• Macromolecular Research
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• v.13 no.5
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• pp.427-434
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• 2005

To improve the performance and reduce raw material costs, blocked isocyanates were prepared with mixture of blocking agents in many industries. Three blocked isocyanates (adducts) namely $\varepsilon$-caprolactam/benzotriazole-blocked 4,4'-diphenylmethane diisocyanate (MDI), toluene-2,4-diisocyanate (TDI) and 4,4'-dicyclohexyl-methane diisocyanate ($H_{12}$MDI) were synthesized. Six reference adducts were also prepared by blocking MDI, TDI, and $H_{12}$MDI with $\varepsilon$-caprolactam ($\varepsilon$-CL) or benzotriazole. The reactions were carried out in acetone medium and dibutyltin dilaurate (DBTDL) was used as a catalyst. The progress of the blocking reaction was monitored by IR spectroscopy. De-blocking temperatures (dissociation temperatures) of these adducts were studied using DSC and TGA and the results were correlated. As expected, the thermal analysis data showed that de-blocking temperature of blocked aromatic isocyanates was lower than that of the blocked aliphatic isocyanates. The low de-blocking temperature of blocked aromatic isocyanate could be due to electron withdrawing benzene ring present in the blocked isocyanates. It was also found that benzotriazole-blocked adducts de-blocked at higher temperature compared with $\varepsilon$-CL-blocked adducts.

• Bulletin of the Korean Chemical Society
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• v.32 no.10
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• pp.3629-3633
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• 2011

The effect of a dense $TiO_2$ blocking layer prepared using the sol-gel method on the performance of dye-sensitized solar cells was studied. The blocking layer formed directly on the working electrode, separated it from the electrolyte, and prevented the back transfer of electrons from the electrode to the electrolyte. The dyesensitized solar cells were prepared with a working electrode of fluorine-doped tin oxide glass coated with a blocking layer of dense $TiO_2$, a dye-attached mesoporous $TiO_2$ film, and a nano-gel electrolyte, and a counter electrode of Pt-deposited FTO glass. The gel processing conditions and heat treatment temperature for blocking layer formation affected the morphology and performance of the cells, and their optimal values were determined. The introduction of the blocking layer increased the conversion efficiency of the cell by 7.37% for the cell without a blocking layer to 8.55% for the cell with a dense $TiO_2$ blocking layer, under standard illumination conditions. The short-circuit current density ($J_{sc}$) and open-circuit voltage ($V_{oc}$) also were increased by the addition of a dense $TiO_2$ blocking layer.

• Industrial Engineering and Management Systems
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• v.14 no.3
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• pp.289-298
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• 2015

This paper analyses the best batch formations for order picking throughput in narrow-aisle order picking systems. Our analytical comparison finds that a high pick density variation leads to a heavy picker blocking. Simulation experiments show that a distance-based batching algorithm reduces picker blocking by decreasing the number of aisles visited and stabilizing the variation in number of picks per aisle by packing orders tightly, and that the solution quality and mechanism for determining the batch size dictated by the sorting strategy causes varying amounts of blocking. We conclude that combining a distance-based batching method with an appropriate batch sizing strategy will reduce picker blocking and shorten travel in narrow-aisle picking systems.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11b
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• pp.243-246
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• 2001

In this paper, we have proposed a novel trench electrode Base Resistance Thyristor(BRT) and trench electrode BRT with a intrinsic region. A new power BRTs have shown superior electrical characteristics including snab-back effict and forward blocking voltage more than the conventional BRT. Especially, the trench electrode BRT with intrinsic region has obtained high blocking voltage of 1600V. The blocking voltage of conventional BRT is about 400V at the same size. Because the breakdown mechanism of BRT is avalanch breakdown by impact ionization, the trench electrode BRT with intrinsic region has suppressed impact ionization, effectively. If we use this principle, we can develope super high voltage power devices and applicate to another power devices including IGBT, EST and etc.

• The Transactions of the Korean Institute of Electrical Engineers D
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• v.49 no.8
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• pp.481-490
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• 2000

This paper analyzes interference power, Erlang capacity, the number of handoff occurrences, and call blocking probability with respect to the cell radius, the soft handoff region, and the mobile's velocity in a CDMA hierarchical cellular system. The microcell cellular system has the higher Erlang capacity than the macrocell cellular system. However, the microcell cellular system, which has a high system capacity through frequency reuse has the call blocking probability higher than macrocell cellular system. Also the interference power and the call blocking probability are decreased with the operation of soft handoff. Therefore, this paper presents the optimization of soft handoff region so as to maximize system's Erlang capacity with the low the call blocking probability according to mobile's velocity in the CDMA hierarchial cellular system.

