• Title/Summary/Keyword: Band Alignment

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Characteristic of Road Traffic Noise According to Road Vertical Alignment (도로 종단선형에 따른 도로교통 소음 특성 분석)

  • Moon, Hak Ryong;Han, Dae Cheol;Kang, Won Pyoung
    • International Journal of Highway Engineering
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    • v.15 no.4
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    • pp.95-105
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    • 2013
  • PURPOSES: The purpose of this study is to research the influence of road traffic noise by road slope through the analysis of the field road traffic noise and determine consideration of road slope in the case of appling active noise cancellation. METHODS: This study measures vehicle's noise by the NCPX method at the three field sections such as uphill, downhill, and flatland. Total sound pressure and sound pressure level by the 1/3 octave band frequency are calculated through the raw field data. Total sound pressure level is compared by ANOVA test and T test statistically. The results obtained are compared in accordance with the road slope and the progress of the uphill section. RESULTS : The noise characteristic of early, medium, and last parts of uphill was found to be consistent when the vehicle was travelling uphill section. The result of statistical test, it was shown that total sound pressures are not different each other. According to the comparison by the geometry, sound pressure of the uphill section was higher than those of the flatland and downhill section in high frequency band. By the result of statistical test, total sound pressure are different according to geometry in the case of high vehicle speed. In the comparison result by road slope, each sound pressure level was found to be consistent in total frequency. However, total sound pressure proportionally increased according to road slope. CONCLUSIONS: It is found that the effect of road slope on noise generation was little in this experimental sites.

Influence of Electron Beam Irradiation on the Electrical and Optical Properties of InGaZnO Thin Film Transistor (InGaZnO 박막 트랜지스터의 전기 및 광학적 특성에 대한 전자빔 조사의 영향)

  • Cho, In-Hwan;Park, Hai-Woong;Kim, Chan-Joong;Jun, Byung-Hyuk
    • Korean Journal of Materials Research
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    • v.27 no.6
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    • pp.345-349
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    • 2017
  • The effects of electron beam(EB) irradiation on the electrical and optical properties of InGaZnO(IGZO) thin films fabricated using a sol-gel process were investigated. As the EB dose increased, the electrical characteristic of the IGZO TFTs changed from semiconductor to conductor, and the threshold voltage values shifted to the negative direction. X-ray photoelectron spectroscopy analysis of the O 1s core level showed that the relative area of oxygen vacancies increased from 14.68 to 19.08 % as the EB dose increased from 0 to $1.5{\times}10^{16}electrons/cm^2$. In addition, spectroscopic ellipsometer analysis showed that the optical band gap varied from 3.39 to 3.46 eV with increasing EB dose. From the result of band alignment, it was confirmed that the Fermi level($E_F$) of the sample irradiated with $1.5{\times}10^{16}electrons/cm^2$ was located at the closest position to the conduction band minimum(CBM) due to the increase of electron carrier concentration.

Simple fabrication route for vertically-aligned CZTS nanorod arrays for photoelectrochemical application based on AAO template

  • Kim, Ji-Min;Yang, U-Seok;O, Yun-Jeong;Mun, Ju-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.402.2-402.2
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    • 2016
  • In photoelectrochemical (PEC) water splitting, Cu2ZnSnS4 (CZTS) compound has attracted intense attention as a photocathode due to not only large optical absorption coefficient, but also earth-abundance of constituent elements and suitable band alignment. With rapid development of nanotechnology, one-dimensional nanostructures of CZTS have been investigated as a potential form to achieve high efficiency because the nanostructures are expected to be capable of capturing more light and enhancing charge separation and transport. Here, we report a well-controlled fabrication route for vertically-aligned CZTS nanorod arrays on anodic aluminium oxide (AAO) template via simple sol-gel process followed by deposition of ZnS or CdS buffer layers on the CZTS nanorod to enhance charge separation. The structure, morphology, composition, optical absorption, and PEC properties of the resulting CZTS nanorod samples were characterized using X-ray diffraction, Raman spectroscopy, transmission electron microscopy, energy dispersive X-ray spectrometry, scanning electron microscopy, and UV-vis spectroscopy.

