• Title/Summary/Keyword: BET model

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Adsorptions Isotherm of Water Vapor for Infant Formula Milk Powders and Calculation of Isosteric Heat (저장온도에 따른 복합조제분유의 등온흡습곡선 및 흡습엔탈피 산출)

  • Min, Sang-Gi;Choi, Mi-Jung;Lee, Seong
    • Food Science of Animal Resources
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    • v.18 no.4
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    • pp.285-291
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    • 1998
  • Adsorption isotherms of water vapour for infant formula milk powders manufactured by P. M. and N company in Korea were measured at temperatures between 20, 30 and 40$^{\circ}C$ using COST-90 modified method. Results showed that the isotherms were sigmoidal in shape. The adsorption isotherms of milk powder were depending on the temperature and products. The BET-model were applied and analyzed to compare the experimental value. It was found that the BET-model is fitted with measuring data. Sample P showed the lowest monolayer value and sample N showed the highest. Isosteric heat obtained upon application of BET-model was calculated in this field of temperature using the Clausius-Clapeyron equation. It is suggested that the usage of the BET-model to estimate the heat of water sorption in infant formula milk powder should be in agreement with the results from COST-90 project.

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A Determination Method of Optimum Combination Ratio of Two Kind Activated Carbon with Different Adsorbability (상이한 흡착 능을 가진 두 가지 활성탄의 적정 배합 비를 결정하는 방법)

  • Park, Young Tae;Im, Cheul Gyu;Kim, Yeon Tae;Rhee, Bosung
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.456-459
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    • 2011
  • Among the various activated carbons available in the market, an optimum mixing method of two kind activated carbons with different adsorbability was investigated in this study. The representative adsorption behaviors of the activated carbon are the adsorption isotherm plots obtained by the BET-Analysis which suggests also basic information of adsorption filter design. So we have tested three cases with certifications, the one was the extreme case of coal cokes based activated carbon with highest BET-model and coconut-shell based activated carbon with the lowest Langmuir-model, the other middle and cross case were applied this method to two kinds of activated carbons with higher and lower specific surface areas which are not available but supplied as research samples by an authority of an Korean Research Institute.

Adsorption isotherm and kinetics analysis of hexavalent chromium and mercury on mustard oil cake

  • Reddy, T. Vishnuvardhan;Chauhan, Sachin;Chakraborty, Saswati
    • Environmental Engineering Research
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    • v.22 no.1
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    • pp.95-107
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    • 2017
  • Adsorption equilibrium and kinetic behavior of two toxic heavy metals hexavalent chromium [Cr(VI)] and mercury [Hg(II)] on mustard oil cake (MOC) was studied. Isotherm of total chromium was of concave type (S1 type) suggesting cooperative adsorption. Total chromium adsorption followed BET isotherm model. Isotherm of Hg(II) was of L3 type with monolayer followed by multilayer formation due to blockage of pores of MOC at lower concentration of Hg(II). Combined BET-Langmuir and BET-Freundlich models were appropriate to predict Hg(II) adsorption data on MOC. Boyd's model confirmed that external mass transfer was rate limiting step for both total chromium and Hg(II) adsorptions with average diffusivity of $1.09{\times}10^{-16}$ and $0.97m^2/sec$, respectively. Desorption was more than 60% with Hg(II), but poor with chromium. The optimum pH for adsorptions of total chromium and Hg(II) were 2-3 and 5, respectively. At strong acidic pH, Cr(VI) was adsorbed by ion exchange mechanism and after adsorption reduced to Cr(III) and remained on MOC surface. Hg(II) removal was achieved by complexation of $HgCl_2$ with deprotonated amine ($-NH_2$) and carboxyl (COO-) groups of MOC.

