• Analytical Science and Technology
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• v.8 no.4
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• pp.561-568
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• 1995

Two methods, precipitation and ultrafiltration, were applied in order to recover platinum group metals(PGM) by complexing them with water-soluble polyelectrolytes, e.g., polyethyleneimine [PEl], poly(2-vinylpyridine) [2-PVP], poly (4-vinylpyridine) [4-PVP], and poly (styrene sulfonic acid) [PSSA]. In the precipitation method, the PGM-polyelectrolyte complex that was formed by mixing first with polybase, e.g.,4-PVP at pH 1 was precipitated by further mixing with polyacid, e.g., PSSA. However, the recovery of PGM obtained by this method was not quantitative(less than 70%). The "sandwiching" binding between the metal anions and two polyelectrolytes was examined by X-ray photoelectron spectroscopy(XPS). The XPS studies indicated that the PGM atom was bound with the acdic and basic polyelectrolyte via its oxygen and nitrogen atom, respectively. The recovery of PGM using polyelectrolyte was further studied by ultrafiltration methods as follows : The PGM ions, eomplexed at pH 1 with polyelectrolyte, allowed the applicntion of membrane filtration by virtue of the great differences in molecular weights between PGM and other low molecular weight species. By applying this method, Pd and Pt (ca. $10^{-4}M$) were selectively separated almost quantitatively from coexisting metal ions, e.g., $Cu^{2+}$ and $Ni^{2+}$. The EPR spectra and viscosity measurements indicated that these polyelectrlytes were not bound to $Cu^{2+}$ and $Ni^{2+}$ ions at this pH, which provided the basis for selective separation of PGM(Pd, Pt and Rh) from these coexisting ions.

• STI Policy Review
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• v.3 no.2
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• pp.152-171
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• 2012

In April 2001, many Japanese national institutes were reorganized as Independent Administrative Institutions (IAI) based on the General Act for Independent Administrative Institutions and the act for each institution. Under the Ministry of Education, Culture, Sports, Science and Technology (MEXT), the National Institute for Materials Science (NIMS) was established by the merger of the National Research Institute for Metals (NRIM) and the National Institute for Research in Inorganic Materials (NIRIM). One of the biggest changes was the expansion of autonomous administration. The nanotechnology and material R&D field was prioritized in the 2nd (2001-2005) and the 3rd (2006-2010) Science and Technology Basic Plans; subsequently, NIMS was assigned to take the initiative in nanotechnology as well as materials science. NIMS has proactively expanded research fields through the introduction of researchers from polymers, electronics, and biotechnology as well as member institutes of the World Materials Research Institute Forum (WMRIF). Globalization has been promoted through programs that include the International Center for Young Scientists (ICYS) and the International Center for Materials Nanoarchitectonics (MANA). The 4th Science and Technology Basic Plan (2011-2015) emphasizes outcomes-recovery and rebirth from the disaster, green innovation, and life innovation. The Midterm Plan for NIMS also follows it. R&D collaboration by multi-partners (that include industry, university, and GRI) should be strategically promoted where GRI are especially required to play a hub function for innovative R&D and open innovation. NIMS highlights are Tsukuba Innovation Arena (TIA) and the Nanotechnology Platform Project. On January 20, 2012, a new organization was decided on by the Japanese Government where several IAI from different science and technology areas will be merged to realize more effective R&D as well as administrative cost reductions. NIMS is also supposed to be merged with 4 other R&D IAI under MEXT by the end of 2013.

