• Title/Summary/Keyword: Bamboo Activated Carbon

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Kinetics of NO Reduction with Copper Containing Bamboo Activated Carbon (구리 촉매 담지 대나무 활성탄의 NO 가스 반응 특성)

  • Bak, Young-Cheol;Choi, Joo-Hong
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.3
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    • pp.144-149
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    • 2016
  • The metal-impregnated activated carbon was produced from bamboo activated carbon by soaking method of metal nitrate solution. The carbonization and activation of raw material was conducted at $900^{\circ}C$. The specific surface area and pore size distribution of the prepared activated carbons were measured. Also, NO and activated carbon reaction were conducted in a thermogravimetric analyzer in order to use as de-NOx agents of used activated carbon. Carbon-NO reactions were carried out with respect to reaction temperature ($20^{\circ}C{\sim}850^{\circ}C$) and NO gas partial pressure (0.1 kPa~1.8 kPa). As results, the specific volume and surface area of bamboo activated carbon impregnated with copper were decreased with increasing Cu amounts of activated carbon. In NO reaction, the reaction rate of Cu impregnated bamboo activated carbon[BA(Cu)] was promoted to compare with that of bamboo activated carbon[BA]. But the reaction rate of Ag impregnated bamboo activated carbon[BA(Ag)] was retarded. Measured reaction orders of NO concentration and activation energy were 0.63[BA], 0.92[BA(Cu)], and 80.5 kJ/mol[BA], 48.5 kJ/mol[BA(Cu)], 66.4 kJ/mol[BA(Ag)], respectively.

Production of Silver Impregnated Bamboo Activated Carbon and Reactivity with NO Gases (은첨착 대나무 활성탄의 제조와 NO 가스 반응 특성)

  • Bak, Young-Cheol;Choi, Joo-Hong;Lee, Geun-Lim
    • Korean Chemical Engineering Research
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    • v.52 no.6
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    • pp.807-813
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    • 2014
  • The Ag-impregnated activated carbon was produced from bamboo activated carbon by soaking method of silver nitrate solution. The carbonization and activation of raw material was conducted at $900^{\circ}C$. Soaking conditions are the variation of silver nitrate solution concentration (0.002~0.1 mol/L) and soaking time (maximum 24 h). The specific surface area and pore size distribution of the prepared activated carbons were measured. Also, NO and activated carbon reaction were conducted in a thermogravimetric analyzer in order to use for de-NOx agents of used activated carbon. Carbon-NO reactions were carried out with respect to reaction temperature ($20{\sim}850^{\circ}C$) and NO gas partial pressure (0.1~1.8 kPa). As results, Ag amounts are saturated within 2h, Ag amounts increased 1.95 mg Ag/g (0.2%)~ 88.70 mg Ag/g (8.87%) with the concentration of silver nitrate solution in the range of 0.002~0.1 mol/L. The specific volume and surface area of bamboo activated carbon of impregnated with 0.2% silver were maximum, but decreased with increasing Ag amounts of activated carbon due to pore blocking. In NO reaction, the reaction rate of impregnated bamboo activated carbon was retarded as compare with that of bamboo activated carbon. Measured reaction orders of NO concentration and activation energy were 0.63[BA], 0.69l[BA(Ag)] and 80.5 kJ/mol[BA], 66.4 kJ/mol[BA(Ag)], respectively.

A Thermal Characteristics Study on the Application Method of Activated Carbon for a Cement Mortar Finishing Materials (활성탄을 이용한 시멘트모르타르 마감재의 열적 특성연구)

  • Park, Kun-Seok;Cho, Gyu-Hwan;Park, Dong-Cheon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.05a
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    • pp.115-116
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    • 2011
  • This study aimed at establishing the fundamental data needed to evaluate the applicability and practicability in using a bamboo activated carbon as a construction material. The experiment on the flow of mortars mixed with a bamboo activated carbon before the hardening was carried out for the evaluation of basic properties. The compressive and bending strength of mortar mixed with bamboo activated carbon after the hardening was measured. the thermal conduction rate and density were also measured. An comparative analysis on mortars mixed with pine charcoals was conducted to compare it with exiting materials.

