• Journal of Korean Society on Water Environment
• /
• v.35 no.4
• /
• pp.362-369
• /
• 2019

In this study, biodegradation efficiency improvement of mixed sludge for the anaerobic digestion process in wastewater treatment plant was investigated. In order to release the organic material contained in the sludge cell and promote the hydrolysis step, mixed sludge of 7% TS (Total Solids) was physically shear-treated at a shear strength of 1,000 ~ 4,000 rpm and a maximum of 120 mins. As a result of the comparison between mixed sludge before and after the treatment, the concentration of $SCOD_{Cr}$(Soluble Chemical Oxygen Demand-chromium method) was increased through the conversion of granular organic matter into dissolved organic matter as shear strength and treatment time increases. The solubilization efficiency increased rapidly after 30 min of solubilization application time, and they were 11.23 %, 20.10 %, 22.52 % and 25.43% at 120 min for each shear strength conditions, respectively. Additionally, the BMP(Biochemical Methane Potential) test was conducted with the optimized samples to determine the increase of methane production by the shear pre-treatment. Consequently, methane production of each samples were 0.275, 0.310, 0.323 and $0.335m^3/kg\;VS_{add}$, which indicates that methane production was increased to a maximum of 21.28% compared to the control without the solubilization process ($0.262m^3/kg\;VS_{add}$). As a result, the physical shear-treatment is a promising process for sewage sludge pre-treatment to reduce the organic waste and increase the energy production.

• Korean Journal of Soil Science and Fertilizer
• /
• v.45 no.2
• /
• pp.156-161
• /
• 2012

Marine biomass is considered an important substrate for anaerobic digestion to recovery energy i.e. methane. Nevertheless, marine biomass has attracted little attention by researchers compared to terrestrial feedstock for anaerobic digestion. In this study, biochemical methane potential (BMP) test was used to evaluate generation of renewable energy from starfish. A cumulative biogas yield of $748{\pm}67mL\;g^{-1}VS^{-1}$ was obtained after 60 days of digestion. The cumulative methane yield of $486{\pm}28mL\;CH_4\;g^{-1}VS^{-1}$ was obtained after 60 days of digestion. The methane content of the biogas was approximately 70%. The calculated data applying the modified Gompertz equation for the cumulative $CH_4$ production showed good correlation with the experimental result obtained from this batch study. Since the result obtained from this study is comparable to results with other substrates, marine biomass can be co-digested with food waste or swine wastewater to produce $CH_4$ gas that will help to reduce the gap in global energy demand.

• Korean Journal of Soil Science and Fertilizer
• /
• v.48 no.6
• /
• pp.697-704
• /
• 2015

This study was carried out to assess bioenergy conversion efficiency by biogas and solid fuel production in the cattle feedlot manure discharged from beef cattle barn. Feedlot manure was sampled from the cattle farmhouse located in Yong-in, Gyeonggi during the mid-fattening stage, periodically. The chemical characteristics, BMP (Biochemical methane potential) and HV (Heating values) of feedlot cattle manures were analyzed. Total solid contents of cattle feedlot manure were in the range of 29.98~44.28%, and volatile solid contents were in the range of 23.53~24.47%. In the anaerobic digestion of cattle feedlot manure, the methane production potential has increased from 0.141 to $0.187Nm^3kg^{-1}-VS_{added}$. The methane production of fresh cattle feedlot manure showed the range $0.141{\sim}0.187Nm^3kg^{-1}$-Manure (average $0.047Nm^3kg^{-1}$-Manure), the LHVs (lower heating values) of the produced methane were in the range of $316{\sim}560kcalkg^{-1}$-Manure (average $400kcalkg^{-1}$-Manure). In the direct combustion of fresh cattle feedlot manure, the LHVs were measured in the range of $747{\sim}1,271kcalkg^{-1}$-Manure (average $916kcalkg^{-1}$-Manure), and LHVs of solid fuel which have the water content of 20% were in the range of $2,694{\sim}2,876kcalkg^{-1}$-Manure (average $2,791kcalkg^{-1}$-Manure). Then, the drying energy of average $443kcalkg^{-1}$-Manure was consumed in the production of solid fuel which has a water content of 20%. Therefore, the direct combustion of cattle feedlot manure showed about 2.3 times higher LHV than the LHV of methane produced by anaerobic digestion. And LHV of solid fuel was about 6.0 times higher than the LHV of methane produced by anaerobic digestion. Then, the production of solid fuel presented more bioenergy conversion efficiency than the biogas production in the bioenergy use of cattle feedlot manure.