• Journal of the Korean Magnetics Society
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• v.8 no.5
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• pp.317-332
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• 1998

The adiabatic nuclear demagnetization cooling technique has reduced the lowest accessible temperature to the regime of microkelvin, and consequently led to a large expansion in microkelvin physics such as solid and liquid $^{3}He$, superconductivity of noble metals, spin glass transition, and nuclear magnetism. Our ability to reach temperature in microkelvin regime has greatly facilitated by the developments of dilution refrigerator and superconductivity magnet. It is appropriate to divide nuclear demagnetization cooling into two categories; those in which only the nuclear spin system is cooled down and those in which the lattice and conduction electrons in the refrigerant or the specimen are also cooled by the cooling power of nuclear spin system. The former cooling technique has utilized to investigate the nuclear magnetism at temperature in nanokelvin regime. The latter is widely used in studying the phenomena occurring in microkelvin regime. In this review paper, we will discuss the basic principles of nuclear demagnetization cooling and its applications. This work is supported by the Basic Science Research Institute Program under contract number BSRI-97-2404.

• Journal of Korea Soil Environment Society
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• v.3 no.1
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• pp.75-81
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• 1998

In most of studies on solidification/stabilization with waste, small columns have been used to examinate adsorption or leachate. However, these experiments using small apparatus have been limited to apply with the field. In this study, considering an application to the field, a large Lysimeter(100cm$\times$100cm$\times$100cm) used for the simulation. Then, the open dumping waste was mixed directly with bentonite to simulate the stabilization of waste, environmental aspects and several basic tests. As a result, the concentration of heavy metals and contaminated substances changed with bentonite rate. Most of contaminated substances were decreased in leaching with increased mixing rate of bentonite. Especially, the concentration of CODcr removed 25~30%. Also, the residual soil in dumping waste produced approximately 80% of total volume by 40$\times$40mm screen.

• Korean Journal of Materials Research
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• v.33 no.2
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• pp.54-62
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• 2023

The most comprehensive and particularly reliable method for non-destructively measuring the residual stress of the surface layer of metals is the sin²ψ method. When X-rays were used the relationship of ε_φψ-sin²ψ measured on the surface layer of the processing metal did not show linearity when the sin²ψ method was used. In this case, since the effective penetration depth changes according to the changing direction of the incident X-ray, σ_φ becomes a sin²ψ function. Since σ_φ cannot be used as a constant, the relationship in ε_φψ-sin²ψ cannot be linear. Therefore, in this paper, the orthogonal function method according to Warren's diffraction theory and the basic profile of normal distribution were synthesized, and the X-ray diffraction profile was calculated and reviewed when there was a linear strain (stress) gradient on the surface. When there is a strain gradient, the X-ray diffraction profile becomes asymmetric, and as a result, the peak position, the position of half-maximum, and the centroid position show different values. The difference between the peak position and the centroid position appeared more clearly as the strain (stress) gradient became larger, and the basic profile width was smaller. The weighted average strain enables stress analysis when there is a strain (stress) gradient, based on the strain value corresponding to the centroid position of the diffracted X-rays. At the 1/5 I_max max height of X-ray diffraction, the position where the diffracted X-ray is divided into two by drawing a straight line parallel to the background, corresponds approximately to the centroid position.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.133-133
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• 2013

For both oxygen reduction (ORR) and hydrogen oxidation reactions (HOR) of proton electrolyte membrane fuel cells (PEMFCs), alloying Pt with another transition metal usually results in a higher activity relative to pure Pt, mainly due to electronic modification of Pt and bifunctional behaviour of alloy surface for ORR and HOR, respectively. However, activity and stability are closely related to the preparation of alloy nanoparticles. Preparation conditions of alloy nanoparticles have strong influence on surface composition, oxidation state, nanoparticle size, shape, and contamination, which result from a large difference in redox priority of metal precursors, intrinsic properties of metals, increasedreactivity of nanocrystallites, and interactions with constituents for the synthesis such as solvent, stabilizer, and reducing agent, etc. Carbon-supported Pt-Ni alloy nanoparticles were prepared by the borohydride reduction method in anhydrous solvent. Pt-Ru alloy nanoparticles supported on carbon black were also prepared by the similar synthetic method to that of Pt-Ni. Since electrocatalytic reactions are strongly dependent on the surface structure of metal catalysts, the atom-leveled design of the surface structure plays a significant role in a high catalytic activity and the utilization of electrocatalysts. Therefore, surface-modified electrocatalysts have attracted much attention due to their unique structure and new electronic and electrocatalytic properties. The carbon-supported Au and Pd nanoparticles were adapted as the substrate and the successive reduction process was used for depositing Pt and PtM (M=Ru, Pd, and Rh) bimetallic elements on the surface of Au and Pd nanoparticles. Distinct features of the overlayers for electrocatalytic activities including methanol oxidation, formic acid oxidation, and oxygen reduction were investigated.