Results of round robin test for specific surface area (비표면적 순회평가 결과)

  • Choi, Byung-Il;Kim, Jong-Chul;Woo, Sang-Bong
    • Analytical Science and Technology
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    • v.24 no.6
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    • pp.503-509
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    • 2011
  • Specific surface area is becoming a very important factor when newly developed advanced nano-materials are evaluated. But there have been many differences in results when measuring specific surface areas, depending on the measuring equipments and analysis method. To verify the reliability of the specific surface area measurement device supplied within the country, Round Robin Test (RRT) has been done at 21 affiliated research institutes. As a result, it was found that several institute had problems in measuring of gas adsorption amount in measuring equipment, and this proved the need for certified reference material (CRM). Furthermore, it was also found that the results from BET analysis is easily swayed by the analyst's subjectivism, and the calculated results may differ up to 16% in case of CRM I depending on the selection range of BET analysis. So this showed that a standard guideline for BET constant C value and fitting correlation coefficient R is needed, to properly select range in BET analysis. The experience in RRT, distribution of CRM, and standardized procedure would result in improved reliability in industrial processes, and thus, would contribute to the quality management, the productivity improvement, the safety evaluation, and the new material development.

Statistical Optimization of Growth Medium for the Production of the Entomopathogenic and Phytotoxic Cyclic Depsipeptide Beauvericin from Fusarium oxysporum KFCC 11363P

  • Lee, Hee-Seok;Song, Hyuk-Hwan;Ahn, Joong-Hoon;Shin, Cha-Gyun;Lee, Gung-Pyo;Lee, Chan
    • Journal of Microbiology and Biotechnology
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    • v.18 no.1
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    • pp.138-144
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    • 2008
  • The production of the entomopathogenic and phytotoxic cyclic depsipeptide beauvericin (BEA) was studied in submerged cultures of Fusarium oxysporum KFCC 11363P isolated in Korea. The influences of various factors on mycelia growth and BEA production were examined in both complete and chemically defined culture media. The mycelia growth and BEA production were highest in Fusarium defined medium. The optimal carbon and nitrogen sources for maximizing BEA production were glucose and $NaNO_3$, respectively. The carbon/nitrogen ratio for maximal production of BEA was investigated using response surface methodology (RSM). Equations derived by differentiation of the RSM model revealed that the production of BEA was maximal when using 108 mM glucose and 25 mM $NaNO_3$.

Comparison of Radical Scavenging and Immunomodulatory Activities Exhibited by an Aqueous Extract of Diospyros kaki Thunb. Fruit (Persimmon) (청도반시 추출물에 의한 라디칼소거 활성과 면역조절 활성의 상호 비교)

  • Heo, Jin-Chul;Chae, Jang-Heui;Lee, Sook-Hee;Lee, Yun-Rae;Moon, Kwang-Deog;Chung, Shin-Kyo;Lee, Sang-Han
    • Food Science and Preservation
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    • v.15 no.5
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    • pp.749-753
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    • 2008
  • To assess the relationship between anti-oxidant and immunomodulatory activities of Diospyros kaki Thunb. fruit, we harvested persimmons on the first Friday of every month from July to October, and conducted a DPPH assay, a T-bet promoter assay, and an ELISA for IL-4 determination. Anti-oxidant activity increased as fruit weight rose. When the fruit was extracted with five different solvents, and the extracts examined for radical scavenging activity, such activity exhibited a pattern similar to that seen when anti-oxidant activity was assessed. T-bet promoter activity decreased on ripening, whereas IL-4 expression increased, as tested in a DNFB-induced animal model. Collectively, the results suggest that inflammation-inhibitory activity, valuable in treatment of some immune diseases, rises as persimmons ripen.

Capacity of Activated Carbon Derived from Agricultural Waste in the Removal of Reactive Dyes from Aqueous Solutions

  • Manoochehri, Mahboobeh;Rattan, V.K.;Khorsand, Ameneh;Panahi, Homayon Ahmad
    • Carbon letters
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    • v.11 no.3
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    • pp.169-175
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    • 2010
  • The study describes the results of batch experiments on the removal of Reactive Yellow 15 (RY15) and Reactive Black 5 (RB5) from synthetic textile wastewater onto Activated Carbon from Walnut shell (ACW). The experimental data were analyzed by the Langmuir, Freundlish, Temkin and Dubinin-Radushkevich (D-R) models of adsorption. The experiments were carried out as function of initial concentrations, pH, temperature (303-333), adsorbent dose and kinetics. The surface area and pore volumes of adsorbent were measured by BET and BJH methods. The findings confirm the surface area (BET) is 248.99 $m^2/g$. The data fitted well with the Temkin and D-R isotherms for RY15 and RB5, respectively. The most favorable adsorption occurred in acidic pH. Pseudo-second order kinetic model were best in agreement with adsorption of RY15 and RB5 on ACW. The results indicate that walnut shell could be an alternative to more costly adsorbent currently being used for dyes removal.

