• 제목/요약/키워드: Barrier films

검색결과 491건 처리시간 0.023초

Polyimide LB막내의 탄성 및 비탄성 tunneling 전기전도특성 (Elastic and inelastic electron tunneling characteristics in polyimide LB films)

  • 김태성;김현종
    • E2M - 전기 전자와 첨단 소재
    • /
    • 제7권6호
    • /
    • pp.473-480
    • /
    • 1994
  • The electron tunnel effect in polvimide LB films sandwiched between metal electrodes has been investigated in the present work by a study of both the elastic and inelastic tunneling components. By the results of elastic tunneling experiments in Au/Pl/Au tunneling junction, we can judge the height and thickness of tunnel barrier. The inelastic current in Inelastic Electron Tunneling Spectroscopy(IETS) is due to the interaction of the tunneling electron with the vibrational modes of the molecular species in the barrier. Measurements are done on Au/PI/Pb tunneling junctions. The spectra obtained are the second derivatives of the current-voltage characteristics of these junctions : specifically, d$^{2}$1/dV$^{2}$ as a function of voltage V. Because the energies measured by IETS can be directly compared to those measured by infrared and Raman spectroscopy, IR-RAS spectroscopy also measured for reference.

  • PDF

XRD 분석에 의한 결정구조와 PL 분석에 의한 광학적 특성의 상관성 (Relationship between Optical Properties Analyzed by Photoluminance of Bonding Structure Analyzed by X-ray Diffractometer)

  • 오데레사
    • 반도체디스플레이기술학회지
    • /
    • 제15권1호
    • /
    • pp.70-75
    • /
    • 2016
  • GZO films prepared on ITO glasses were annealed at various temperatures in a vacuum condition to research the relationship between oxygen vacancies and optical properties. GZO films after annealing in a vacuum showed the various optical-chemical properties depending on the annealing temperatures and oxygen gas flow rate during the deposition. The oxygen vacancy of GZO film prepared by oxygen gas flows of 22 sccm increased with increasing the annealing temperatures, because of the extraction of oxygen by the annealing. But the intensity of photoluminance of GZO with 22 sccm decreased in accordance with the annealing temperature, because of the reduction of ionized charge carriers. The oxygen vacancy by the extraction of oxygen enhanced a depletion, so the widen depletion had the strong Schottky barrier and the PL intensity due to the low carrier density decreased.

The Properties of Nitrogen Implanted Tungsten Diffusion Barrier for Cu Metallization

  • Kim, D.J.;Kim, D.J.;Kim, Y.T.;Lee, J.Y.
    • 한국진공학회지
    • /
    • 제4권S2호
    • /
    • pp.79-82
    • /
    • 1995
  • $N^+$ beam modified diffusion barriers have been proposed for Cu metallization . The crystalline phases of W and Ti thin films change from polycrytalline to amorphous phase by the N ion implantation of 1~$3\times 10^{17}$atoms/$\textrm{cm}^2$. The comparison between these amorphized diffusion barriers and the conventional W and TiN films shows that the amorphized W and Ti diffusion barriers are superior to the conventional w and TiN for protecting the Cu diffusion barriers are superior to the conventional W and TiN for protecting the Cu diffusion at the annealing temperature range $600^{\circ}C$~$800^{\circ}C$ for 30min. This is a worldwidely new and excellent result on the high temperature thermal stability of diffusion barrier.

  • PDF

Langmuir-Blodgett법을 이용한 (N-docosyl quinolinium)-TCNQ(1:2) 착물의 초박막 제작 (Fabrication of Ultra Thin Films with (N-docosyl quinolinium)-TCNQ(1:2) complex by the Langmuir -Blodgett Technique)

  • 정순욱;정회걸
    • 한국재료학회지
    • /
    • 제9권12호
    • /
    • pp.1229-1233
    • /
    • 1999
  • 본 연구에서는 (N-docosyl quinolinium)-TCNQ (1:2) 착물의 LB초박막을 제작하였다. LB막의 누적을 위한 최적조건을 구하기 위하여 subphase 온도, barrier 압축속도 및 분산량을 변화시키면서 표면압-면적(${\pi}$-A) 등온선 특성을 측정하였다. 그리고 전이비, UV-vis의 최대 흡광도, 정전용량 및 두께를 측정하여 LB막의 누적상태를 확인하였다. 그 결과 분자수준으로 잘 제어된 양호한 LB막이 제작되었음을 알 수 있었다..