• 한국신재생에너지학회:학술대회논문집
• /
• 2010.11a
• /
• pp.101-101
• /
• 2010

Anaerobic digestion(AD) is the most promising method for treating and recycling of different organic wastes, such as organic fraction of municipal solid waste, household wastes, animal manure, agro-industrial wastes, industrial organic wastes and sewage sludge. During AD, i.e. organic materials are decomposed by anaerobic forming bacteria and fina1ly converted to excellent fertilizer and biogas which is a mixture of carbon dioxide and methane. AD has been one of the leading technologies that can make a large contribution to produce renewable energy and to reduce $CO_2$ and other green-house gas(GHG) emission, it is becoming a key method for both waste treatment and recovery of a renewable fuel and other valuable co-products. Currently some 80% of the world's overall energy supply of about 400 EJ per year in derived from fossil fuels. Nevertheless roughly 10~15% of this demand is covered by biomass resources, making biomass by far the most important renewable energy source used to date. The representative biofuels produced from the biomass are bioethanol, biodiesel and biogas, and currently biogas plays a smaller than other biofuels but steadily growing role. Traditionally anaerobic digestion applied for different biowaste e.g. sewage sludge, manure, other organic wastes treatment and stabilization, biogas has become a well established energy resource. However, the biowaste are fairly limited in respect to the production and utilization as renewable source, but the plant biomass, the so called "energy crops" are used for more biogas production in EU countries and the investigation on the biomethane potential of different crops and plant materials have been carried out. In Korea, with steadily increasing oil prices and improved environmental regulations, since 2005 anaerobic digestion was again stimulated, especially on the biogasification of different biowastes and agro-industrial biomass including "energy crops". This study have been carried out to investigate anaerobic biodegradability by the biochemical methane potential(BMP) test of animal manures, different forage crops i.e. "energy crops", plant and industrial organic wastes in the condition of thermophilic temperature, The biodegradability of animal manure were 63.2% and 58.2% with $315m^3CH_4/tonVS$ of cattle slurry and $370m^3CH_4/tonVS$ of pig slurry in ultimate methane yields. Those of winter forage crops were the range 75% to 87% with ultimate methane yield of $378m^3CH_4/tonVS$ to $450m^3CH_4/tonVS$ and those of summer forage crops were the range 81% to 85% with ultimate methane yield of $392m^3CH_4/tonVS$ to $415m^3CH_4/tonVS$. The forge crops as "energy crops" could be used as good renewable energy source to increase methane production and to improve biodegradability in co-digestion with animal manure or only energy crop digestion.

• Environmental Engineering Research
• /
• v.24 no.1
• /
• pp.38-44
• /
• 2019

The Biochemical Methane Potential (BMP) of fresh leachate and domestic wastewaters codigestion was determined by laboratory Bach Tests at $35^{\circ}C$ over a period of 90 d using a wide range of leachates volumetric ratios from 0% to 100%. To simulate wastewaters plant treatment step, all the ratios were first air stripped for 48 h before anaerobic incubation. The kinetic of biogas production was assessed using modified Gompertz model and exponential equation. The results obtained showed that cumulative biogas production was insignificant in the case of wastewaters monodigestion while the codigestion significantly improves the BMP. Air stripping pretreatment had positive effect on both ammonium concentration and volatiles fatty acids with reduction up to 75% and 42%, respectively. According to the Modified Gompertz model, the optimal anaerobic co-digestion conditions both in terms of maximal biogas potential, start-up period and maximum daily biogas production rate, could be achieved within large leachate volumetric ratios from 25% to 75% with a maximum BMP value of 438.42 mL/g volatile solid at 50% leachate ratio. The positive effect of codigestion was attributed to a dilution effect of chemical oxygen demand and volatile fatty acid concentrations to optimal range that was between 11.7 to $32.3gO_2/L$ and 2.1 to 7.4 g/L, respectively. These results suggested that the treatment of fresh leachate by their dilution and co digestion at wastewaters treatment plants could be a promising alternative for both energetic and treatment purposes.

• Journal of the Korean GEO-environmental Society
• /
• v.15 no.9
• /
• pp.5-12
• /
• 2014

Anaerobic digestion was investigated for the stabilization of sludge, decrease of volatile solids, production of biogas for wastewater sludge. In this study, total solids and volatile solids, elemental analysis were conducted to determine characteristics of various types of sludges and investigate the feasibility of biogas production of Municipal Wastewater Sludge (MWS), Industrial Wastewater Sludge (IWS), mixed sludge (Mix), and Municipal Wastewater Sludg Cake (MWSC). Total solids, volatile solids, and C/N ratio were determined in the range of 11.2~20.6 %, 62.1~83.1 % of TS and 4.96~8.33 %. Using the biochemical methane potential (BMP test), mixed sludge and wastewater sludge finished the methane production within approximately 20 day and 16~17 day. Sludge cake finished within 10 day. Mixed sludge produced 395.5 mL $CH_4$ per g of Volatile Solid (VS) and resulted in the highest methane production. For carbon dioxide production, five sludges had similar value of accumulated carbon dioxide production except for sludge cake.

