• Title/Summary/Keyword: BaTiO$_3$

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Application of Nano-TDR Health Monitoring System in Civil Engineering (나노-TDR센서를 이용한 토목구조물 모니터링 시스템)

  • Han, Heui-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.5 s.57
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    • pp.93-100
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    • 2009
  • This study presents reasonable relationships to estimate the deformation based on beam mechanism analysis and TDR(Time Domain Reflectometry) data. To declar the length points of co-axial cable installed in civil structure, Nano material ($BaTiO_3$ powders and silver mixture) is used on co-axial cables. From the laboratory test, nano material could make the correct information about attached cable points on beam, and TDR sensor system and Fourier series (data filter) found out the deformation of beam. Therefore it is concluded that the correct deformed information of beam were acquired by Nano-TDR and Fourier filter, they are much more effective to apply at health monitoring system in civil structure compared to conventional TDR or Fiber Optic Sensor (FOS) systems.

Effects of Oxygen Vacancies on the Electrical Properties of High-Dielectric (Ba,Sr)TiO$_3$Thin Films (산소 결핍이 고유전 BST 박막에 미치는 영향)

  • 김일중;이희철
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.4
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    • pp.63-69
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    • 1999
  • The electrical properties of rf-magnetron sputtered $Ba_{0.5}Sr_{0.3}TiO_3$ (BST) capacitors were investigated by varying annealing temperature and atmosphere of the rapid thermal annealing (RTA). The electrical properties of Pt/BST/Pt capacitors were found to strongly depend on the RTA condition. It seems that the dependence of the electrical properties of the Pt/BST/Pt capacitors on the RTA condition is related to the oxygen vacancies in BST thin films. In order to clarify the relation between the oxygen vacancies and the electrical properties of Pt/BST/Pt capacitors, we have examined the two different annealing methods. One annealing method was performed in $O_2$ gas and the other was done in $O_2$-plasma at the same condition of 450$^{\circ}C$, 20 mtorr. It was found that the leakage current densities of $O_2$-plasma annealed capacitor were much lower than those of $O_2$ annealed capacitor. The dielectric constants of $O_2$ annealed capacitor decreased about 14% comparing with those of as-deposited. In contrast, there was no decrease in the dielectric constant of $O_2$-plasma annealed. These results indicate that $O_2$-plasma annealing is very effective in compensation the oxygen vacancies in BST thin films. It can be also concluded that the oxygen vacancies greatly affect the electrical properties of Pt/BST/Pt capacitors.

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Fast Abnormal Grain Growth Behavior and Electric Properties of Lead-Free Piezoelectric (K,Na)NbO3-Ba(Cu,Nb)O3 Grains through Transient Liquid Phase (과 액상 형성에 의한 비납계 압전 (Na,K)NbO3-Ba(Cu,Nb)O3 결정립의 비정상 성장 거동 및 전기적 특성)

  • Lim, Ji-Ho;Lee, Ju-Seung;Lee, SeungHee;Jung, Han-Bo;Park, Chun-kil;Ahn, Cheol-Woo;Yoo, Il-Ryeol;Cho, Kyung-Hoon;Jeong, Dae-Yong
    • Korean Journal of Materials Research
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    • v.29 no.4
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    • pp.205-210
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    • 2019
  • $Pb(Zr,Ti)O_3$ (PZT) is used for the various piezoelectric devices owing to its high piezoelectric properties. However, lead (Pb), which is contained in PZT, causes various environment contaminations. $(K,Na)NbO_3$ (NKN) is the most well-known candidate for a lead-free composition to replace PZT. A single crystal has excellent piezoelectric-properties and its properties can be changed by changing the orientation direction. It is hard to fabricate a NKN single crystal due to the sodium and potassium. Thus, $(Na,K)NbO_3-Ba(Cu,Nb)O_3$ (NKN-BCuN) is chosen to fabricate the single crystal with relative ease. NKN-BCuN pellets consist of two parts, yellow single crystals and gray poly-crystals that contain copper. The area that has a large amount of copper particles may melt at low temperature but not the other areas. The liquid phase may be responsible for the abnormal grain growth in NKN-BCuN ceramics. The dielectric constant and tan ${\delta}$ are measured to be 684 and 0.036 at 1 kHz in NKN-BCuN, respectively. The coercive field and remnant polarization are 14 kV/cm and $20{\mu}C/cm^2$.

