• Title/Summary/Keyword: BTX

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Study on Control Efficiency of Fully Thermally Coupled Distillation Column for BTX Separation (BTX 분리용 열복합 증류탑의 제어성능에 관한 연구)

  • Kim, Mi Hee;Park, Chang Won;Lee, Ju-Yeong;Kim, Young Han;Hwang, Kyu Suk
    • Korean Chemical Engineering Research
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    • v.48 no.6
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    • pp.725-730
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    • 2010
  • The fully thermally coupled distillation columns(FTCDC) are thermodynamically more efficient than conventional columns. Despite these advantages, industry has been reluctant to use FTCDC. This can be largely attributed to the lack of established design procedures and column operability. In this study, the $3{\times}3$control structure was applied to control the FTCDC which was simulated using Aspen HYSYS on the possible control structure of 4 kinds and control performance was investigated. As the result of dynamic simulations, one of the proposed structures had better controllability of product compositions and control efficiency was evaluated.

Taxonomical Classification of Bugog Series (부곡통의 분류)

  • Song, Kwan-Cheol;Hyun, Byung-Geun;Sonn, Yeon-Kyu;Hong, Suk-Young;Kim, Yi-Hyun;Choe, Eun-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.42 no.6
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    • pp.472-477
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    • 2009
  • This study was conducted to reclassify Bugog series based on the second edition of Soil Taxonomy : A Basic System of Soil Classification for Making and Interpreting Soil Surveys. Morphological properties of typifying pedon of Bugog series were investigated and physico-chemical properties were analyzed according to Soil Survey Laboratory Methods Manual. The typifying pedon of Bugog series has strong brown (7.5YR 4/6) loam Ap horizon (0~22 cm), brown (7.5YR 4/4) clay loam BAt horizon (22~41 cm), strong brown (7.5YR 4/6) silty clay loam Bt1 horizon (41~59 cm), strong brown (7.5YR 4/6) silty clay loam Bt2 horizon (59~78 cm), brown (7.5YR 4/4) silty clay loam Btx1 horizon(78~90 cm), and brown (7.5YR 4/4) Btx2 horizon(90~160 cm). That occurs on swale foot slope in area of mainly granite gneiss, granite, and schist rock materials. The typifying pedon has an argillic horizon from a depth of 22 to more than 160 cm and a base saturation (sum of cations) of less than 35% at 75 cm below the upper boundary of the fragipan. That can be classified as Ultisol, not as Alfisol. The pedon has udic soil moisture regime, and can be classified as Udult. That has a fragipan with an upper boundary within 100 cm of the mineral soil surface, and keys out as Fragiudult. Also that meets the requirements of Typic Fragiudult. That has 18% to 35% clay at the particle-size control section, and has mesic soil temperature regime. Bugog series can be classified as fine silty, mixed, mesic family of Typic Fragiudults, not as fine loamy, mixed, mesic family of Typic Fragiudalfs.

Taxonomical Classification of Yongdang Series (용당통의 분류)

  • Song, Kwan-Cheol;Hyun, Byung-Geun;Moon, Kyung-Hwan;Jeon, Seung-Jong;Lim, Han-Cheol
    • Korean Journal of Soil Science and Fertilizer
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    • v.42 no.5
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    • pp.393-398
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    • 2009
  • This study was conducted to reclassify Yongdang series based on the second edition of Soil Taxonomy : A Basic System of Soil Classification for Making and Interpreting Soil Surveys. Morphological properties of typifying pedon of Yongdang series were investigated and physico-chemical properties were analyzed according to Soil Survey Laboratory Methods Manual. The typifying pedon of Yongdang series has dark reddish brown (5YR 2/3) silt loam Ap horizon (0~14 cm), dark brown (7.5YR 2/3) silt loam BA horizon (14~32 cm), dark brown (7.5YR 2/3) clay loam Bt horizon (32~57 cm), dark yellowish brown (10YR 4/6) silty clay loam Btx1 horizon (57~110 cm), and dark yellowish brown (10YR 4/6) silty clay loam Btx2 horizon(more than 110 cm). That occurs on gently sloping lava plain and is derived from baslt materials. The typifying pedon has an argillic horizon from a depth of 32 to more than 110 cm and a fragipan from a depth of 57 to more than 110 cm. That has a base saturation (sum of cations) of 35% or more at 75 cm below the upper boundary of the fragipan. That can be classified as Alfisol, not as Inceptisol. The typifying pedon has udic soil moisture regime, and can be classified as Udalf. That has a fragipan with an upper boundary within 100 cm of the mineral soil surface, and keys out as Fragiudalf. Also that meets the requirements of Typic Fragiudalf. That has 18% to 35% clay at the particle-size control section, and has thermic soil temperature regime. Yongdang series can be classified as fine loamy, mixed, thermic family of Typic Fragiudalfs, not as fine loamy, mixed, thermic family of Aquic Eutrudepts.