• Journal of The Korean Society of Agricultural Engineers
• /
• v.62 no.2
• /
• pp.17-29
• /
• 2020

The objective of this study was to find an optimum methane yield condition in anaerobic digestion of sewage sludge with microwave pretreatment. The pretreatment process was carried out using a lab scale industrial microwave unit (2,450 MHz frequency). The digestion efficiency of pretreated sludge was evaluated by biochemical methane potential (BMP) test. Box-Behnken design and Response Surface Analysis (RSA) were applied to determine the optimal combination of sludge mixing ratio (0 to 100%), power (400 to 1600 W), holding time (0 to 10 min) and pretreatment temperature (60 to 100℃). BMP test results showed that Volatile Solid (VS) removal efficiency was up to 48% at a condition of 0% for mixing ratio, 1600 W for power, 5 min for holding time, and 80℃ for pretreatment temperature. Methane production was up to 832.3 mL/g VS_removed at a condition of 50% for mixing ratio, 1000 W for power, 5 min for holding time, and 80℃ for pretreatment temperature. The results of the variance analysis (ANOVA) showed that the p-value of the power and pretreatment temperature among the independent variables were significant (p<0.05), and in particular, the pretreatment temperature significantly affected on the solubilization and methane production. The optimum condition for the maximum methane yield (847 mL/g VS_removed) was consist of 38.4% of mixing ratio, 909.1 W of power, 4.1 min of holding time, and 80℃ of temperature within the design boundaries.

• Journal of Animal Environmental Science
• /
• v.17 no.3
• /
• pp.197-204
• /
• 2011

During the process of anaerobic digestion, hydrolysis of substrate is the key factor determining methane production efficiency. The hydrolysis efficiency are directly affected by biodegradability of substrate. In this study, three types of pre-treatment methods were tested to enhance biodegradability effectiveness. By the application of blender and the Cavitation treatment, the SCODcr increased from 24,723 mg/l to 24.726~29,175 mg/l and to 25,589~26,456 mg/l, respectively. In case of ozone treatment, the SCODcr decreased from 24,723 mg/l to 22.540~23,988 mg/l. In batch experiment, there was a little improvement of the biochemical methane potential (BMP) by the blender and the cavitation treatment. In contrast, the BMP somewhat decreased by ozone treatment. This result shows that higher anaerobic digestion efficiency of livestock manure could be obtained through pre-treatment of substrate.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.27 no.3
• /
• pp.27-39
• /
• 2019

In this study, thermal-alkali pre-treatment (THAP) optimal condition and co-digestion efficiency with THAP of the mixture food waste and sewage sludge were evaluated for improving the performances of co-digestion for mixed food waste and sewage sludge. The optimal condition of THAP was evaluated for solubilization COD, CST(Capillary Suction Time), TTF(Time to Filter), and volatile fatty acids (VFAs) with THAP temperature and NaOH concentration. In addition, the co-digestion of mixed food waste and sewage sludge were evaluated using biochemical methane potential (BMP) test. The optimal THAP reaction temperature and NaOH concentration of food waste and sewage sludge were $140^{\circ}C$ and 60 meq/L to solubilization COD over 20%, CST and TTF under 60sec and VFAs concentration over 12,000 mg-COD/L, respectively. The optimal condition of co-digestion of mixed food waste and sewage sludge equal to THAP condition. Therefore, it was determined that the optimal condition of THAP reaction temperature and NaOH concentration for co-digestion of mixed food waste and sewage sludge were $140^{\circ}C$ and 60 meq/L, respectively.

• Korean Journal of Soil Science and Fertilizer
• /
• v.45 no.4
• /
• pp.524-531
• /
• 2012

The objective of this study was to investigate the organic solubilization (SCOD) and improvement of methane production for pig slurry by thermal hydrolysis. A sludge cake was pretreated by thermal hydrolysis at different reaction temperatures (200, 220, 250, $270^{\circ}C$). Ultimate methane potential (Bu) was determined at several substrate and inoculum (S/I) ratios (1:9, 3:7, 5:5, 7:3 in volume ratio) by biochemical methane potential (BMP) assay for 73 days. Pig slurry SCOD were obtained with 98.4~98.9% at the reaction temperature of $200{\sim}270^{\circ}C$. Theoretical methane potentials ($B_{th}$) of thermal hydrolysates at the reaction temperature of $200^{\circ}C$, $220^{\circ}C$, $250^{\circ}C$, $270^{\circ}C$ were 0.631, 0.634, 0.705, $0.748Nm^3\;kg^{-1}-VS_{added}$, respectively. $B_u$ of $200^{\circ}C$ thermal hydrolysate were decreased from $0.197Nm^3\;kg^{-1}-VS_{added}$ to $0.111Nm^3\;kg^{-1}-VS_{added}$ with the changes of S/I ratio from 1:9 to 7:3, and also $B_u$ of different thermal hydrolysates ($220^{\circ}C$, $250^{\circ}C$, $270^{\circ}C$) showed same tendency to $B_u$ of $200^{\circ}C$ thermal hydrolysate according to the changes of S/I ratio. Anaerobic biodegradability ($B_u/B_{th}$) of $200^{\circ}C$ thermal hydrolysate at different S/I ratios was decreased from 32.2% for S/I ratio of 1:9 to 17.6% for S/I ratio of 7:3. $B_u/B_{th}$ of $220^{\circ}C$, $250^{\circ}C$, and $270^{\circ}C$ thermal hydrolysat were decreased from 36.4% to 9.6%, from 31.3% to 0.8%, and from 26.6% to 0.8%, respectively, with the S/I ratio change, respectively. In this study, the rise of thermal reaction temperature caused the decrease of anaerobic digestibility and methane production while organic materials of pig slurry were more solubilized.