Microwave Characteristics of Barium Titanate for Frequency Sensor and Temperature Sensor (고주파특성 측정을 통한 barium titanate의 주파수센서 및 온도센서 연구)

  • Kim, J.O.;Han, M.H.
    • Journal of Sensor Science and Technology
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    • v.5 no.1
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    • pp.9-14
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    • 1996
  • The effect on the microwave properties was investigated for the barium titanate doped with impurity of $WO_{3}$ 0.230 mole% produced by conventional solid state reaction method. Microwave resistance, reactance and impedance of the barium titanate were measured with 2-port s-parameter method by using network analyzer, in the range of room temperature to $160^{\circ}C$ and of frequency 300 kHz to 300 MHz. And possibility of frequency sensor and temperature sensor was estimated with barium titanate doped with $WO_{3}$.

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Dielectric and Pyroelectric Properties of Dy-doped BSCT Thick Films by Screen-printing Method

  • Noh, Hyun-Ji;Lee, Sung-Gap;Nam, Sung-Pill
    • Journal of Electrical Engineering and Technology
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    • v.4 no.4
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    • pp.527-530
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    • 2009
  • $(Ba_{0.57}Sr_{0.33}Ca_{0.10})TiO_3$(=BSCT) powders, prepared by the sol-gel method, were doped using $MnCO_3$ as the acceptor and $Dy_2O_3$ as the donor. This powder was mixed with an organic vehicle. BSCT thick films were fabricated by the screen-printing techniques on the alumina substrate. The structural and dielectric properties of BSCT thick films were investigated with variation of the $Dy_2O_3$ amount. As a result of the differential thermal analysis (DTA), the exothermic peak was observed at around $670^{\circ}C$ due to the formation of the polycrystalline perovskite phase. All the BSCT thick films showed the XRD patterns of a typical polycrystalline perovskite structure. The average grain size of BSCT thick films decreased with an increasing amount of $Dy_2O_3$. The relative dielectric constant and dielectric loss of the BSCT thick film doped $Dy_2O_3$ 0.1mol% were 4637.4 and 1.6% at 1kHz, respectively.

A 3D finite element static and free vibration analysis of magneto-electro-elastic beam

  • Vinyas., M;Kattimani, S.C.
    • Coupled systems mechanics
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    • v.6 no.4
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    • pp.465-485
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    • 2017
  • In this paper, free vibration and static response of magneto-electro-elastic (MEE) beams has been investigated. To this end, a 3D finite element formulation has been derived by minimization the total potential energy and linear constitutive equation. The coupling between elastic, electric and magnetic fields can have a significant influence on the stiffness and in turn on the static behaviour of MEE beam. Further, different Barium Titanate ($BaTiO_3$) and Cobalt Ferric oxide ($CoFe_2O_4$) volume fractions results in indifferent coupled response. Therefore, through the numerical examples the influence of volume fractions and boundary conditions on the natural frequencies of MEE beam is illustrated. The study is extended to evaluate the static response of MEE beam under various forms of mechanical loading. It is seen from the numerical evaluation that the volume fractions, loading and boundary conditions have a significant effect on the structural behaviour of MEE structures. The observations made here may serve as benchmark solutions in the optimum design of MEE structures.

Dielectric and Structural of BST Thin Films with Cr doped prepared by Sol-gel method for Tunable application (Tunable 소자 응용을 위한 Sol-gel 법으로 제작된 BST 박막의 Cr 첨가에 따른 구조적, 유전적 특성)

  • Kim, Seung-Bum;Kim, Kyoung-Tae;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.623-626
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    • 2004
  • [ $Ba_{0.6}Sr_{0.4}TiO_3$ ] (BST) dielectric thin films doped by Cr were prepared using an alkoxide-based sol-gel method on the Pt/Ti/SiO2/Si substrate. Atomic force microscopy and x-ray diffraction analysis showed that increasing the Cr doping ratio causes increased grain size while the surface remains smooth and crack-free. It was also found that compared with undoped films the increase of Cr content in BST improves the dielectric constant and the leakage-current characteristics. The figure of merit reached the maximum value of 72.3 at the 5 mol % of Cr doping. This composition showed the dielectric constant of 426, the loss factor of 0.0065, tenability of 47.7%, and leakage-current density (at the electric field of 100 kV/cm) of $5.31{\times}10^{-8}A/cm^2$. The results show that the Cr-doped BST thin films are prospective candidates for applications in tunable devices.