  • PDF

Roll-to-Roll Barrier Coatings on PET Film by Using a Closed Drift Magnetron Plasma Enhanced Chemical Vapor Deposition

  • Lee, Seunghun;Kim, Jong-Kuk;Kim, Do-Geun
    • 한국표면공학회:학술대회논문집
    • /
    • 한국표면공학회 2012년도 춘계학술발표회 논문집
    • /
    • pp.124-125
    • /
    • 2012
  • Korea institute of materials science (KIMS) use a linear deposition source called as a closed drift linear plasma source (CDLPS) as well as dual magnetron sputtering (DMS) to deposit SiOxCyHz films in $HMDSO/O_2$ plasma. The CDLPS generates linear plasma using closed drifting electrons and can reduce device degradations due to energetic ion bombardments on organic devices such as organic photovoltaic and organic light emission diode by controlling an ion energy. The deposited films are investigated by Fourier transform infrared (FT-IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM). Optical emission spectroscopy (OES) is used to measure relative radical populations of dissociation and recombination products such as H, CH, and CO in plasma. And SiOx film is applied to a barrier film on organic photovoltaic devices.

  • PDF

창유리 위에 졸겔 담금 방법으로 코팅된 인듐 주석 산화막의 에너지 절약 특성 (Energy Saving Properties of Sol Gel Dip Coated Indium Tin Oxide Films on a Glass Pane)

  • 정형진;이희형;이동헌;이전국
    • 한국세라믹학회지
    • /
    • 제29권1호
    • /
    • pp.48-52
    • /
    • 1992
  • Indium tin oxide (ITO) layers are of considerable interest on account of the combination of properties they provide high electrical conductivity, high infrared reflection with high solar energy transmission, high transmission in the visible range. We are concerned about the variation of the spectral transmittances and sheet resistances as the thickness of SiO2-ZrO2 barrier layer and ITO layers and heat treating conditions are changed. Transmittances and reflectivities were studied by measuring UV-VIS-NIR-, FT-IR spectroscopy. ITO films are crack free, homogeneous and of polycrystalline cubic structure. The microstructure of good ITO films shows a narrow grain size distribution and mean value of 100 nm. The selectivity of absorbing properties is improved by increasing the thickness of ITO films. The increase of sheet resistance of ITO films are due to the increase in the reaction between films and glass substrate.

  • PDF

Alumina Sol을 코팅한 BOPP 복합체의 제조 및 기체 투과 특성 (Preparation of Alumina Sol Coated BOPP Composites and Their Gas Permeation Characteristics)

  • 홍성욱;오재원;고영덕;송기창
    • 멤브레인
    • /
    • 제19권1호
    • /
    • pp.19-24
    • /
    • 2009
  • 졸-겔 공정은 비교적 간단하고 사용이 편리하며 저렴한 설비투자비가 소요되면서도 우수한 물성 및 차단특성을 갖는 코팅 박막을 얻을 수 있다는 장점이 있다. 졸-겔 공정으로 코팅된 필름은 산소 등의 영향에 의해 부패되기 쉬운 식품, 음료, 약품, 의약품 등의 포장재나 단열제로 응용 가능하다. 본 연구에서는 aluminum isopropoxide를 출발물질로 하여 alumina sol을 제조한 후 실란 커플링제를 첨가하여 코팅 용액을 제조하였다. 또한, 제조된 alumina sol 용액을 이축연신 폴리프로필렌(BOPP)에 코팅하여 복합 필름을 만들고 산소 투과 특성을 측정한 결과 순수한 BOPP에 비해서 산소 투과도가 약 85% 정도 감소되는 효과를 보였다.