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The Interfacial Electronic Structure of Organic-organic Heterojunction: Effect of Molecular Orientation

  • Jo, Sang-Wan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.114.2-114.2
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    • 2014
  • The orientation of the constituent molecules in organic thin film devices can affect significantly their performance due to the highly anisotropic nature of ${\pi}$-conjugated molecules. We report here an angle dependent x-ray absorption study of the control of such molecular orientation using well-ordered interlayers for the case of a bilayer heterojunction of chloroaluminum phthalocyanine (ClAlPc) and C60. Furthermore, the orientation-dependent energy level alignment of the same bilayer heterojunction has been measured in detail using synchrotron radiation-excited photoelectron spectroscopy. Regardless of the orientation of the organic interlayer, we find that the subsequent ClAlPc tilt angle improves the ${\pi}-{\pi}$ interaction at the interface, thus leading to an improved short-circuit current in photovoltaic devices based on ClAlPc/C60. The use of the interlayers does not change the effective band gap at the ClAlPc/C60 heterointerface, resulting in no change in open-circuit voltage.

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Soft X-ray Spectroscopy of ClAlPc/Pentacene/ITO Interfaces: Role of ClAlPc on Energetic Band Alignment

  • Kim, Min-Su;Heo, Na-Ri;Lee, Sang-Ho;Jo, Sang-Wan;Smith, Kevin E.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.190.1-190.1
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    • 2014
  • The interfacial electronic structure of a bilayer of chloroaluminum phthalocyanine (ClAlPc) and pentacene grown on indium tin oxide (ITO) has been studied using synchrotron radiation-excited photoelectron spectroscopy. The energy difference between the highest occupied molecular orbital (HOMO) level of the pentacene layer and the lowest unoccupied molecular orbital (LUMO) level of the ClAlPc layer (EDHOMO - EALUMO) was determined and compared with that of C60/pentacene bilayers. The EDHOMO - EALUMO of a heterojunction with ClAlPc was found to be 1.4 eV, while that with C60 was 1.0 eV. This difference is discussed in terms of the difference of the ionization energy of each acceptor materials. We also obtained the complete energy level diagrams of ClAlPc/pentacene/ITO and C60/pentacene/ITO, respectively.

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Solid-Electrolyte Interphase in the Spinel Cathode Exposed to Carbonate Electrolyte in Li-Ion Battery Application: An ab-initio Study

  • Choe, Dae-Hyeon;Gang, Jun-Hui;Han, Byeong-Chan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.169-169
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    • 2017
  • Due to key roles for the electrochemical stability and charge capacity the solid-electrolyte interphase (SEI) has been extensively studied in anodes of a Li-ion battery cell. There is, however, few of investigation for cathodes. Using first-principles based calculations we describe atomic-level process of the SEI layer formation at the interface of a carbonate electrolyte and $LiMn_2O_4$ spinel cathode. Furthermore, using beyond the conventional density functional theory (DFT+U) calculations we examine the work function of the cathode and frontier orbitals of the electrolyte. Based on the results we propose that proton transfer at the interface is an essential mechanism initiating the SEI layer formation in the $LiMn_2O_4$. Our results can guide a design concept for stable and high capacity Li-ion battery cell through screening an optimum electrolyte fine-tuned energy band alignment for a given cathode.

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Optical System with 4 ㎛ Resolution for Maskless Lithography Using Digital Micromirror Device

  • Lee, Dong-Hee
    • Journal of the Optical Society of Korea
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    • v.14 no.3
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    • pp.266-276
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    • 2010
  • In the present study, an optical system is proposed for maskless lithography using a digital micromirror device (DMD). The system consists of an illumination optical system, a DMD, and a projection lens system. The illumination optical system, developed for 95% uniformity, is composed of fly's eye lens plates, a 405 nm narrow band pass filter (NBPF), condensing lenses, a field lens and a 250W halogen lamp. The projection lens system, composed of 8 optical elements, is developed for 4 ${\mu}m$ resolution. The proposed system plays a role of an optical engine for PCB and/or FPD maskless lithography. Furthermore, many problems arising from the presence of masks in a conventional lithography system, such as expense and time in fabricating the masks, contamination by masks, disposal of masks, and the alignment of masks, may be solved by the proposed system. The proposed system is verified by lithography experiments which produce a line pattern with the resolution of 4 ${\mu}m$ line width.

