Styrene dimers and trimers from polystyrene cup noodle containers were analyzed by GC and GC/MS extracted with various simulants. For the quantitation of styrene dimers and trimers, 1,3-diphenylpropane (DP) and benzyln-butyl phthalate (BBP) were chosen as the standards. The results showed that the average of the styrene dimers in the containers was 603 ppm, and that of trimers was 5731 ppm. Four styrene dimers, including 1,2-diphenyl-cyclobutane, were identified as well as seven trimers such as 2,4,6-triphenyl-l-hexene. The migration of the styrene dimers and trimers, from the cup noodle containers of polystyrene into foods, was conducted using simulants including boiling water as well as soybean oil and n-heptane. In addition to, the analysis of each migrated styrene was also performed filled with boiling water into noodle and soup after certain time (5, 10, 20, 30 min). The results showed that the migration of styrene dimers and trimers from cup noodle containers was not detected in the case of using boiled water or soybean oil as a simulant, while styrene dimers and trimers were detected 1.18 ppm and 14.21 ppm, respectively, when heptane was adopted as a simulant. In the case of filling with boiled water into noodle and soup, both styrenes were not detected at 5 min and 10 min, however, some samples standing for 20 min released styrene dimers and trimers as much as 0.009 ppm, and 0.019 ppm for 30 min.
An, So Hyeon;Kyung, Jai Bok;Song, Seok Goo;Cho, Hyung-Ik
Journal of the Korean earth science society
/
v.41
no.3
/
pp.238-247
/
2020
This study simulated strong ground motion waveforms in the southern Korean Peninsula, based on the physical earthquake modeling of the Southern California Earthquake Center (SCEC) BroadBand Platform (BBP). Characteristics of intensity attenuation were investigated for M 6.0-7.0 events, incorporating the site effects. The SCEC BBP is software generates broadband (0-10 Hz) ground-motion waveforms for earthquake scenarios. Among five available modeling methods in the v16.5 platform, we used the Song Model. Approximately 50 earthquake scenarios each were simulated for M 6.0, 6.5, and 7.0 events. Representative metrics such as peak ground acceleration (PGA) and peak ground velocity (PGV) were obtained from the synthetic waveforms that were simulated before and after the consideration of site effects (VS30). They were then empirically converted to distribution of instrumental intensity. The intensity that considers the site effects is amplified at low rather than high VS30 zones.
Park Chan Koo;Shin Jeong Sik;Kim Min Young;Kim Pan Gyi
Journal of Environmental Health Sciences
/
v.31
no.6
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pp.457-466
/
2005
Industrial plasticizers such as phthalates can induce peroxisome proliferation. A growing concern among environmental and health groups has arisen because phthalates such as di-2-ethy1hexy1 phthalate (DEHP) and DBP may cause hormonal disorders, reproductive toxicity, hepatocellular tumors, genital disorders owing to a capacity to bind estrogen receptors, and a low-dose toxic action during certain periods of fetal development. Phthalate esters are used extensively as a plasticizer for plastic manufacture such as PVC bags and medical devices. This study investigated the effects of leached components from spring water container's cap and seal film. Phthalates, e.g. dimethy1 phthalate (DMP), diethy1 phthalate (DEP), di-n-buty1 phthalate (DBP), benzy1buty1 phthalate (BBP), di-(2-ethy1hexy1) phthalate (DEHP), and bisphenol A (BPA) were measured in the spring water. The bisphenol A was not detected or below the detection limit on the leaching from cap, sealing or spring water. DEHP were detected 90-116 ppb on the leaching from seal after 2 weeks, and 0.48-0.51 ppb from the spring water after I week. BBP were measured from seal within 1 week 25.4-66 ppb and below 0.12 ppb from spring water within 2 days. DMP were detected from seal within 2 weeks 51-68.5 ppb and 0.12 ppb after 2 weeks. DEP were measured from seal within 2 weeks 48.1-141 ppb and the concentrations were increased by the time from 0.10 to 0.31 ppb at spring water. DBP were detected from the seal within 2 weeks 92.3-5100 ppb and the concentration were decreased by the time from 0.24 to 0.10 ppb at spring water. These results indicate that some phthalate esters contaminated with spring water using the intact cap and seal film. It is concluded that the measured levels of phthalates leaching from these materials might in vivo only be slightly less than 1/10 of the LOAEL.