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Radon Adsorption Characteristics of Blast Furnace Slag Matrix Using Bamboo Activated Carbon (대나무 활성탄을 활용한 고로슬래그 경화체의 라돈흡착 특성)

  • Park, Chae-Wool;Lee, Jae-Hun;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.27-28
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    • 2019
  • Recently, a bed company detected a radon more than Red Politics and became a hot topic of conversation. This has led to increased interest in radon, and a number of free-of-charge bodies have also been established to recognize the dangers of radon. In addition, the Korean Institute of Geological and Resource Research is planning to assist the installation of radon alarm systems in 10,000 households nationwide, free of charge. Since radon is a colorless, odorless and tasteless gas that causes lung cancer, it aims to reduce lung cancer incidence by absorbing radon using bamboo activated carbon as a way to reduce it. Due to the use of bamboo activated carbon, radon concentration per hour tends to decrease as substitution rate increases, and table flow tends to decrease as substitution rate increases. Through this experiment, 30% of the replacement rate of bamboo activated carbon is judged to be the most suitable replacement rate.

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Micro-Structural and Electrochemical Properties of Activated Carbon Synthesized from Natural Bamboo (천연 대나무로부터 합성된 활성 탄소의 미세구조 및 전기화학적 특성)

  • YANG, DONG-CHEOL;KIM, SU-WON;CHOURASHIYA, M.G.;PARK, CHOONG-NYEON;PARK, CHAN-JIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.5
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    • pp.418-427
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    • 2019
  • Activated carbon was synthesized from bamboo charcoal by KOH activation at various temperatures for electrochemical double layer capacitor applications. The micro-structural and surface properties of all the samples were characterized by X-ray diffraction, scanning electron microscopy and N2 adsorption/desorption isotherm method. The electrochemical properties of the activated bamboo charcoal were examined by cyclic voltammetry in the potential window of -1.0 to 0.2 V in 6 M KOH electrolyte at different scan rates. An electrode made from the sample activated with 7.5 M KOH and heat treated at $750^{\circ}C$ for 3 h gave a maximum capacitance of 553 F/g at 1 mV/s and 450 F/g at 10mV/s.

Properties of Cement Matrix Using Vegetable Activated Carbon (식물성 활성탄을 활용한 시멘트 경화체의 특성)

  • Lee, Jae-Hoon;Park, Chae-Wool;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.06a
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    • pp.138-139
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    • 2020
  • With the rapid progress of industrialization, indoor air quality is a very important factor for modern people who spend most of their day indoors. The recent issue of fine dust and radon on the portal site's popularity search shows that interest in indoor air quality has increased. Fine dust causes respiratory diseases, and radon causes severe lung cancer. The new material was tested using plant activated carbon, palm activated carbon and bamboo activated carbon. Both palm activated carbon and bamboo activated carbon are porous materials and generate smooth physical adsorption. As a result of the experiment, both the activated carbon tends to gradually decrease in strength and fluidity as the replacement ratio increases. The reason for this is that both activated carbons have the property of absorbing moisture, so it is judged that the strength is lowered by absorbing moisture necessary for curing. In the case of fluidity, it is judged that the fluidity is reduced by absorbing the moisture required for the flow. In the future, if the problem of the color of the finished cured body is compensated, it will be possible to manufacture a functional finishing board to replace the existing interior finishing material.

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Effects of Acid Modification on Pb(II) and Cu(II) Adsorption of Bamboo-based Activated Carbon (대나무 활성탄의 산 개질이 납과 구리 이온의 흡착에 미치는 영향)

  • Lee, Myoung-Eun;Chung, Jae-Woo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.1
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    • pp.3-10
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    • 2016
  • Effects of acid ($HNO_3$ and HCl) modification on the adsorption properties of Pb(II) and Cu(II) onto bamboo-based activated carbon (BAC) were investigated through a series of batch experiments. The carbon content increased and oxygen content decreased with acid treatment. $HNO_3$ induced carboxylic acids and hydroxyl functional groups while HCl added no functional group onto BAC. The pseudo-second order model better described the kinetics of Pb(II) and Cu(II) adsorption onto experimented adsorbents, indicating that the rate-limiting step of the heavy metal sorption is chemical sorption involving valency forces through sharing or exchange of electrons between the adsorbate and the adsorbent. The equilibrium sorption data followed both Langmuir and Freundlich isotherm models. The adsorption capacities of BAC were affected by the surface functional groups added by acid modification. The adsorption capacities were enhanced up to 36.0% and 27.3% for Pb(II) and Cu(II), respectively by the $HNO_3$ modification, however, negligibly affected by HCl.

