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Effect of Temperature on the Nitrogen Removal of Municipal Wastewater in a Pilot-scale Moving Bed Biofilm Reactor with Waste-tire Media (폐타이어 담체를 이용한 파일럿 규모 유동상 생물막 공정에서 하수의 질소제거에 미치는 온도 영향)

  • Park, Woon-Ji;Ahn, Johng-Hwa;Lee, Chan-Ki
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.5
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    • pp.507-516
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    • 2008
  • This research was conducted to elucidate the effect of temperature on the nitrogen removal of municipal wastewater with waste-tire media. The experiments were carried out in laboratory-scale batch reactor and pilot-scale moving bed biofilm reactor filled at a 0.15 filling ratio with waste-tire media, respectively. In batch tests, specific nitrification rate(SNR) with media was 3.4 mg NH$_4^+$-N/g Mixed-Liquor Volatile Suspended Solid(MLVSS)$\cdot$hr, compared with 1.7 mg NH$_4^+$-N/g MLVSS$\cdot$hr without media. In pilot-scale test with media, total nitrogen removal efficiency increased from 53 $\pm$ 8% to 76 $\pm$ 5% as the temperature increased from 9$\sim$10$^{\circ}C$ to 20$\sim$24$^{\circ}C$. At the temperature of 9$\sim$10$^{\circ}C$, 10$\sim$20$^{\circ}C$, and 20$\sim$24$^{\circ}C$, the SNRs were 0.8 $\pm$ 0.5, 3.1 $\pm$ 1.9, and 3.4 $\pm$ 2.1 mg NH$_4^+$-N/g MLVSS$\cdot$hr and the specific denitrification rates(SDNR) were 0.6 $\pm$ 0.2, 1.1 $\pm$ 0.6, 1.4 $\pm$ 0.6 mg NO$_3^-$-N/g MLVSS.hr, respectively. The overall activities of biomass in anaerobic, anoxic, and oxic zones at 20$\sim$24$^{\circ}C$ increased to 22, 20, and 15%, compared with those at 9$\sim$10$^{\circ}C$, respectively. The activity distribution of Nitrosomonas and Nitrobacter also increased with the increase of temperature.

Development of 'Carbon Footprint' Concept and Its Utilization Prospects in the Agricultural and Forestry Sector ('탄소발자국' 개념의 발전 과정과 농림 부문에서의 활용 전망)

  • Choi, Sung-Won;Kim, Hakyoung;Kim, Joon
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.17 no.4
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    • pp.358-383
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    • 2015
  • The concept of 'carbon footprint' has been developed as a means of quantifying the specific emissions of the greenhouse gases (GHGs) that cause global warming. Although there are still neither clear definitions of the term nor rules for units or the scope of its estimation, it is broadly accepted that the carbon footprint is the total amount of GHGs, expressed as $CO_2$ equivalents, emitted into the atmosphere directly or indirectly at all processes of the production by an individual or organization. According to the ISO/TS 14067, the carbon footprint of a product is calculated by multiplying the units of activity of processes that emit GHGs by emission factor of the processes, and by summing them up. Based on this, 'carbon labelling' system has been implemented in various ways over the world to provide consumers the opportunities of comparison and choice, and to encourage voluntary activities of producers to reduce GHG emissions. In the agricultural sector, as a judgment basis to help purchaser with ethical consumption, 'low-carbon agricultural and livestock products certification' system is expected to have more utilization value. In this process, the 'cradle to gate' approach (which excludes stages for usage and disposal) is mainly used to set the boundaries of the life cycle assessment for agricultural products. The estimation of carbon footprint for the entire agricultural and forestry sector should take both removals and emissions into account in the "National Greenhouse Gas Inventory Report". The carbon accumulation in the biomass of perennial trees in cropland should be considered also to reduce the total GHG emissions. In order to accomplish this, tower-based flux measurements can be used, which provide a direct quantification of $CO_2$ exchange during the entire life cycle. Carbon footprint information can be combined with other indicators to develop more holistic assessment indicators for sustainable agricultural and forestry ecosystems.