Journal of Korean Society of Environmental Engineers
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v.27
no.5
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pp.461-467
/
2005
Phthalate esters is recently considered as an environmental pollutant. This study investigated removal methods of phthalate esters in water environment. On tap water treatment condition with batch test, removal efficiency of coagulation precipitation of one oxidation were $26.6{\sim}33.8%$ and $10{\sim}15%$, respectively. Phthalate esters was effectively removed by the activated carbon adsorption process on tap water treatment condition. The operation of raw water with EBCT of 10 minutes on continuous process satisfied the standard of drinking water by the WHO and US EPA when the concentration of phthalate esters was $100\;{\mu}g/L$. On pilot plant test, coagulation precipitation process got $32{\sim}44%$ of removal efficiency, sand filtration process $6{\sim}10%$ and ozone oxidation process $8{\sim}10%$, respectively. DEP, DBP, BBP and DEHP were not detected after the raw water was processed with activated carbon. The actual survey of phthalate esters removal by advanced water treatment showed that $29{\sim}76%$, $3{\sim}29%$ and $17{\sim}22%$ of phthalate esters were removed on coagulation precipitation process, sand filtration and ozone oxidation process, respectively. DEP, DBP, BBP and DEHP were not detected after the raw water was processed with activated carbon.
Kim, Myung-Jin;Lee, Ju-Youn;Kim, Sung-Jo;Choi, Jeom-Il
Journal of Periodontal and Implant Science
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v.38
no.1
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pp.97-102
/
2008
Purpose: Periodontal intrabony defects have great deal of importance since they contribute to the development of periodontal disease. Current treatment regimens for intrabony defects involve grafting of numerous bony materials, GTR using biocompatible barriers, and biomodification of root surface that will encourage the attachment of connective tissue. Xenograft using deproteinized bovine bone particles seems to be very convenient to adjust because it doesn't require any donor sites or imply the danger of cross infections. These particles are similar to human cancellous bone in structure and turned out to be effective in bone regeneration in vivo. We here represent the effectiveness of grafting deproteinized bovine bone particles in intrabony defect and furcation involvements that have various numbers of bony walls. Materials and methods: Open flap debridement was done to remove all root accretions and granulation tissue from the defects within persisting intrabony lesions demonstrating attachment loss of over 6mm even 3 months after nonsurgical periodontal therapy have been completed. Deproteinized bovine bone particles($BBP^{(R)}$, Oscotec, Seoul) was grafted in intrabony defects to encourage bone regeneration. Patients were instructed of mouthrinses with chlorohexidine-digluconate twice a day and to take antibiotics 2-3 times a day for 2 weeks. They were check-up regularly for oral hygiene performance and further development of disease. Probing depth, level of attachment and mobility were measured at baseline and 6 months after the surgery. The radiographic evidence of bone regenerations were also monitored at least for 6 months. Conclusion: In most cases, radio-opacities increased after 6 months. 2- and 3-wall defects showed greater improvements in pocket depth reduction when compared to 1-wall defects. Class I & II furcation involvements in mandibular molars demonstrated the similar results with acceptable pocket depth both horizontally and vertically comparable to other intrabony defects. Exact amount of bone gain could not be measured as the re-entry procedure has not been available. With in the limited data based on our clinical parameter to measure pocket depth reduction following $BBP^{(R)}$ grafts, it was comparable to the results observed following other regeneration techniques such as GTR.
Kim Tae-Uk;Yeon Kyeong-Ho;Cho Jaeweon;Moon Seung-Hyeon
Membrane Journal
/
v.15
no.4
/
pp.297-309
/
2005
As a number of potential endocrine disrupting compounds (EDCs) are released into the environment, recently growing attention has been drawn to them. Therefore sensitive and reliable analytical methods are essential to monitor those compounds. In this study, complementary CC-MS and LC-MS were employed to analyze the endocrine disrupters, and the results of two methods were compared for di(2-ethylhexyl)phthalate (DEHP), benzylbutylphthalate (BBP), pentachlorophenol (PCP), and 4,4'-Isopropylidenediphenol (Bisphenol-A, or BPA). The results indicate that it was possible to lower the detection limits of EDCs by LC-MS. Also, LC-MS enabled to identify the EDCs as almost intact molecules. Furthermore, this study presented a nanofiltration membrane (MWCO 250) and a ultrafiltration membrane (MWCO 1,000) filtration system as methods far removing EDCs from drinking water containing $\gamma$-BHC, p,p'-DDE, BBP, p,p'-DDT, DEHP, PCP, and BPA. Cross-flow type nanofiltrations showed $100\%$ removal of EDCs, and the result implies that MWCO 250 nanofilter was sufficient for treatment of EDCs. The ratio of permeate flux to mass transfer coefficient of nanofiltration, high flux ultrafiltration, and low flux ultrafiltration with ultrapure water were 0.67, 3.4, and 0.44, respectively. It was found that nanofiltration and low flux ultrafiltration were operated at a diffusion dominant condition, and the high flux ultrafiltration was operated at a convection dominant condition. Furthermore, a diffusion dominant process attained reasonable rejection of EDCs. The removal in the ultrafiltration was depending on the molecular weight of an EDC, and the filtration was governed by diffusion-dominant hydrodynamic conditions.