Simulation of Benzene-Toluene-Xylene Plant (BTX제조공정의 모사연구)

  • 정해동
    • Journal of the Korea Society for Simulation
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    • v.4 no.1
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    • pp.121-130
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    • 1995
  • This paper deals with modeling and simulation of an industrial benzene-toluene-xylene plant. Because the fractionation unit of benzene-toluene-xylene plant has a narrow range of boiling point and doesn't have any sidecut and side reboiler, we employed boiling point estimation method in the modeling and simulation of the plant. Soave-Redlich-Kwong equation was used in the computation of thermodynamical properties. We solved resulting nonlinear equations by using Newton-Raphson method which is known to show fast convergence. Results of simulation showed good agreement with actual plant operation data.

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Development of naphtha reforming process simulator (나프타 개질 공정 전문 모사기의 개발)

  • 최영호;권영운;윤인섭
    • 제어로봇시스템학회:학술대회논문집
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    • 1991.10a
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    • pp.87-92
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    • 1991
  • A naphtha reforming process treats the feed naphtha for the production of BTX and high octane gasoline. In this paper, the development of NAFOS (Naphtha Reformer Steady-State Simulator), which is the efficient tool for the wide range of reforming process studies, is presented. NAFOS system is based on the sequential modular approach and composed of unit computation routines, physical properties data base, numerical routines, flowsheet convergence routine and user interfaces for input-output control. The developed NAFOS system has been tested by computation of the UOP Platforrming process. Simulation results of NAFOS corresponded with that of established general purpose simulator (ASPEN PLUS), and faster for the same simulation case.

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Complete Oxidation of Volatile Organic Compounds(BTX) over the Supported Transition Metal Catalysts (전이금속 담지 촉매상에서 휘발성유기화합물(BTX)의 완전산화)

  • Kim, Sang-Chai;Seo, Seong-Gyu;Yu, Eui-Yeon
    • Clean Technology
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    • v.6 no.1
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    • pp.17-25
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    • 2000
  • Catalytic oxidation of volatile organic compounds(benzene, toluene, xylene) over transition metals/ALO-6 catalysts was investigated in a fixed bed flow reactor system at atmospheric pressure. The orders of catalytic activities for the complete oxidation of toluene were Cu>Mn>Fe>V>Mo>Co>Ni>Zn for 15% transition metals/ALO-6 catalyst system. Increasing the calcination temperature resulted in decreasing the specific surface areas of catalyst, subsequently the catalytic activity. The loading of Cu on ALO-6 had a great effect on the catalytic activity and 5% Cu/ALO-6 catalyst showed higher catalytic activity, which may be contributed to the uniformly distributed active sites. Benzene, toluene and xylene were completely oxidized to carbon dioxide over 5% Cu/ALO-6 catalyst at over $380^{\circ}C$ and 4.5 g-cat.hr./g-mole. The orders of the kinds of reactants for catalytic activity over 5% Cu/ALO-6 were toluene>xylene>benzene. As the concentration of reactant increased, the catalytic activity decreased due to self-poison of reactant.