Water Environment and Freshwater Algae in the Upstream of the Tamjin River Dam (탐진강댐 상류하천에서 수환경과 담수조류)

  • Shin, Jae-Ki;Cho, Kyung-Je
    • Journal of Environmental Impact Assessment
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    • v.10 no.2
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    • pp.109-121
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    • 2001
  • Water environment and freshwater algae were studied in the upstream of the Tamjin River Dam. Among the environmental factors, DO concentration in the Tamjin River ranged from 9.0 mg $O_2/l$ to 9.2 mg $O_2/l$, pH from 7.0 to 7.1 and conductivity from $98{\mu}S/cm$ to $100{\mu}S/cm$. Average concentration of $NH_4$ and $NO_3$ ranged from $40{\mu}g\;N/l$ to $56{\mu}g\;N/l$ and from $489{\mu}g\;N/l$ to $611{\mu}g\;N/l$, respectively. $NO_3$ was more plentiful above 9~15 fold than that of $NH_4$. Average concentrations of soluble reactive phosphorus and soluble reactive silicon were $2{\mu}g\;P/l$ and 1.6 mg Si/l, respectively. Particulaly, Si nutrient increased by heavy rain events during summer season. The ratios of N/P and Si/P ranged from 248 to 261 and from 640 to 740, respectively. It is assumed that P would be limiting nutrient on the freshwater algal growth. Average content of planktonic chlorophyll-a ranged from $5{\mu}g/l$ to $13{\mu}g/l$. Mean contents of chlorophyll-a, phaeo-pigment and ash-free dry matter of periphyton were $50.3mg/m^2$, $11.9mg/m^2$, $11.5g/m^2$ in the main stream and $30.1mg/m^2$, $5.6mg/m^2$, $7.8g/m^2$ in the tributary. By comparison of the epilithon biomass, the main stream was higher with 1.5~2.1 fold than the tributary. The impotant algae were composed of diatom Achnanthes linearis, A. minutissima, Fragilaria crotonensis, Gomphonema gracile, Tabellaria flocculosa and blue-green algae Microcystis aeruginosa. In the relative abundance of the phytoplankton and epilithon, the serial dominance were diatom > green algae > blue-green algae, and diatoms were very abundant in comparison with other algal phylum.

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Target Strength of Schlegel′s Black Rockfish (Sebastes schlegeli)and Red Seabream (Pagrus major) (조피볼락과 참돔의 표적 강도에 관한 연구)

  • 손창환;황두진
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.38 no.2
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    • pp.119-128
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    • 2002
  • This study investigates dorsal aspect target strength with fish size, tilt angle and frequency characteristics for the schlegel's black rockfish(Sebastes achlegeli) and the red seabream (Pagrus major). This study was carried out on free swimming fish in a cage in order to obtain acoustic data of the biomass estimation using the scientific echo sounder. The results obtained from this study are summarized as follows; 1 The coefficients of the schlegel's black rockfish and the red seabream using maximum TS with fish length were expressed -63.7dB and -62.6dB at a frequency of 38kHz, -64.4dB and -65.4dB at 120kHz, and -62.4dB and -65.0dB at 200kHz, respectively. 2. The coefficients of the schlegel\`s black rockfish and the red seabream using averaged TS with fish length were expressed -68.4dB and -67.9dB at a frequency of 38kHz, -73.4dB and -72.7dB at 120kHz, and -70.BdE and -73.4dB at 2001Hs, respectively. 3. The coefficients of the schlegel's black rockfish and the red seabream using maximum TS with body weight were expressed -52.0dB and -50.9dB at a frequency of 38kHz, -52.7dB and -53.7dB at 120kHz, and -50.7dB and -53.3dB at 200kHz, respectively. 4. The coefficients of the schlegel's black rockfish and the red seabream using averaged TS with body weight were expressed -56.7dB and -56.2dB at a frequency of 38kHz, -61.7dB and -61.0dB at 120kHz, and -59.ldE and -61.6dB at 200kHz, respectively. 5. Varying the tiIt angle of the two red seabream from -26$^{\circ}$to +25$^{\circ}$, the variation width of target strength expressed smaller at a frequency of 38kHz than at 120kHz and expressed about 3~6dB higher head up than head down at 120kHz.