Optical Characteristics of Liquid Crystal Cell Prepared by Using Surface Relief Grating As the Alignment Layer (표면 부조격자를 배향막으로 사용하여 제작된 액정셀의 광특성)

  • 이종진;김정성;황의중;오차환;이건준;박병주;이영백;백상현
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.07a
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    • pp.120-121
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    • 2003
  • 아조벤젠 고분자는 광 정보저장 및 광 스위치 소자 등의 응용가능성 때문에 많은 연구가 진행되어왔다. 이것은 바로 아조 분자가 가지고 있는 두 이성체 간의 광 이성화 과정에 의한 아조 분자의 정렬에 의한 광 유도 anisotropy가 생기는 특성과 더불어 아조 분자의 이동에 의한 표면 부조가 형성됨이 보고된 이후에 광 정보 저장은 물론 액정의 배향이나 phase mask로의 응용, 특히 photonic band gap(PBG) 효과를 기대 할 수 있는 주기구조 형성에의 응용성 때문에 더욱 관심이 집중되고 있다.

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Align-free Micro-optic Mach-Zehnder Interferometric Filter (정렬에 무관한 마이크로옵틱 마하젠더 간섭계형 필터)

  • Lee, Jong-Hoon;Kim, Hyun-Deok;Song, Jae-Won
    • Korean Journal of Optics and Photonics
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    • v.17 no.3
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    • pp.285-289
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    • 2006
  • A novel alignment-free micro-optic MZI filter has been demonstrated. The filter is composed of two fiber-pigtailed collimators and a beam-splittingplate with a periodically etched stripe pattern. We fabricated the plate through a standard lithographic formulation process by using a pyrex substrate glass with SU-8 resist coating on its one of the surfaces. The maximum insertion loss of the implemented filter was less than 2 dB over 1000 nm to 1600 nm and the extinction ratio was larger than 33 dB. The measured PDL within the 3-dB pass band of the filter was less than 0.15dB and the maximum extinction ratio variation was less than 2 dB even when the worst alignment error occured.

IGRINS Mirror Mount Design for Three Off-Axis Collimators and One Slit-Viewer Fold Mirror

  • Rukdee, Surangkhana;Park, Chan;Kim, Kang-Min;Lee, Sung-Ho;Chun, Moo-Young;Yuk, In-Soo;Oh, Hee-Young;Jung, Hwa-Kyoung;Lee, Chung-Uk;Lee, Han-Shin;Rafal, Marc D.;Barnes, Stuart;Jaffe, Daniel T.
    • Journal of Astronomy and Space Sciences
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    • v.29 no.2
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    • pp.233-244
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    • 2012
  • The Korea Astronomy and Space Science Institute and the Department of Astronomy at the University of Texas at Austin are developing a near infrared wide-band high resolution spectrograph, immersion grating infrared spectrometer (IGRINS). The compact white-pupil design of the instrument optics uses seven cryogenic mirrors, including three aspherical off-axis collimators and four flat fold mirrors. In this study, we introduce the optomechanical mount designs of three off-axis collimating mirrors and one flat slit-viewer fold mirror. Two of the off-axis collimators are serving as H and K-band pupil transfer mirrors, and are designed as system alignment compensators in combination with the H2RG focal plane array detectors in each channel. For this reason, the mount designs include tip-tilt and parallel translation adjustment mechanisms to properly perform the precision alignment function. This means that the off-axis mirrors' optomechanical mount designs are among the most sensitive tasks in all IGRINS system hardware. The other flat fold mirror is designed within its very limitedly allowed work space. This slit-viewer fold mirror is mounted with its own version of the six-point kinematic optics mount. The design work consists of a computer-aided 3D modeling and finite element analysis (FEA) technique to optimize the structural stability and the thermal behavior of the mount models. From the structural and thermal FEA studies, we conclude that the four IGRINS mirror mounts are well designed to meet all optical stability tolerances and system thermal requirements.