• International journal of advanced smart convergence
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• v.7 no.3
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• pp.101-109
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• 2018

In this paper, we propose an adaptive filtering scheme of connection requests for the defense of malicious energy consumption attacks against wireless computing devices with limited energy budget. The energy consumption attack tries to consume the battery energy of a wireless device with repeated connection requests and shut down the wireless device by exhausting its energy budget. The proposed scheme blocks a connection request of the energy consumption attack in the middle, if the same connection request is repeated and its request result is failed continuously. In order to avoid the blocking of innocuous mistakes of normal users, the scheme gives another chance to allow connection request after a fixed blocking time. The scheme changes the blocking time adaptively by comparing the message arriving ate during non-blocking period and that during blocking period. Evaluation shows that the proposed defense scheme saves up to 94% energy consumption compared to the non-defense case.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11a
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• pp.243-246
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• 2001

In this paper, we have proposed a novel trench electrode Base Resistance Thyristor(BRT) and trench electrode BRT with a intrinsic region. A new power BRTs have shown superior electrical characteristics including snab-back effect and forward blocking voltage more than the conventional BRT. Especially, the trench electrode BRT with intrinsic region has obtained high blocking voltage of 1600V. The blocking voltage of conventional BRT is about 400V at the same size. Because the breakdown mechanism of BRT is avalanch breakdown by impact ionization, the trench electrode BRT with intrinsic region has suppressed impact ionization, effectively. If we use this principle, we can develope super high voltage power devices and applicate to another power devices including IGBT, EST and etc.

• Journal of the Korean Ceramic Society
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• v.52 no.4
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• pp.294-298
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• 2015

Blocking layers with nano carbon blacks (NCBs) were prepared by adding 0.0 ~ 0.5 wt% NCBs to the $TiO_2$ blocking layer. Then, dye sensitized solar cells (DSSCs) were fabricated with a $0.45cm^2$ active area. TEM and micro-Raman spectroscopy were used to characterize the microstructure and phases of the NCBs, respectively. Optical microscopy and AFM were used to analyze the microstructure of the $TiO_2$ blocking layer with NCBs. UV-VIS-NIS spectroscopy was used to determine the band gap of the $TiO_2$ blocking layer with NCBs. A solar simulator and potentiostat were used to determine the photovoltaic properties and impedance of DSSCs with NCBs. The energy conversion efficiency (ECE) increased from 3.53 to 6.20 % when the NCB content increased from 0.0 to 0.3 wt%. This indicates that the effective surface area and electron mobility increased in the $TiO_2$ blocking layer with NCBs. However, the ECE decreased when the NCB content was increased to over 0.4 wt%. This change occurred because the effective electron transport area decreased with the addition of excessive NCBs to the $TiO_2$ blocking layer. The results of this study suggest that the ECE of DSSCs can be enhanced by adding the appropriate amount of NCBs to the $TiO_2$ blocking layer.

• The KIPS Transactions:PartB
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• v.15B no.5
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• pp.383-390
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• 2008

Block based transform coding is most popular approach for image and video compression. However it suffers from severe quality degradation especially from blocking artifacts. The subjective quality degradation caused by such blocking artifacts in general does not agree well with an objecive quality measurement such as PSNR. Hence new quality evaluation technique is necessary. We propose a new image quality assessment method by measuring blocking artifacts for block based transform coded images. In order to characterize blocking artifacts, proposed method utilizes the facts that, blocking artifacts, when occur, have different pixel values along the block boundaries and such differences usually continuously span along the whole boundaries. This method does not require the original uncompressed image. It operates on single block boundary and quantifies the amount of blocking artifacts on it. Experiments on various compressed images various bitrates show that proposed quantitative measure of blocking artifacts matches well with the subjective quality of them judged by human visual system.

• The Korean Journal of Community Living Science
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• v.17 no.4
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• pp.29-38
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• 2006

The present study proposed to develop a Hanji hat that can protect the body from UV rays and be preferred by consumers. For this purpose, using Hanji dyed by ginkgo leaf extract, we manufactured Hats in 12 designs. The UV blocking rate was determined by putting the hats on a mannequin and measuring the quantity of UV rays penetrating through the hat. In addition, preference for each design was surveyed, and the hat most suitable for the purpose was selected. The results of this study are as follows. 1. The UV blocking rate of the manufactured Hanji hats was over 92% for UVA and 97% for UVB in all of the 12 hats. 2. Among the 12 designs, the UV blocking rate for UVA was highest in 'Design(b)' and 'Design(1)' $(P\leq0.05)$, and the UV blocking rate for UVB was identical in all the designs except 'Design(i)' and 'Design(g)' $(P\leq0.01)$. 3. The effect of UV blocking was highest on the nape of the neck; next, on the brow, the cheeks, the nose and the chin in that order. 4. According to the result of the survey of preference, simple designs such as 'Design(a), (b)' and 'Design(9)' were preferred. In addition, it was found that the design would affect the purchase of a hat marked with a UV blocking index (68%). 5. Based on the results of this research as presented above, 'Design(b)', which showed a high UV blocking effect and was highly preferred, was selected as the most suitable hat for the purpose of this research.