Species Composition of the Catches collected by a Bottom Trawl in the Southern Waters of Korea in Summer, 2004 (2004년 하계 한국 남해에 있어서 저층 트롤 어획물의 종조성)

  • Jeong, Sun-Beom;Hwang, Doo-Jin;Kim, Young-Ju;Shin, Hyeong-Ho;Son, Yong-Uk
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.41 no.1
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    • pp.35-45
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    • 2005
  • The experiment was conducted to investigate the species composition of catches collected by the bottom trawl on June 24 to 26, 2004 in the southern waters of Korea using a trawler "DONGBAEK" belongs to Yosu National University. The investigation was carried out at the 5 stations and the towing speed was 3.4${\sim}$3.7k't. The catches were composed of 46 species from 37 families, 10 orders and 2 classes for fishes and 2 species, 2 families and 2 orders for Chondrichthyes and 44 species, 35 familes, 8 orders for Osteichthyes. The catches of Perciforms were the highest as 24 species and 18 families for fishes. The catches of Spear squid, Loli해 bleekeri and Red banded lobster, Metanephrops thomsoni were also the highest for mollusca and crustacea as 1 class, 3 species, 3 families, 2 orders, 1 class and 7 species, 5 families, 1 order, 1 class respectively. In the 5 stations, number of individuals and biomass were 1,144 and 376.0kg at ST-1, 908 and 240.3kg at ST-2, 666 and 90.1kg at ST-3, 2,050 and 300..4kg at ST-4 and 561 and 24.7kg at ST-5. The diversity index of each stations ranged between 1.49 and it showed the richness index of 2.13${\sim}$3.48, the evenness index of 0.48${\sim}$0.77 and the dominance index of 0.43${\sim}$0.8. Body length distributio of the dominant specise were 9${\sim}$32cm(fork length) for Japanese horse mackerel, Trachurus japonicus, 7${\sim}$23cm(mantle length) for Common squid, Todarodes pacificus, 9${\sim}$43cm(mantle length) for Spear squid, Loli해 bleekeri, 23${\sim}$36cm(total length) for File fish, Thamnaconus modestus, 10${\sim}$28cm(fork length) for Yellow porgy, Dentex tumifrons, 10${\sim}$36cm(fork length) for Target dory, Zeus faber and 8${\sim}$35cm(fork length) for Red seabream, Pagrus major.

Acoustic Scattering Characteristis of the Individual Fish (어체의 초음파 산란특성에 관한 연구)

  • 신형일
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.27 no.1
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    • pp.21-30
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    • 1991
  • The estimation of the fish biomass density or the size of fish by means of the acoustic equipment is an important part in the quantitative assessment of fisheries resources. The precision of such estimates depend upon the target strength of fish and the accuracy to which the acoustic equipment has been calibrated. This paper examine the accuracy of the digital measurement system which is manufactured by way of trial in order to masure the target strength of fish, and calibrations of that system carry out with an ogive and a ellipsoid made of the aluminum and the epoxy, respectively. Furthermore, measurements of target strength for eight species of fish are made at 25, 50, 100 kHz. The accuracy of the digital measurement system is compared the theory with measurements on ogive and ellipsoid, and the agreement is reasonable. Result of establishments on the target strength to fish length and to fish weight regression obtained from the measurements are available to provide the methods of design for use in interpreting acoustic measurements of fish abundance on the experimented eight species.

