• Title/Summary/Keyword: Background gases

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On the Determination Method of Background Aerosol Concentration (에어로졸의 배경농도 산정기법에 관한 연구)

  • Heo, Junghwa;Kim, Sang-Woo;Yoon, Soon-Chang;Kim, Ji-Hyoung;Kim, Man-Hae;Kim, Yumi
    • Atmosphere
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    • v.23 no.4
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    • pp.501-511
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    • 2013
  • In this study, we estimate the background concentration of black carbon (BC) mass concentration measured at Gosan Climate Observatory from January 2008 to December 2011 by applying six methods: (1) Mean and Median (2) Trimmed mean method deployed in Interagency Monitoring of Protected Visual Environments (IMPROVE) network program (hereafter, IMPROVE method), (3) Concentration-frequency distribution analysis method, (4) Advanced Global Atmospheric Gases Experiment (AGAGE) method (hereafter, AGAGE method), (5) Kaufman et al. (2001) method (hereafter, Kaufman method), and (6) Airmass sector analysis. The background concentration of BC mass concentrations is estimated to be about 400~900 ng $m^{-3}$, but each method shows a large difference. The estimated background concentration, in general, is arranged in the order of: mean > IMPROVE method > median > Kaufman method > concentration-frequency distribution analysis method > AGAGE method. The background concentration estimated by the airmass sector analysis is found to be about 550 ng $m^{-3}$ which is lower than those estimated by other methods. When we apply the same analytical period (i.e., 4-day and 6-day) to both AGAGE and Kaufman methods, the estimated background concentrations are quite similar. However, further researches on the development of statistical method for estimating background concentration for various gas-phase and particulate pollutants under different environment are needed.

A Study of Hexane Decomposition using Electron Beam Irradiation under Background Gases(Helium, Nitrogen, Oxygen, Air) (배경가스에 따른 Hexane의 전자빔 제어 연구)

  • Kim, Ki-Joon;Park, Kang-Nam;Kim, Jo-Chun;SunWoo, Young;Son, Youn-Suk;Kim, Ki-Hyung
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.5
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    • pp.724-730
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    • 2006
  • A study on the electron beam(E-Beam) decompositions of volatile organic compounds(VOCs) under background gases(helium, nitrogen, oxygen, air) has been carried out. Hexane selected as aliphatic VOCs was irradiated with electron beam using a batch reactor in the dose range of $0{\sim}10kGy$ and at ambient temperature. The concentrations of Hexane were 140 ppmC, 300 ppmC and 600 ppmC, respectively. Irradiation treatment efficiency of Hexane was evaluated by the GC/FID, GC/MSD, and the by-products were analyzed by $CO/CO_2\;and\;O_3$ analyzers. In different concentration, the maximum degrees of Hexane decomposition at 10 kGy were 96.4%(140 ppmC), 88.3%(300 ppmC), and 49.9%(600 ppmC). It was found that the decomposition efficiency of Hexane was higher than that of toluene at the same conditions(140 ppmC). In addition, the formation of acetone, benzene, 2-hexanone, and 3-hexanone were observed after the treatment of Hexane.

[Retracted]Gas Mask Removal Efficiency of CO, HCl, HCN, and SO2 Gas Produced by Fire ([논문철회]화재용 방독면의 CO, HCl, HCN, SO2 연소생성물 제거효율)

  • Kong, Ha-Sung;Gong, Ye-Som;Kim, Sang-Heon
    • Fire Science and Engineering
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    • v.29 no.4
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    • pp.57-60
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    • 2015
  • The removal efficiencies by elastic fire gas mask of toxic gases CO, HCl, HCN, and $SO_2$ produced by a fire have a key role in saving lives. The elastic fire gas mask comprises a visible window, elastic hood, gas purification canister, and air vent. It does not have hair or neck thongs, which makes it easy to use and put on quickly. This research examined the removal efficiency of toxic gases by such a mask. The removal efficiencies for CO with a background concentration of 2505.0 ppm were 99.99 and 99.98% after 3.5 and 8.5 min, respectively. The residual CO concentration was drastically increased after 8.5 min. The removal efficiencies for HCl, HCN, and $SO_2$ with background concentrations of 1003.0, 399.0, and 100.3 ppm, respectively, were 100% after 20 min.