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Risk Analysis of Transporting Hazardous Substances in Harbor Using Modeling Program (항만에서 위험물 운송 중 유해화학물질 누출 위험성에 관한 연구)

  • Yoon, Sukyoung;Yun, Jayeon;Han, Jiyun;Jung, Seungho
    • Journal of Ocean Engineering and Technology
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    • v.32 no.4
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    • pp.272-278
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    • 2018
  • Recently, the use of hazardous chemicals has been continuously increasing. Therefore, the international trade volume is growing and chemical accidents have increased. Nowadays, the safety awareness of the public has increased. As a result, the management and supervision of hazardous chemicals have been strengthened. However, the port policy of Korea has focused on increasing the volume of cargo through facility development. Thus, the port management of hazardous chemicals has been relatively neglected. For national economic growth and society, the port management of hazardous chemicals should be considered to efficiently ensure safety and economic growth. Therefore, this study assumed scenarios where hazardous materials were moved in a dangerous container, not only on appropriate wharfs but also in ports that were close to a big city. The BTX substances were selected among the toxic chemicals with large import and export volumes, and the risk distance and damage effects were predicted using various risk assessment programs. It is expected that this could be used to improve a port safety management system and could be utilized to determine the safety distance in case of an accident.

Transduced PEP-1-FK506BP ameliorates corneal injury in Botulinum toxin A-induced dry eye mouse model

  • Kim, Dae Won;Lee, Sung Ho;Ku, Sae Kwang;Cho, Soo Hyun;Cho, Sung-Woo;Yoon, Ga Hyeon;Hwang, Hyun Sook;Park, Jinseu;Eum, Won Sik;Kwon, Oh-Shin;Choi, Soo Young
    • BMB Reports
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    • v.46 no.2
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    • pp.124-129
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    • 2013
  • FK506 binding protein 12 (FK506BP) belongs to a family of immunophilins, and is involved in multiple biological processes. However, the function of FK506BP in corneal disease remains unclear. In this study, we examined the protective effects on dry eye disease in a Botulinum toxin A (BTX-A) induced mouse model, using a cell-permeable PEP-1-FK506BP protein. PEP-1-FK506BP efficiently transduced into human corneal epithelial cells in a time- and dose-dependent manner, and remained stable in the cells for 48 h. In addition, we demonstrated that topical application of PEP-1-FK506BP was transduced into mouse cornea and conjunctiva by immunohistochemistry. Furthermore, topical application of PEP-1-FK506BP to BTX-A-induced mouse model markedly inhibited expression levels of pro-inflammatory cytokines such as interleukin-$1{\beta}$ (IL-$1{\beta}$), tumor necrosis factor-${\alpha}$ (TNF-${\alpha}$) and macrophage inhibitory factor (MIF) in corneal and conjunctival epithelium. These results suggest PEP-1-FK506BP as a potential therapeutic agent for dry eye diseases.

The Aspect of Voice Characteristics Change after Botulinum Toxin-A Injection in Patients with Adductor Spasmodic Dysphonia according to Vocal Tremor (음성진전 유무에 따른 내전형 연축성 발성장애의 보툴리눔 독소-A 주입 후 음성 특성 변화 양상)

  • Ko, Hyeju;Choi, Hong-Shik;Lim, Sung-Eun;Choi, Yaelin
    • Phonetics and Speech Sciences
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    • v.4 no.4
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    • pp.95-107
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    • 2012
  • As BTX-A, which has been known to be the most effective treatment for ADSD, is not effective in treating vocal tremors, voice assessment must be employed to perform differential diagnosis of SD and vocal tremor in an accurate fashion. In this study, the characteristics of vocal changes after botulinum toxin injection were compared by analyzing the voice characteristics resulting from the presence of vocal tremors using objective analysis devices, with the aim of helping to provide prognoses and to determine remedial effects in clinical cases comprising patients with adductor spasmodic dysphonia accompanied by voice tremors. Respiratory function tests, aerodynamic analysis, electroglottography (EGG), acoustic analysis, auditory perception tests, and K-VHI had been conducted at intervals of four, eight, and twelve weeks before and after injection, targeting a group of 17 ADSD female patients (a ADSD group of four with vocal tremor and a ADSD group of 13 without voice tremor). For average FVC and FEV1, the T group showed statistically significant low averages compared with the NT group, whereas the T group showed statistically significant high average ATRI compared with the NT group. In addition, the T group showed a statistically significant Fatr, lower than that of the NT group. For the ADSD group of patients with voice tremor, their vocal tremor remained unchanged despite noticeable decrease in wringing voices. In other words, as the vocal tremor and wringing voices are two distinctive features, there is a need for the two features to be targeted separately for differential diagnosis.