THE INVESTIGATION OF HELICOPTER ROTOR AERODYNAMIC ANALYSIS METHODS (헬리콥터 로터 공력해석을 위한 수치적 방법 연구)

  • Park, N.E.;Woo, C.H.;Rho, H.W.;Kim, C.H.;Yee, S.J.
    • 한국전산유체공학회:학술대회논문집
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    • 2007.04a
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    • pp.120-124
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    • 2007
  • Helicopters and rotary-wing vehicles encounter a wide variety of complex aerodynamic phenomena and these phenomena present substantial challenges for computational fluid dynamics(CFD) models. This investigation presents the rotor aerodynamic analysis items for the helicopter development and variety aerodynamic analysis methods to provide the better solution to researchers and helicopter developers between aerodynamic problems and numerical aerodynamic analysis methods. The numerical methods to make an analysis of helicopter rotor are as below - CFD Modelling : actuator disk model, BET model, fully rotor model,... - Grid : sliding mesh, chimera mesh / structure mesh, unstructure mesh,... - etc. : panel method periodic boundary, quasi-steady simulation, incompressible,... The choice of CFD methodology and the numerical resolution for the overall problem have been driven mostly by available computer speed and memory at any point in time. The combination of the knowledge of aerodynamic analysis items, available computing power and choice of CFD methods now allows the solution of a number of important rotorcraft aerodynamics design problems.

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Studying of the Effects of Gamichungsangboha-tang water-extract and ethanol-extract on $IFN{\gamma}$, IL-4, T-bet, GATA-3, c-maf in Asthma Model (가미청상보하탕(加味淸上補下湯)의 물과 에탄올 추출법에 따른 항(抗)알레르기 효과(效果)에 대(對)한 연구(硏究))

  • Heo, Tae-Seok;Ko, Eun-Jung;Jung, Hee-Jae;Rhee, Hyung-Koo;Bae, Hyun-Su;Jung, Sung-Ki
    • The Journal of Internal Korean Medicine
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    • v.27 no.1
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    • pp.40-54
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    • 2006
  • Objective: This study aimed to identify the different effects of GMCSBHT water-extract and ethanol-extract on Th1/Th2 differentiation by monitoring Th1/Th2 specific cytokine secretion patterns and the transcriptional activities of T-bet, GATA-3, c-maf, $INF{\gamma}$ and IL-4. Materials and Methods: Spleen cells from eight week-old BALB/c mice were cultured in GMCSBHT extracts containing medium without activation for 24 hours and with activation for 48 hours. CD4+ T cells were isolated and mRNA expression levels of $INF{\gamma}$, IL-4, T-bet, GATA-3, c-maf by RT-PCR and secretion cytokines levels of $IFN{\gamma}$, IL-4 by ELISA were analyzed. Results: GMCSBHT extracts didn't have mitogenic effects on the unstimulated CD4+ T cells. In Th1 skewed condition, GMCSBAHT water extract had no significant effects on mRNA expression levels of $IFN{\gamma}$, T-bet and c-maf, but inhibited mRNA expression levels of IL-4, GATA-3. It showed significantly increased secretion cytokine levels of $IFN{\gamma}$, but had no significant effect on secretion cytokine levels of IL-4. In Th2 skewed condition, GMCSBHT ethanol extract inhibited mRNA expression levels of $INF{\gamma}$, IL-4, GATA-3 and c-maf significantly, but had no significant effects on mRNA expression levels of T-bet. It had no significant effects on secretion cytokine levels of $INF{\gamma}$, but showed remarkable inhibitory effects on secretion cytokine levels of IL-4. Conclusion: Results suggest that on Th1/Th2 deviation, GMCSBHT water extract has both amplifying effects on Th1 differentiation and inhibitory effects on Th2, but GMCSBHT ethanol extract has stronger inhibitory effects on Th2 differentiation than on Th1.

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