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Feasibility Test of Biohydrogen Production from Food Waste (음식물쓰레기의 수소발효 타당성 평가)

  • Han, Sun-Kee;Kim, Sang-Hyoun;Shin, Hang-Sik
    • Journal of the Korea Organic Resources Recycling Association
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    • v.11 no.3
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    • pp.87-95
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    • 2003
  • Although extensive studies were conduced on hydrogen fermentation of organic wastewaters, little is known about biohydrogen production from organic solid wastes. The leaching-bed reactor treating food waste by heat-shocked anaerobic sludge was, therefore, operated at D of 2.1, 3.6, 4.5 and $5.5d^{-1}$ to find optimal D for hydrogen production. Successful operation of a reactor can be accomplished when it is operated at proper dilution rate (D). Operation at high D leads to the washout of biomass in the reactor while operation at low D leads to product inhibition due to the accumulation of excess VFA. These appear to limit the production of hydrogen to reach a higher level. All the reactors showed that, on day 1-3, hydrogen production was dominant and VFA concentration was higher than ethanol. Butyrate and acetate were major components of VFAs over the whole operation, though lactate was very high on day 1-2. Compared with other D values, D of $4.5d^{-1}$, resulted in higher butyrate/acetae (B/A) ratios during the fermentation. The trend of B/A ratios was similar to the hydrogen production, suggesting that butyrate formation favored hydrogen production. Ethanol increased significantly from day 4 when hydrogen Production stopped. It indicated that heat-shocked sludge was able to induce a metabolic flow from hydrogen-and acid-producing pathway to solvent-producing pathway. Operation at D of $4.5d^{-1}$ led to higher fermentation efficiency (58%) than those (51.5, 55.3 and 53.7%) at 2.1, 3.6 and $5.5d^{-1}$. The COD removed was convened to hydrogen (10.1%), VFA (30.9%), and ethanol (17.0%).

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Immobilization of Xylose Isomerase and Trial Production of High Fructose Corn Syrup (Xylose 이성화 효소의 고정화 및 이성화당의 생산)

  • Chun, Moon-Jin;Lim, Bun-Sam
    • Applied Biological Chemistry
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    • v.26 no.4
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    • pp.222-230
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    • 1983
  • This study was designed to develop a process for the immobilization of xylose isomerase(D-xylose ketol isomerase, EC 5.3.1.5) from Streptomyces griseolus previously isolated by the authors and its application on a pilot plant scale for the production of high fructose corn syrup. The biomass which has endo-excreted xylose isomerase was homogenized under a pressure of $500kg/cm^2$ and 90.8% of the enzyme recovery of the native activity was obtained as compared to 54.7% recovery by the lysozyme treatment. Ionic bonding method was adopted for the enzyme immobilization due to its many reported merits. It was found that the porous resins such as Diaion HP 20, Duolite A-7, Amberlite IRA 93 and 94 were effective in immobilizing the enzyme. In addition, it was disclosed that the regeneration form of $BO_4--$ is effective for Amberlite IRA 93 and $HCO_3-$ for Diaion HP 20. Optimal immobilization condition for Amberlite IRA 93 was pH 8.0 and $55^{\circ}C$ yielding 80.6% of immobilization. Activity decay test showed half life of the immobilized enzyme with Amberlite IRA 93 was more than 24 days at $65^{\circ}C$. The carrier was evaluated to be resuable and its result showed the relative immobilization yields were 98.2, 93.3, 90.7 and 87.5%, respectively at second, third, forth and fifth rebinding test of the enzyme on Amberlite IRA 93. Optimal temperature of the immobilized enzyme was slightly lowered and the range widened to $60\sim70^{\circ}C$, while optimal pH moved toward $8.0\sim8.3$ in its isomerization reaction. The trial production result of high fructose corn syrup in pilot scale immobilization showed that one liter of immobilized xylose isomerase (350 IXIU/ml-R) is capable producing about 293l high fructose corn syrup(75% dry substance) in 30 days.

