• Title/Summary/Keyword: Band aggregation

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Aggregation-induced photoluminescence enhancement of polymetalloles by energy migration (에너지 전달을 이용한 Polymetalloles의 응집에 의해 유도되는 광발광성의 증가)

  • Kwon, Hyung-Jun;Jung, Dae-Hyuk;Song, Jin-Woo;Jang, Seung-Hyun;Kim, Bum-Seok;Kwon, Yong-Hee;Cho, Sung-Dong;Sohn, Hong-Lae
    • Journal of Sensor Science and Technology
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    • v.15 no.5
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    • pp.303-308
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    • 2006
  • Aggregation-induced emissions of polymetalloles have been investigated since they are very attractive in their possible optoelectronic applications such as P-LED's and Sensors. Size of nanoparticulates was measured by using scanning electron micrograph and was about 200-300 nm. Phenylmethylpolysilane (PMPS) and polymetalloles emit the light at 360 nm and 520 nm, respectively. However, the aggregates of polymetallole containing PMPS exhibit an enhanced emission band at 520 nm, indicating that the energy transfer occurs from PMPS to polymetalloles in aggregates. Emission intensity of PMPS/polymetallole nanoparticulates at 520 nm increases depending on the aliquot of PMPS.

Principles of Flexible-Use Spectrum Rights

  • Matheson Robert J.
    • Journal of Communications and Networks
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    • v.8 no.2
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    • pp.144-150
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    • 2006
  • A serious problem with traditional 'command & control' spectrum management techniques is that they do not easily accommodate new technologies and new services. This paper describes the necessary principles of flexible-use spectrum rights which may allow a wide variety of spectrum uses in a single general-purpose band. Based on the electrospace description of the radio spectrum, these principles allow general aggregation or division of licensed electrospace regions via secondary markets, providing rules for how regulatory limits change under aggregation or division. These flexible-use principles limit transmitter behaviors that tend to create a more difficult operating environment for receivers, while making receivers responsible for handling any remaining interference. The author shows how flexible-use principles could provide a basis for real-world flexible-use frequency bands.

Effect of Urea on the Rose Bengal Sensitized Photocurrent (Rose Bengal 감응 광전류에 미치는 Urea의 영향)

  • Yun, Gil Jung;Gang, Seong Cheol;Kim, Gang Jin
    • Journal of the Korean Chemical Society
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    • v.34 no.6
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    • pp.600-605
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    • 1990
  • Electron injection from excited rose bengal into the conduction band of a thin film of SnO$2$, semiconductor was investigated in an electrochemical cell, ITO/SnO$2$/rose bengal, NaClO$4$/Pt. It was observed that urea enhanced the supersensitized photocurrent, followed by the reduction in the photocurrent after a shallow maximum. Spectroscopic analyses of the dye solution containing urea revealed that dye aggregation appeared to be involved in the increased photocurrent, although the concentration of the dye was continuously decreased dye to photochemical reactions.

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Anion co-doped Titania for Solar Photocatalytic Degradation of Dyes

  • Lee, Young-Seak;Kim, Sang-Jin;Venkateswaran, P.;Jang, Jeen-Seok;Kim, Hyuk;Kim, Jong-Gyu
    • Carbon letters
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    • v.9 no.2
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    • pp.131-136
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    • 2008
  • In order to investigate the effect of doping C, N, B and F elements on $TiO_2$ for reducing the band gap, the heat treatment of $TiO_2$ was carried out with tetraethylammonium tetrafluoroborate. Through XRD and XPS analysis, the C, N, B and F doped anatase $TiO_2$ was confirmed. According to the increase of temperature during treatment, the particle size was increased due to aggregation of $TiO_2$ with elements (B, C, N and F). To investigate the capacity of photocatalyst for degradation of dye under solar light, the degradation of acridine orange and methylene blue was conducted. The degradation of dyes was carried out successfully under solar light indicating the effect of doping elements (B, C, N and F) on $TiO_2$ for reducing the band gap effectively.

A Study on Permittivity of Multi-walled Carbon nanotube/Epoxy Composites (다중벽 탄소나노튜브/에폭시 복합재료의 유전율에 관한 연구)

  • 이상의;박기연;김천곤;한재흥
    • Composites Research
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    • v.17 no.3
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    • pp.38-44
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    • 2004
  • The electromagnetic interference (EMI) shielding is very essential for commercial and military purposes. We fabricated multi-walled carbon nanotube (MWNT)/epoxy composites and studied the electromagnetic characteristics of the composites before we study the characteristics of MWNT-added glass fiber-reinforced composites. After setting up the fabrication process, we measured the permittivity of MWNT/epoxy composites with process variables and MWNT concentrations in X-band (8.2GHz~12.4GHz). We also observed re-aggregation phenomenon of MWNTs and investigated its effect on the permittivity. The permittivity of the composites was influenced by the degree of dispersion of MWNTs and increased almost linearly as MWNT concentration increases.

