jong-Pill;Shin, Joon-Su;Kim, Kyoung-Soon;Hong, Seon-Pyo;Kim, Kyeong-Ho;Kim, Bak-Kwang
    • YAKHAK HOEJI
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    • v.40 no.6
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    • pp.670-678
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    • 1996
  • The combinations of N-4-salicyloamido-2-amino-6-piperidinopyrimidine 3-oxide (Salmi) and two transitional metals were colored. Among metals, Fe(III) made a distinct colored comp lex with Salmi. The mole ratio of Salmi and Fe(III) in the complex was 1:1. This Salmi-Fe(III) complex was recrystallized in Hexane/Acetone(=10/1, v/v) and investigated its physicochemical properties. The color of this complex was changed by pH.; deep violet pink in acids, orange in neutral, and yellow in bases. The range of color change was approximately 0.7 pH unit. Acid-base titration of various acidic or basic drugs using Salmi-Fe(III) complex as an indicator showed good accuracy and reproducibility.

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A Study on the Experimental Evaluation of the Forming Limit and Deep-Drawability of Sheet Metals (금속판재의 성형한계 및 디프드로잉 성형성의 실험적 평가에 관한 연구)

  • Rim, Jae-Kyu;Lee, Sang-Ho;Kim, Hyung-Jong
    • Journal of Industrial Technology
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    • v.19
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    • pp.67-74
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    • 1999
  • The mechanical properties including forming limit and deep-drawability of commercially-used sheet metals were experimentally estimated in this study. Uniaxial tensile test to obtain basic mechanical properties was carried out, followed by limiting dome height (LDH) test and forming limit diagram (FLD) test to quantitatively evaluate the sheet-formability. Deep drawing and reverse drawing tests were also performed to find out the critical values of the blank holding force and the gap between the die and the blank holder which enabled the deep drawing and reverse drawing of a successful cop without any wrinkle or fracture. The thickness of the cup wall along the rolling-, transeverse- and $45^{\circ}$-directions was measured and compared with one another. And the punch force-stroke curve and the critical punch force expected from the theory coincided with the experimental result very well for mild steel while not for aluminium alloy.

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Basic Study on Conditions and Analytical Methods of Biofilm Formation for the Bioassessment of Artificial Groundwater Recharge System (지하수 인공함양시스템의 생물학적 평가를 위한 생물막 형성 조건 및 형성도 분석 방법에 관한 기초연구)

  • Kong, In Chul;Lee, So Ra;Ha, Kyoochul;Ko, Kyung-Seok
    • Journal of Soil and Groundwater Environment
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    • v.20 no.4
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    • pp.22-30
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    • 2015
  • For the preliminary investigations of the bioclogging on groundwater artificial recharge system, studies for conditions and analytical methods of biofilm formation on sediments were performed. Based on the tested results, following conditions were determined for biofilm formation on batch process: optimum period for biofilm formation (30 days), the proper inoculating water (pond water), medium (minimum salt medium with 0.1% yeast extract). Procedures for the measurement of ATP and DHA were also determined. Biomass extract was used for ATP measurement, while sediment itself for DHA. Effects of metals on the biofilm formation were investigated under the determined conditions. Different sensitivities and orders were found depending on tested metals and measurement methods. In general, biomass measurement by ATP and viable cell count showed higher sensitivity than that of DHA. Following toxicity orders were also appeared for ATP and viable cell: Cu ≈ Cd > As(III).

Selective transport of Cadmium by PVC/Aliquat 336 polymer inclusion membranes (PIMs): the role of membrane composition and solution chemistry

  • Adelung, Sandra;Lohrengel, Burkhard;Nghiem, Long Duc
    • Membrane and Water Treatment
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    • v.3 no.2
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    • pp.123-131
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    • 2012
  • This study investigated the extraction and stripping performance of PIMs consisting of PVC and Aliquat 336. Extraction and stripping of three representative heavy metals - namely $Cd^{2+}$, $Cu^{2+}$, and $Zn^{2+}$ - by the synthesized membranes were evaluated as a function of sodium chloride concentration and under different stripping solutions (0.01 M $HNO_3$, Milli-Q water, 0.01 M HCl and 0.01 M NaOH), respectively. Results reported here indicate that the formation of negatively charged metal chloride complex species was responsible for the extraction of the target metal to PIMs. Experimental results and thermodynamic modeling of the speciation of chloro metal complexes further confirm that the extraction selectivity between $Cd^{2+}$, $Cu^{2+}$ and $Zn^{2+}$ can be controlled by regulating the chloride concentration of the feed solution. An acidic solution without any chloride was the most effective stripping solution, followed by Milli-Q water, and a diluted hydrochloric acid solution. On the other hand, the stripping of metals from PIMs did not occur when a basic stripping solution was used.

Thermodynamic of Phosphorus in FeO-MnO-CaO-SiO2-MgOsatd. Slag Systems (FeO-MnO-CaO-SiO2-MgOsatd. 슬래그에서의 P의 열역학적 거동)

  • Cho, Moon Kyung;Park, Kyung Ho;Min, Dong Joon
    • Korean Journal of Metals and Materials
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    • v.47 no.3
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    • pp.188-194
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    • 2009
  • Recently, new extraction technology for manganese nodule has been developed as alternative noble metallic resources. It is important to understand thermodynamic behaviors of phosphorus in low basic slag system from the viewpoint of the refining processing optimization. Thermodynamic behaviors of phosphorus in the $FeO-MnO-CaO-SiO_2-MgO_{satd.}$ slag system were investigated at 1723 K with various oxygen potential and slag composition of low basicity. The experimental results for dependence of phosphorus on oxygen potential and slag basicity indicated that the dissolution mechanism of phosphorus into slag of low basicity could be derived as follows; $[P]+5/4O_2+(O^{2-})=({PO_{3.5}}^{2-})$ Present experimental results implied that stability of phosphorus in slag would be depended on both of $O^{2-}$ (basicity) and content of $Ca^{2+}$ in molten slag. The thermodynamic effect of FeO, MnO and $Na_2O$ on low basicity on phosphate capacity was discussed.

Evaluation of the Cu Target Fabricated by the SPS Technique and its Sputtered Film (방전플라즈마 소결법에 의해 제조된 Cu 타겟과 스퍼터링 박막의 특성평가)

  • Hyun, Hye Young;Kim, Min Jung;Yoo, Jung Ho;Yang, Jun-Mo;Oh, Ik Hyun;Lee, Seung Min;Oh, Yong Jun
    • Korean Journal of Metals and Materials
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    • v.49 no.3
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    • pp.250-255
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    • 2011
  • The basic properties and electrical characteristics of sputtering films deposited with a commercial cast target and Spark Plasma Sintering (SPS) were compared and analyzed. From the results, the Cu film prepared heating $60^{\circ}C/min$ (SPS process) showed a similar specific resistance compared to the commercial cast Cu film. Also, auording to the results of XRD, SIMS, and TEM. There was not much difference in the crystal structure and impurities between the two films. Consequently, the SPS Cu target was found to have quite similar properties with the commercial one and it is expected to be applied in futare research to the metal wiring material for semiconductor/display devices.

Total value recovery in the copper smelting and refining operations

  • Kim Joe. Y.;Kong Bong S.
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.590-597
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    • 2003
  • Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and $Dor\'{e}$ furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyro-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

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