Kinetics of Nitric Oxide Reduction with Alkali Metal and Alkali Earth Metal Impregnated Bamboo Activated Carbon (알칼리금속과 알칼리 토금속 촉매 담지 대나무 활성탄의 NO 가스 반응 특성)

  • Bak, Young-Cheol;Choi, Joo-Hong
    • Korean Chemical Engineering Research
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    • v.54 no.5
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    • pp.671-677
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    • 2016
  • The impregnated alkali metal (Na, K), and the alkali earth metal (Ca, Mg) activated carbons were produced from the bamboo activated carbon by soaking method of alkali metals and alkali earth metals solution. The carbonization and activation of raw material was conducted at $900^{\circ}C$. The specific surface area and the pore size distribution of the prepared activated carbons were measured. Also, NO and activated carbon reaction were conducted in a thermogravimetric analyzer in order to use for de-NOx agents of the used activated carbon. Carbon-NO reactions were carried out in the nonisothermal condition (the reaction temperature $20{\sim}850^{\circ}C$, NO 1 kPa) and the isothermal condition (the reaction temperature 600, 650, 700, 750, 800, $850^{\circ}C$, NO 0.1~1.8 kPa). As results, the specific volume and the surface area of the impregnated alkali bamboo activated carbons were decreased with increasing amounts of the alkali. In the NO reaction, the reaction rate of the impregnated alkali bamboo activated carbons was promoted to compare with that of the bamboo activated carbon [BA] in the order of BA(Ca)> BA(Na)> BA(K)> BA(Mg) > BA. Measured the reaction orders of NO concentration and the activation energy were 0.76[BA], 0.63[BA(Na)], 0.77[BA(K)], 0.42[BA(Ca)], 0.30 [BA(Mg)], and 82.87 kJ/mol[BA], 37.85 kJ/mol[BA(Na)], 69.98 kJ/mol[BA(K)], 33.43 kJ/mol[BA(Ca)], 88.90 kJ/mol [BA(Mg)], respectively.

Production of Activated Carbon from Bamboo by Gas Activation Method (기상 활성화법에 의한 대나무 활성탄 제조)

  • 조광주;박영철
    • Journal of Energy Engineering
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    • v.13 no.2
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    • pp.166-172
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    • 2004
  • The activated carbon was produced from Sancheong bamboo by steam and carbon dioxide gas activation methods. The carbonization of raw material was conducted at 90$0^{\circ}C$ and gas activation reactions were conducted with respect to various conditions. -activation temperature 750-90$0^{\circ}C$, the flow rate of steam 0.5-2g-$H_2O$/g-char$.$hr, the flow rate of carbon dioxide 5-30$m\ell$-$CO_2$/g-char-min and activation time 1-5 hr. The prepared activated carbons were measured yield, the adsorption capacity of iodine and methylene blue, BET specific surface area and pore size distribution. The adsorption capacity of iodine (680.5-1526.1 mg/g) and methylene blue (18.3-221.5 mg/g) increased with creasing activation temperature and activation time. The adsorption capacity of iodine and methylene blue increased with the activation gas quantity in the range of 0.5-1.5g-$H_2O$/g-charㆍhr, 5-18.9$m\ell$-Co$_2$/g-charㆍmin. But those decreased over those range due to the pore shrinkage. The steam activation method was superior in efficiency to carbon dioxide activation method.

Production and CO2 Adsorption Characteristics of Activated Carbon from Bamboo by CO2 Activation Method (CO2 활성화법에 의한 대나무 활성탄 제조와 CO2 흡착 특성)

  • Bak, Young-Cheol;Cho, Kwang-Ju;Choi, Joo-Hong
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.146-152
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    • 2005
  • The activated carbon was produced from Sancheong bamboo by carbon dioxide gas activation methods. The carbonization of raw material was conducted at $900^{\circ}C$, and $CO_2$ activation reactions were conducted under various conditions: activation temperatures of $750-900^{\circ}C$, flow rates of carbon dioxide $5-30cm^3/g-char{\cdot}min$, and activation time of 2-5 h. The yield, adsorption capacity of iodine and methylene blue, specific surface area and pore size distribution of the prepared activated carbons were measured. The adsorption capacity of iodine (680.8-1450.1 mg/g) and methylene blue (23.5-220 mg/g) increased with increasing activation temperature and activation time. The adsorption capacity of iodine and methylene blue increased with the $CO_2$ gas quantity in the range of $5-18.9cm^3/g-char{\cdot}min$. But those decreased over those range due to the pore shrinkage. The specific volume of the mesopore and macropore of bamboo activated carbon were $0.65-0.91cm^3/g$. Because of this large specific volume, it can be used to the biological activated carbon process. Bamboo activated carbon phisically adsorbed the $CO_2$ of maximum 106 mg/g-A.C in the condition of 90% $CO_2$ and adsorption temperature of $20^{\circ}C$. The $CO_2$ adsorption ability of bamboo activated carbon was not changed in the 5 cyclic test of desorption and adsorption.