Passive Remote Chemical Detection of SF6 Clouds in the Atmosphere by FTIR (수동형 FTIR 원격화학 탐지기를 이용한 SF6 오염운의 실시간 탐지)

  • Chong, Eugene;Park, Byeonghwang;Kim, Ju Hyun
    • Journal of the Korea Institute of Military Science and Technology
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    • v.17 no.1
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    • pp.8-14
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    • 2014
  • Brightness temperature spectra acquired from FTIR(Fourier Transform Infrared)-SCADS (Standoff Chemical Agent Detection System) could be available for detection and identification of the chemical agents and pollutants from different background. IR spectrum range of 770 to 1350 $cm^{-1}$ is corresponding to "atmospheric window". A 2-dimensional(2D) brightness temperature spectrum was drawn from combining each data point through automatic continuous scanning of FTIR along with altitude and azimuth. At higher altitude, temperature of background was decreased but scattering effect of atmospheric gases was increased. Increase in temperature difference between background and blackbody in SCADS at higher temperature causes to increases in peak intensity of $SF_6$. This approach shows us a possibility that 2D visual information is acquired from scanning data with a single FTIR-SCADS.

Gas ebullition associated with biological processes in radioactively contaminated reservoirs could lead to airborne radioactive contamination

  • E.A. Pryakhin;Yu.G. Mokrov;A.V. Trapeznikov;N.I. Atamanyuk;S.S. Andreyev;A.A. Peretykin;K. Yu. Mokrov;M.A. Semenov;A.V. Akleyev
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.4204-4212
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    • 2023
  • Background: Storage reservoirs of radioactive waste could be the source of atmospheric pollution due to the efflux of aqueous aerosol from their water areas. The main mechanism of formation of aqueous aerosols is the collapse of gas bubbles at the water surface. In this paper, we discuss the potential influence of biological factors on gas ebullition in the water areas of the radioactively contaminated industrial reservoirs R-9 (Lake Karachay) and R-4 (Metlinsky pond) of the Mayak PA. The emission of the released non-dissolved gases captured with gas traps in reservoir R-9 was (88-290) ml/m2 per day (2015) and in reservoir R-4 (270-460) ml/m2 per day (2016). The analysis of gas composition in reservoir R-4 (60% methane, 35% nitrogen, 2.4% oxygen, 1.5% carbon dioxide) confirms their biological origin. It is associated with the processes of organic matter destruction in bottom sediments. The major source of organic matter in bottom sediments is the dying phytoplankton developing in these reservoirs. Conclusion: The obtained results form the basis to set a task to quantify the relationship between the phytoplankton development, gases ebullition and radioactive atmosphere contamination.

Effect of Weathering of Bottom Ash on Mitigation of Green House Gases Emission from Upland Soil (밭토양에서 저회의 풍화가 온실가스 배출 저감에 미치는 영향)

  • Heo, Do Young;Hong, Chang Oh
    • Korean Journal of Environmental Agriculture
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    • v.38 no.4
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    • pp.245-253
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    • 2019
  • BACKGROUND: Weathering of bottom ash (BA) might induce change of its surface texture and pH and affect physical and chemical properties of soil associated with greenhouse gas emission, when it is applied to the arable soil. This study was conducted to determine effect of weathering of BA in mitigating emission of greenhouse gases from upland soil. METHODS AND RESULTS: In a field experiment, methane (CH4), carbon dioxide (CO2), and nitrous oxide (N2O) emitted from the soil was periodically monitored using closed chamber. Three month-weathered BA and non-weathered BA were applied to an upland soil at the rates of 0, 200 Mg ha-1. Maize (Zea mays L.) was grown from July 1st to Oct 8th in 2018. Both BAs did not affect cumulative CH4 emission. Cumulative CO2 emission were 23.1, 19.8, and 18.8 Mg/ha/100days and cumulative N2O emission were 35.8, 20.9, and 17.7 kg/ha/100days for the control, non-weathered BA, and weathered BA, respectively. Weathering of BA did not decrease emission of greenhouse gases significantly, compared to the weathered BA in this study. In addition, both BAs did not decrease biomass yields of maize. CONCLUSION: BA might be a good soil amendment to mitigate emissions of CO2 and N2O from arable soil without adverse effect on crop productivity.

Influence of Manufacturing Conditions for the Life Time of the Boron-Doped Diamond Electrode in Wastewater Treatment (폐수처리용 붕소 도핑 다이아몬드 전극의 수명에 미치는 제조공정 변수의 영향)