• Resources Recycling
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• v.15 no.2 s.70
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• pp.58-68
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• 2006

This study is carried out for the purpose of investigating the property of phosphogypsum, and suggesting the proper recycling system for it. The chemical composition, mineralogical composition, particle size distribution and shape of phosphogypsum were investigated. The size distribution and constitution of impurities, distribution of heavy metals are also investigated. In conclusion, the grade and yield of recoverable phosphogypsum were discussed.

• Journal of Integrative Natural Science
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• v.10 no.4
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• pp.175-191
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• 2017

In organic chemistry amide synthesis is performed through condensation of a carboxylic acid and an amine with releasing one equivalent of water via the corresponding ammonium carboxylate salt. This method is suffering from tedious processes and poor atom-economy due to the adverse thermodynamics of the equilibrium and the high activation barrier for direct coupling of a carboxylic acid and an amine. Most of the chemical approaches to amides formations have been therefore being developed, they are mainly focused on secondary amides. Direct carbonylations of tertiary amines to amides have been an exotic field unresolved, in particular direct carbonylation of trimethylamine in lack of commercial need has been attracted much interests due to the versatile product of N,N-dimethylacetamide in chemical industries and the activation of robust N-C($sp^3$) bond in tertiary amine academically. This review is focused mainly on carbonylation of trimethylamine as one of the typical tertiary amines by transition metals of cobalt, rhodium, platinum, and palladium including the role of methyl iodide as a promoter, the intermediate formation of acyl iodide, the coordination ability of trimethylamine to transition metal catalysts, and any possibility of CO insertion into the bond of Me-N in trimethylamine. In addition reactions of acyl halides as an activated form of acetic acid with amines are reviewed in brief since acyl iodide is suggested as a critical intermediate in those carbonylations of trimethylamine.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2001.04a
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• pp.1072-1075
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• 2001

$Al_2O_3$ ceramics are generally used as components in processing equipment, devices or machinery because it can perform some functions better than competing metals or polymers. Many of these applications rely on $Al_2O_3$ ceramics special electromagnetic properties, its relative chemical inertness, hardness, strength and its temperature capabilities. But $Al_2O_3$ ceramics are brittle materials, a fact that may cause problems and at the same time be helpful while machining with laser. This study described a basic study of the input parameters effect on the dimension of the microhole at the $Al_2O_3$ ceramics using Excimer laser. In the laser microhole machining of $Al_2O_3$ ceramics, major input parameters are pulse energy, pulse power, pulse frequency and pulse numbers. In conclusion, we can get a smaller microhole and diameter rate by an appropriate pulse energy, pulse frequency and pulse number.

• Journal of Environmental Science International
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• v.5 no.6
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• pp.771-778
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• 1996

The sediment in the highly contaminated Gamjeon brook was collected, mixed with the raw material of the tile, and then the commercial tile was produced using the mixture. The concentrations of the heavy metals in the mixture-before and after the tile was produced-were analyzed and the effects of the acid solution on the produced tile were examined. The production of the tiles was successful and the result of heavy metal analysis showed that the concentration of Fe was the highest and that of Cd was the lowest The amount of heavy metal in the sediment - the raw material of the tile mixture was more than that of the produced tile. The elution concentration of the heavy metal by the acid solution(pH : 4 - 7) was low and the quality of the produced tile was better than the commercial tile. The result of this study suggested that the contaminated sediment was removed to produce good tiles, therefore the water pollution and soil pollution were reduced.