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Enhanced hydrogen fermentation of food waste (음식물쓰레기를 이용한 수소발효 시 효율향상에 관한 연구)

  • Han, Sun-Kee;Kim, Hyun-Woo;Shin, Hang-Sik
    • Journal of the Korea Organic Resources Recycling Association
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    • v.11 no.4
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    • pp.105-113
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    • 2003
  • Successful operation of a reactor can be accomplished when it is operated at proper D depending on the state of degradation. Operation at high D leads to the washout of biomass in the reactor while operation at low D leads to product inhibition due to the accumulation of excess VFA. These appear to limit the production of hydrogen to reach a higher level. Operation by D control was performed to improve the efficiency of hydrogen fermentation of food waste. Although simple organic matters were rapidly degraded in the early stage (day 1-2), proper VFA concentration and pH values were kept in the reactor at D of $4.5d^{-1}$, which was previously reported to be optimum initial D. High butyrate/acetate (B/A) ratios over 3.2 were obtained. Without D control, the reduction of simple organic matters after day 2 caused the decrease of VFA production and the increase of pH. Hydrogen production also decreased, as microbial proliferation was less than microbial loss by washout. However, the reactor performance was dramatically improved at D control from 4.5 to $2.3d^{-1}$. It showed the highest B/A ratios over 2.0 among the reactors on day 4-7. The second hydrogen peak appeared on day 4, resulting in the highest fermentation efficiency (70.8%) among the reactors. It was caused by the enhanced degradation of slowly degradable matters. The COD removed was converted to hydrogen (19.3%), VFA (36.5%), and ethanol (15.0%). Therefore, the strategy using D control, depending on the state of degradation, was effective in improving the efficiency of hydrogen fermentation.

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Water Quality Improvement of Stagnant Water using an Upflow Activated Carbon Biofilm Process and Microbial Community Analysis (상향류 활성탄 생물막 공정을 이용한 정체 수역 수질 개선 및 공정 내 미생물 군집 해석)

  • Oh, Yu-Mi;Lee, Jae-Ho;Park, Jeung-Jin;Choi, Gi-Choong;Park, Tae-Joo;Lee, Tae-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.1
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    • pp.23-32
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    • 2010
  • The capacity of natural purification was limited by the interruption of natural flow and the problems such as eutrophication were occurred by nutritive salts accumulation in stagnant stream. Moreover, the inflow of non-point sources causes non-degradable materials to increase in stagnant stream. In this study, an upflow biological activated carbon (BAC) biofilm process comprised of anoxic, aerobic 1, and aerobic 2 reactors were introduced for treatment of stagnant stream and SS, $BOD_5$, $COD_{Mn}$, $COD_{Cr}$, TN, and TP were monitored in the upflow BAC biofilm reactors with continuous cycling. In order to simulate stagnant stream, the lake water of amusement park and golf course were stored as influent in a tank of $2m^3$ and hydraulic retention time (HRT) was changed into 6, 4, and 2 hours. At HRT 4hr and the lake water of amusement park as influent, the removal efficiencies of SS, $BOD_5$, $COD_{Mn}$, $COD_{Cr}$, TN, and TP showed the best water quality improvement and were 69.8, 83.0, 91.3, 74.1, 74.7, and 88.9%, respectively. At HRT 4hr and the lake water of golf course as influent, the removal efficiencies of SS, $BOD_5$, $COD_{Mn}$, $COD_{Cr}$, TN and TP were 78.5, 78.0, 80.2, 74.9, 55.6 and 97.5%, respectively. As the results of polymerase chain reaction - denaturing gel gradient electrophoresis (PCR-DGGE), microbial community was different depending on influent type. Fluorescence in situ hybridization (FISH) showed that nitrifying bacteria was dominant at HRT 4 hr. The biomass amount and microbial activities by INT-DHA test were not decrease even at lower HRT condition. In this study, the upflow BAC biofilm process would be considered to the water quality improvement of stagnant stream.