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The Structural and Electrical Properties of the BST Thin Film Prepared by Sol-Gel method. (Sol-Gel법으로 제조한 BST 박막의 구조 및 전기적 특성)

  • Kim, Kyoung-Duk;Chung, Jang-Ho;Bae, Seon-Gi;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 1997.11a
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    • pp.291-293
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    • 1997
  • In this study, Sol-Gel derived $(Ba_{0.7}Sr_{0.3})TiO_3$ thin films were fabricated and investigated. The stock solution was synthesized and spin-coated on Pt/Ti/$SiO_2$/Si substrate at 4000(rpm] and then, annealed at $650{\sim}750[^{\circ}C]$. Crystallization condition, microstructural properties and interfacial structure were observed by XRD, AFM, SEM and TEM. It was found that the BST thin films were completely crystallized at 750[$^{\circ}C$] and showed nano-sized grains. The dielectric constant and loss of the BST thin films were 220, 0.01 at 1[kHz] respectively. Increasing the temperature, the dielectric constant and loss characteristics were not varied widely. At the applied voltage of 1.5[V], the leakage current density was under the $10^{-9}[A/cm^2]$.

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Alteration of Physical Properties of Nanoparticle Embedded liquid Crystal Causing the Enhancement of the Performance of LCDs

  • Kobayashi, Shunsuke;Kineri, Tohru;Takatoh, Kohki;Akimoto, Mitsuhiro;Hoshi, Hajime;Nishida, Naoto;Toshima, Naoki;Sano, Satoru
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1473-1476
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    • 2008
  • Doping the nanoparticles of Pd, p-$BaTiO_3$, $SiO_2$ and MgO into LCs alters their physical properties such as $K_{ii}$, $\Delta\varepsilon$, ${\Delta}n$, $\gamma_1$ and $T_{NI}$. Except for $K_{33}$, all these parameters decreases and thus bring the reduction of operating voltage and/or response times.

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Characterization and Potent Application of Pleurotus floridanus Trypsin Inhibitor (PfTI)

  • Pannippara, Manzur Ali;Kesav, Sapna;Raghavan, Rekha Mol Kollakal Naduvil;Mathew, Abraham;Bhat, Sarita Ganapathy;Kozhiyil, Elyas Kothanan
    • Natural Product Sciences
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    • v.26 no.3
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    • pp.207-213
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    • 2020
  • Characterization and in vitro inhibition studies of protease inhibitor from the mushroom Pleurotus floridanus (PfTI) towards the pest Papilio demoleus is studied. The addition of 1 mM Mn2+, Na2+, Ba2+ and Ni 2+ enhanced the PfTI activity. The ICP-atomic emission spectrum showed the presence of Ca2+, Mg2+ and Zn2+ in the PfTI. Surfactants SDS and CTAB at a concentration of 1% reduced the PfTI activity whereas, the nonionic detergents Triton X and Tween 80 increased the activity. The inhibitory activity gradually decreased with increase in concentration of DMSO and H2O2. The activity was increased by dithiothreitol up to a concentration of 80 μM and inactivated at 140 μM. The activity of PMSF modified PfTI was drastically reduced to 0.234 U/mL at 4 mM concentration and similar results were obtained for modification of cysteine by N-Ethylmaleimide at slightly higher concentrations. The complex of trypsin and PfTI showed complete loss in fluorescence intensity at 343 nm compared with control. In vitro inhibition studies of PfTI with midgut proteases isolated from citrus pest P. demoleus with protease activity of 1.236 U was decreased to 0.613 U by 50 μL (0.1 mg/mL) of the inhibitor. Inhibitor was stable up to 0.04 M concentration of HCl.