  • Choi, Yong-Sun;Lee, Young-Ki;Kim, Jung-Yuel;Kim, Kyeong-Min;Lee, You-Kee
    • Korean Journal of Materials Research
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    • v.27 no.3
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    • pp.137-143
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    • 2017
  • Boron-doped diamond (BDD) electrode has an extremely wide potential window in aqueous and non-aqueous electrolytes, very low and stable background current and high resistance to surface fouling due to weak adsorption. These features endow the BDD electrode with potentially wide electrochemical applications, in such areas as wastewater treatment, electrosynthesis and electrochemical sensors. In this study, the characteristics of the BDD electrode were examined by scanning electron microscopy (SEM) and evaluated by accelerated life test. The effects of manufacturing conditions on the BDD electrode were determined and remedies for negative effects were noted in order to improve the electrode lifetime in wastewater treatment. The lifetime of the BDD electrode was influenced by manufacturing conditions, such as surface roughness, seeding method and rate of introduction of gases into the reaction chamber. The results of this study showed that BDD electrodes manufactured using sanding media of different sizes resulted in the most effective electrode lifetime when the particle size of alumina used was from $75{\sim}106{\mu}m$ (#150). Ultrasonic treatment was found to be more effective than polishing treatment in the test of seeding processes. In addition to this, BDD electrodes manufactured by introducing gases at different rates resulted in the most effective electrode lifetime when the introduced gas had a composition of hydrogen gas 94.5 vol.% carbon source gas 1.6 vol.% and boron source gas 3.9 vol.%.

Effect of Rice Straw on Methane Production Potential of Cow Manure (우분과 볏짚의 병합 혐기성 소화를 통한 메탄 생산에 대한 고찰)

  • Park, So Yun;Jang, Jeong A;Zhao, Xin;Hong, Jin-Kyung;Jho, Eun Hea
    • Korean Journal of Environmental Agriculture
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    • v.41 no.2
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    • pp.71-81
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    • 2022
  • BACKGROUND: Animal manures are one of the biggest sources of greenhouse gases and improper manage-ment of animal wastes contributes to the increasing greenhouse gases in the atmosphere. Con-verting greenhouse gases generated from animal manures to energy is one way of contributing to the net-zero carbon emissions. METHODS AND RESULTS: The potential for methane production from cow manure (CM) was studied by measuring the methane yield using the biochemical methane potential (BMP) test. In particular, the effect of co-digestion using rice straw (RM) on the methane production was studied. The methane yields from the co-digestion of CM and RS were statistically similar to that from the mono-digestion of CM or RS. But there was a synergy effect at the CM:RS ratio of 1:2 and 1:1. This can be attributed to the increased C/N ratio. The changed microbial community structure with the addition of substrates (CM, RS) probably led to the increase in the methane produc-tion. CONCLUSION(S): The methane production potential of the particular CM used in this study was not improved by the addition of RS as a co-substrate. The addition of substrates to the anaerobic sludge promoted the increase in the microbial species having synergetic relationship with methano-gens, and this can partially explain the increase in the methane production with the addition of substrates. Overall, there are needs for further studies to improve the methane yield from CM.

Vocal Fold Paralysis Following General Anesthesia with Endotracheal Intubation (기관내 삽관에 의한 전신 마취 후 발생된 성대 마비)

  • 정성민;이재연;장주애;구태완
    • Journal of the Korean Society of Laryngology, Phoniatrics and Logopedics
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    • v.10 no.2
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    • pp.130-134
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    • 1999
  • Background and Objectives : Vocal fold paralysis is an unusual complication following endotracheal intubation. We experienced five cases and analyzed their causes and preventions. Materials and Methods : We reviewed 5 cases of vocal fold paralysis following general anesthesia with endotracheal intubation at Ewha Womans University Hospital from September 1997 to May 1999 retrospectively. Results : Four cases were unilateral vocal fold paralysis(3 cases were left side, 1 case was right side) and a case was bilateral vocal fold paralysis. Conclusion : Vocal fold paralysis following endotracheal intubation is the result of recurrent laryngeal nerve damage. This damage can occur as the result of compressing the anterior branch of recurrent laryngeal nerve between an inflated endotracheal tube cuff and thyroid cartilage. Prevention of this complication lies in eliminating the use of endotracheal tubes with cuff inflated unevenly, desisting from the practice of deliberately placing the cuff within the larynx, and filling the cuff with a sample of the inspired mixture of gases.

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On Using the Eddy Covariance Method to Study the Interaction between Agro-Forest Ecosystems and the Atmosphere (농림생태계와 대기간의 상호 작용 연구를 위한 에디 공분산 방법의 사용에 관하여)

  • Choi Taejin;Kim Joon;Yun Jin-il
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.1 no.1
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    • pp.60-71
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    • 1999
  • The micrometeorological tower flux network is the cornerstone of the global terrestrial vegetation monitoring. The eddy covariance technique used for tower fluxes is derived from the conservation of mass and is most applicable for steady-state conditions over flat, extended, and uniform vegetation. This technique allows us to obtain surface fluxes of energy budget components, greenhouse and trace gases, and other pollutants. The quality-controlled flux data are invaluable to validate various models with temporal scales ranging from minutes to years and spatial scales ranging from a few meters to hundreds of kilometers. In this paper, we review the theoretical background of this important eddy covariance technique, examine the measurement criteria and corrections, and finally suggest some measurement strategies that may facilitate coordinated flux measurements among different disciplines and provide a strong infrastructure for the global flux network.

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