Bone graft using growth factors and guided tissue regeneration have been used for the regeneration of infrabony defects which caused by periodontal disease. Calcium sulfate which is one of the resorbable barrier materials used for guided tissue regeneration. Platelet rich plasma which is a easy method to obtain the growth factors had many common points but, platelet rich plasma was still studying. This study was the comparative study between bone graft using platelet rich plasma and guided tissue regeneration using calcium sulfate barrier material in clinical view. For the study, 28 sites(2 or 3 wall infrabony defects) were treated. 14 infrabony defects were received surgical implantation of BBP-calcium sulfate composite with a calcium sulfate barrier and the others received BBP mixed with platelet rich plasma. Clinical outcome was accessed 3 and 6 months of postsurgery. 1. There was no statistical difference between CS group and PRP group in pocket depth, gingival recession, clinical attachment level, and probing bone level at baseline. 2. There was statistically significant reduction in probing depth, clinical attachment level, and probing bone level at 3 and 6 months postsurgery(p<0.05). 3. In the probing depth and clincial attachment level PPR group had less improvement than CS group, but there was no statistically difference at 3 and 6 months postsurgery. 4. In the recession PPR group had less recession than CS group, but there was no statistically difference at 3 and 6 months postsurgery. 5. In the probing bone level PPR group had less improvement than CS group, but there was no statistically difference at 6 months postsurgery. In conclusion bone graft using platelet rich plasma and guided tissue regeneration using calcium sulfate barrier showed similar clinical improvement for the treatment of 2 or 3 wall infrabony defects.
Park, Tae-Seong;Lim, Sung-Bin;Chung, Chin-Hyung;Kim, Jong-Yeo
Journal of Periodontal and Implant Science
/
v.30
no.3
/
pp.527-538
/
2000
Several extraction cases with advanced bone loss as a result of periodontal disease, root or labial bone fracture, extensive caries, and periapical lesions occur esthetic, functional problems and severe bone loss. Therefore, to treat these cases used several surgical methods and socket preservation among this therapies have been evaluated simple, effective and good prognosis in the implant placement. Socket preservation therapy have been used with barrier membranes or/and graft materials. Deproteinized bovine bone mineral have been evaluated ideal grafting materials. Recently, calcium-phosphate thin film coated bovine bone powders were developed in our country, but the study for these material wasn't reported. When two types of xenograft materials were implanted in extraction sockets of Beagle dogs, the effects of these were analyzed after 4 weeks and 8 weeks histological views. The results of this study were as follows. 1. In control groups, 4 weeks after implantation, the extraction sockets were filled with connective tissue which has dilated vessels and epithelial growth. And after 8 weeks, irregular connective bundles were observed. But new bone formation was not seen. 2. In Bio-Oss groups, epithelial growth was not seen and bone powder was covered with connective tissue fiber. New bone formation was found around the interproximal bone. There was no special change seen after 8 weeks, connective tissue fibers became more regular, and bone growth near bone powder was not made well. 3. In Ca-P BBP groups, epithelial cells didn't grow in the extraction sockets, there was a lot of new bone made around the bone powder after 8 weeks, new bone around bone powder was replaced with mature bone. It is thought that bone powder grafting into the extraction sockets is very useful for conservation of ridge, and Ca-P BBP is more effective in bone formation than Bio-Oss.
The objectives of this study were to determine the effects of substituting bread by-product (BBP) for barley grain in high concentrate fattening diets for kids on nutrient intake, growth performance, and nutrient digestibility. Twenty-eight Baladi kids (body weight=17.1${\pm}$1.0 kg) were assigned randomly to 4 experimental finishing diets (7 kids/treatment) in a completely randomized design for 70 days. The control (CON) diet contained 20, 60, 11, 7 and 2% (DM basis) alfalfa hay, barley grain, soybean meal, corn grain, and mineral and vitamin mix, respectively. Bread by-product substituted barley grain by 10, 20 and 30% of the diet DM in the LBBP, MBBP, and HBBP diets, respectively. Dry matter intakes for the CON, LBBP and MBBP diets were similar (p>0.05; avg.=592 g/day), however, kids fed the HBBP diet had a lower (p<0.05) DM intake (451 g/day). Organic matter and CP intakes showed similar patterns to that observed for DM. Dietary treatments did not affect (p>0.05) average daily gain for kids fed the CON, LBBP and MBBP diets (avg.=150 g/day). Final body weights for kids fed the CON, LBBP and MBBP diets (avg. 27.1 kg) were greater (p<0.05) than for kids fed the HBBP diet (23.7 kg). Feed to gain ratio was greater for the CON, LBBP and MBBP diets (avg. 3.9) compared with the HBBP diet (5.0). No significant (p>0.05) effect of the dietary treatment was observed for DM, OM and NDF digestibility. Substituting BBP for barley grain up to 20% of the diet DM did not affect nutrient intake, growth performance and nutrient digestibility of kids and resulted in a decrease in feed cost.
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