INTRODUCTION OF NUC ALGORITHM IN ON-BOARD RELATIVE RADIOMERIC CALIBRATION OF KOMPSAT-2

  • Song, J.H.;Choi, M.J.;Seo, D.C.;Lee, D.H.;Lim, H.S.
    • Proceedings of the KSRS Conference
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    • 2007.10a
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    • pp.504-507
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    • 2007
  • The KOMPSAT-2 satellite is a push-broom system with MSC (Multi Spectral Camera) which contains a panchromatic band and four multi-spectral bands covering the spectral range from 450nm to 900nm. The PAN band is composed of six CCD array with 2528 pixels. And the MS band has one CCD array with 3792 pixels. Raw imagery generated from a push-broom sensor contains vertical streaks caused by variability in detector response, variability in lens falloff, pixel area, output amplifiers and especially electrical gain and offset. Relative radiometric calibration is necessary to account for the detector-to-detector non-uniformity in this raw imagery. Non-uniformity correction (NUC) is that the process of performing on-board relative correction of gain and offset for each pixel to improve data compressibility and to reduce banding and streaking from aggregation or re-sampling in the imagery. A relative gain and offset are calculated for each detector using scenes from uniform target area such as a large desert, forest, sea. In the NUC of KOMPSAT-2, The NUC table for each pixel are divided as HF NUC (high frequency NUC) and LF NUC (low frequency NUC) to apply to few restricted facts in the operating system ofKOMPSAT-2. This work presents the algorithm and process of NUC table generation and shows the imagery to compare with and without calibration.

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Aspartyl aminopeptidase of Schizosaccharomyces pombe has a molecular chaperone function

  • Lee, Song-Mi;Kim, Ji-Sun;Yun, Chul-Ho;Chae, Ho-Zoon;Kim, Kang-Hwa
    • BMB Reports
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    • v.42 no.12
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    • pp.812-816
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    • 2009
  • To screen chaperone proteins from Schizosaccharomyce pombe (S. pombe), we prepared recombinant citrate synthase of the fission yeast as a substrate of anti-aggregation assay. Purified recombinant citrate synthase showed citrate synthase activity and was suitable for the substrate of chaperone assay. Several heat stable proteins including aspartyl aminopeptidase (AAP) for candidates of chaperone were screened from the supernatant fraction of heat-treated crude extract of S. pombe. The purified AAP migrated as a single band of 47 kDa on SDS-polyacrylamide gel electrophoresis. The native size of AAP was estimated as 200 kDa by a HPLC gel permeation chromatography. This enzyme can remove the aspartyl residue at N-terminus of angiotensin I. In addition, AAP showed the heat stability and protected the aggregation of citrate synthase caused by thermal denaturation. This study showed that S. pombe AAP is a moonlight protein that has aspartyl aminopeptidase and chaperone activities.

Self-Aggregation of Synthetic Magnesium Bacteriochlorins as a Photosynthetic Antenna Model

  • Kunieda, Michio;Mizoguchi, Tadashi;Tamiaki, Hitoshi
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.353-355
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    • 2002
  • We prepared 3-(1-hydroxyethyl)-bacteriopyrochlorophy11-a (3) possessing magnesium atom and phytyl ester from modification of natural bacteriochlorophyll(BChl)-a. A dichloromethane solution of (3$^1$R) and (3$^1$S)-3 was diluted with 100~1000 fold volume of cyclohexane to give new species absorbing near-infrared lights. The resulting Q, maximum of (3$^1$R)-3 was 860 nm and red-shifted by 2150 $cm^{-1}$ / from the monomeric. In the nonpolar organic solvent, epimeric (3$^1$S)-3 showed a 1ess red-shifted peak at 798 nm as well as a residual monomeric band. Such visible spectra indicated that 3 diastereose1ectively aggregated in cyclohexane to afford oligomers possessing a simi1ar supramolecular structure with chlorosomal aggregates of natural BChl-d, 7,8-dehydro-form of 3.

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A Method for IPv6 Address Assignments of the Next Generation Defense Network (차세대 국방정보통신망을 위한 IPv6 주소 할당 방안)

  • Kim, Kwon-Il;Lee, Sang-Hoon
    • Journal of KIISE:Computing Practices and Letters
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    • v.14 no.4
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    • pp.441-445
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    • 2008
  • Korean military is propelling the M&S on new warfare concept, such as NCW(Network Centric Warfare) which is the aspect of future war. IPv6 is the essential element of next generation defense network which is supporting the future battlefield. There have been many studies on allocating the IPv6 address for next generation defense network. However, they assigned the address by level on the basis of the military organization or assigned it from the service network, so it had the defect, the big size routing table. This study reviews the topology of next generation defense network and adjusts the position of service network ID on the basis of the network topology. Finally, it improved the efficiency of route aggregation and minimized the routing table size in comparison with the previous studies and it was proved by OPNET simulator.

Kinetic Studies of the Aggregation of 3,3'-Diethyl Oxacarbocyanine onto Polyacrylic Acid (폴리아크릴산 용액에서의 옥사카르보시안닌 색소분자의 회합현상에 대한 반응속도론적 연구)

  • Lee, Hong;Im, Eun Suk;Bae, Hyeon Ok
    • Journal of the Korean Chemical Society
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    • v.38 no.11
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    • pp.792-799
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    • 1994
  • The spectral changes of 3,3'-diethyl oxacarbocyanine(DOC) in the aqueous solution and in the presence of polyacrylic acid(PAA) were studied by means of absorption and fluorescence spectroscopy. The spectral change of DOC in the aqueous solution with concentration changes is attributed to the formation of dimer. In the presence of PAA, the characteristic changes of metachromatic band with changes of P/D (the ratio between available binding site and the dye concentration) are found and the discussions are made in terms of stacking theory. A kinetic study of the interaction between DOC and PAA was also investigated by the absorption and fluorescence stopped-flow spectroscopy. The observed relaxation effect in PAA-DOC system can be described quantitatively by assuming two relaxation processes occur.

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